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Licensed Unlicensed Requires Authentication Published by De Gruyter August 18, 2020

Synthesis, crystal structure, luminescence, and photocatalytic properties of a 2D Cu(II) metal-organic frameworks based on 3,5-di(1H-benzimidazol-1-yl)pyridine and 4,4′-oxybis(benzoate) ligands

  • Chen Zhang and Jian-Qing Tao EMAIL logo

Abstract

A new Cu(II) metal-organic framework, [Cu(L)(OBA)·H2O]n (1) [H2OBA = 4,4′-oxybis(benzoic acid), L = 3,5-di(1H-benzimidazol-1-yl)pyridine] was hydrothermally synthesized and characterized through IR spectroscopy, elemental and thermal analysis and single-crystal X-ray diffraction. Complex 1 is a four-connected uni-nodal 2D net with a (44·62) topology which shows an emission centered at λ ∼393 nm upon excitation at λ = 245 nm. Moreover, complex 1 possesses high photocatalytic activities for the decomposition of Rhodamine B (RhB) under UV light irradiation.


Corresponding author: Jian-Qing Tao, School of Chemistry & Environmental Engineering, Yancheng Teachers University, Yancheng, Jiangsu 224007, PR China, E-mail:

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2020-02-22
Accepted: 2020-05-02
Published Online: 2020-08-18
Published in Print: 2020-09-25

© 2020 Walter de Gruyter GmbH, Berlin/Boston

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