Abstract
A new Cu(II) metal-organic framework, [Cu(L)(OBA)·H2O]n (1) [H2OBA = 4,4′-oxybis(benzoic acid), L = 3,5-di(1H-benzimidazol-1-yl)pyridine] was hydrothermally synthesized and characterized through IR spectroscopy, elemental and thermal analysis and single-crystal X-ray diffraction. Complex 1 is a four-connected uni-nodal 2D net with a (44·62) topology which shows an emission centered at λ ∼393 nm upon excitation at λ = 245 nm. Moreover, complex 1 possesses high photocatalytic activities for the decomposition of Rhodamine B (RhB) under UV light irradiation.
Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
Research funding: None declared.
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
References
1. Chen, H. P., Zhou, S. X., Han, Z. Y., Jiang, Y. Y., Yu, H., Zhou, X. P., Jiang, R. Q., Liu, X. J., Li, X. Y. J. Mater. Chem. 2016, 4, 17207; https://doi.org/10.1039/c6ta07134a.Search in Google Scholar
2. Ma, H. P., Liu, N. L., Li, B., Zhang, L. M., Li, Y. G., Tan, H. Q., Zang, H. Y. J. Am. Chem. Soc. 2016, 138, 5897; https://doi.org/10.1021/jacs.5b13490.Search in Google Scholar
3. Chen, L. Y., Zhang, J. G., Zhou, Z. N., Zhang, T. L. RSC Adv. 2016, 6, 98381; https://doi.org/10.1039/c6ra22525j.Search in Google Scholar
4. Zhao, Y., Xu, X. Y., Qiu, L., Kang, X. J., Wen, L. L., Zhang, B. G. ACS Appl. Mater. Interfaces. 2017, 9, 15164; https://doi.org/10.1021/acsami.6b11797.Search in Google Scholar
5. Yao, S., Sun, X. D., Liu, B., Krishna, R., Li, G. H., Hu, Q. S., Liu, Y. L. J. Mater. Chem. 2016, 4, 15081; https://doi.org/10.1039/c6ta05142a.Search in Google Scholar
6. Wu, Y. P., Wu, X. Q., Wang, J. F., Zhao, J., Dong, W. W., Li, D. S., Zhang, Q. C. Cryst. Growth Des. 2016, 16, 2309; https://doi.org/10.1021/acs.cgd.6b00093.Search in Google Scholar
7. Lv, X. L., Wang, K. C., Wang, B., Su, J., Zou, X. D., Xie, Y. B., Li, J. R., Zhou, H. C. J. Am. Chem. Soc. 2017, 139, 211; https://doi.org/10.1021/jacs.6b09463.Search in Google Scholar
8. Lun, H., Li, Y., Zhang, X., Yang, J.-H., Xiao, C., Xu, Y., Li, J. J. Solid State Chem. 2014, 215, 277; https://doi.org/10.1016/j.jssc.2014.04.016.Search in Google Scholar
9. Ma, Y., Han, Z., He, Y., Yang, L. Chem. Commun. 2007, 4107; https://doi.org/10.1039/b708479j.Search in Google Scholar
10. Xu, J., Sun, X., Yan, X., Wang, S., Sun, M. Inorg. Chem. Commun. 2013, 37, 49.https://doi.org/10.1016/j.inoche.2013.09.033.Search in Google Scholar
11. Zhai, L.-L., Zhao, Y., Luo, L., Wang, P., Liu, Q., Chen, K., Sun, W.-Y. Micropor. Mesopor. Mater. 2014, 187, 86; https://doi.org/10.1016/j.micromeso.2013.12.019.Search in Google Scholar
12. Sheldrick, G. M. Acta Crystallogr. 2008, A64, 112; https://doi.org/10.1107/s0108767307043930.Search in Google Scholar
13. Spek, A. L. Acta Crystallogr. 2015, C71, 9. https://doi.org/10.1107/S2053229614024929.Search in Google Scholar
14. Spek, A. L. Acta Crystallogr. 2009, D65, 148; https://doi.org/10.1107/s090744490804362x.Search in Google Scholar
15. Wang, J., Chen, N.-N., Zhang, C., Jia, L.-Y., Fan, L. Cryst. Eng. Comm. 2020, 22, 811; https://doi.org/10.1039/c9ce01474h.Search in Google Scholar
16. Liu, G., Liang, S., Li, Q., Guo, J., Xu, N., Wang, X., Li, Y., Chen, B. Cryst. Eng. Comm. 2020, 22, 1209; https://doi.org/10.1039/c9ce01878f.Search in Google Scholar
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