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Relationship of the Permittivity with the Activity Coefficients of Water and Ions in Aqueous Solutions of Lithium and Sodium Sulfates

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Abstract

The activity coefficients in aqueous solutions of lithium and sodium sulfates at 298 K were calculated by the generalized Debye–Hückel theory using the experimental values of the static permittivity of the solutions. The effect of the hydration and ion association on the dielectric and thermodynamic properties of the electrolyte solutions was considered.

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Funding

This work was supported by the Russian Foundation for Basic Research (project no. 19-03-00033) and by IGIC RAS state assignment.

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Authors and Affiliations

  1. Moscow State University Department of Chemistry, 119991, Moscow, Russia

    I. Yu. Shilov

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    A. K. Lyashchenko

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  1. I. Yu. Shilov
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  2. A. K. Lyashchenko
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Correspondence to I. Yu. Shilov.

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The authors declare that they have no conflicts of interest.

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Translated by V. Glyanchenko

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Shilov, I.Y., Lyashchenko, A.K. Relationship of the Permittivity with the Activity Coefficients of Water and Ions in Aqueous Solutions of Lithium and Sodium Sulfates. Russ. J. Inorg. Chem. 65, 1240–1244 (2020). https://doi.org/10.1134/S003602362008015X

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