Das Ytterbium(III)-Oxidbromid-Oxidotellurat(IV) Yb3O2Br[TeO3]2

Steffen F. Meier; Philip L. Russ; Thomas Schleid

doi:10.1515/znb-2020-0106

Published by De Gruyter August 21, 2020

Das Ytterbium(III)-Oxidbromid-Oxidotellurat(IV) Yb₃O₂Br[TeO₃]₂

The ytterbium(III) oxide bromide oxidotellurate(IV) Yb₃O₂Br[TeO₃]₂

Steffen F. Meier , Philip L. Russ and Thomas Schleid

From the journal Zeitschrift für Naturforschung B

https://doi.org/10.1515/znb-2020-0106

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Abstract

The ytterbium(III) oxide bromide oxidotellu-rate(IV) Yb₃O₂Br[TeO₃]₂ was obtained from a mixture of Yb₂O₃, YbBr₃ and TeO₂ in a molar ratio of 2:1:2 along with an excess of KBr as fluxing agent in evacuated fused silica ampoules after 10 days at T = 800 °C and subsequent slow cooling to room temperatures as colorless, plate-shaped single crystals. Its triclinic crystal structure (a = 663.97(5), b = 697.46(5), c = 1080.15(8) pm, α = 105.102(3), β = 90.931(3), γ = 100.034(3)°; Z = 2, space group: P1‾) displays three crystallographically different Yb³⁺ cations with coordination numbers of six, seven and eight. Six out of eight distinct oxygen atoms belong to two independent ψ¹-tetrahedral [TeO₃]²⁻anions, whereas the other two represent O²⁻ anions in tetrahedral coordination of four Yb³⁺ cations each, not having any contact to tellurium. Condensed via common vertices and edges, these [OYb₄]¹⁰⁺ tetrahedra form cationic layers ∞2{[O₂Yb₃]⁵⁺}, which spread out parallel to the (001) plane. Two discrete [TeO₃]²⁻ groups and one Br⁻ anion per formula unit take care of their three-dimensional interconnection along [001] and the overall charge balance of Yb₃O₂Br[TeO₃]₂. Remarkable interactions between the lone pair of electrons at the Te⁴⁺ cations of the ψ¹-tetrahedral [TeO₃]²⁻ anions and those at the Br⁻ anions are discussed.

Keywords: crystal structure; oxide bromides; oxidotellurates; rare earth metals; X-ray diffraction

Gewidmet Professor Christian Robl zum 65. Geburtstag.

Corresponding author: Thomas Schleid, Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, D-70569 Stuttgart, Germany, E-mail: schleid@iac.uni-stuttgart.de

Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
Research funding: None declared.
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2020-06-30

Accepted: 2020-07-05

Published Online: 2020-08-21

Published in Print: 2020-09-25

Das Ytterbium(III)-Oxidbromid-Oxidotellurat(IV) Yb₃O₂Br[TeO₃]₂

Abstract

Literatur

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