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Effect of Transition-Metal Ions (Ni2+, Cu2+ and Co2+) on the Electric and Dielectric Properties of Zinc Sodium Phosphate

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Abstract

In this work, the influence of transition-metal ions doping on the zinc phosphate glass has been investigated. To do so, a series of glass doped with Ni2+, Cu2+and Co2+ at different ratio (1, 2 and 5 mol %) was synthesized. The Fourier transform infrared spectra was used to elucidate the bonding system of the constituent atoms. The dielectric and conductivity properties were studied by impedance spectroscopy over a frequency range from 10–2 Hz to 1 MHz at different temperatures. The changes in the conductivity and activation energy dependon the chemical composition and indicate a changeover of the predominant conduction mechanism from ionic to polaronic. The results have shown a lower electrical conductivity for glass containing CuO. This is related to the lower depolymerization degree of the glass network by Cu2+ ions. The dielectric constant and dielectric loss increased with the temperature and decreased with the frequency for all glasses studied. The variation of the value s factor for all glass samples as the function of temperature agrees with the correlated barrier-hopping (CBH) model.

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Authors and Affiliations

  1. ZianeAchour University, Faculty of Exact Sciences and Informatics, 17000, Djelfa, Algeria

    C. Kalai, M. Kharroubi, L. Gacem & A. Belbel

  2. Université Mouloud Mammeri, 15000, Tizi-Ouzou, Algérie

    C. Kalai & F. Lalam

  3. Institut Européen des Membranes, UMR563, Université de Montpellier—CNRS—ENSCM, 34095, Place Eugène Bataillon, France

    S. Balme

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  1. C. Kalai
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Kalai, C., Kharroubi, M., Gacem, L. et al. Effect of Transition-Metal Ions (Ni2+, Cu2+ and Co2+) on the Electric and Dielectric Properties of Zinc Sodium Phosphate. Glass Phys Chem 45, 503–512 (2019). https://doi.org/10.1134/S1087659619060087

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  • DOI: https://doi.org/10.1134/S1087659619060087

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