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Synthesis of Functionalized Poly(N-(3-carboxyphenyl)maleimide-alt-styrene) and Its Heat-Resistance Mechanism

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Abstract

Poly(N-(3-carboxyphenyl)maleimide-alt-styrene) with superior heat-resistance was synthesized by free radical copolymerization and its structure was confirmed by FTIR and NMR spectroscopy. To show the advantages in heat-resistance of the synthesized copolymers, the thermal properties of poly(N-phenylmaleimide-alt-styrene) and poly(N-phenylmaleimide-alt-maleic anhydride) with similar structures were determined. DSC/TG analysis showed that the synthesized copolymer exhibited the better thermal properties than two other copolymers due to the formation of a chemically crosslinked three-dimensional network during heating.

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Funding

The authors would like to acknowledge the financial support from the National Natural Science Foundation of China (grant no. 51663006), Guizhou Province Graduate Research Foundation (KYJJ2017012), Guizhou Province Science and Technology Program Project (grant [2017] 5788).

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Authors and Affiliations

  1. College of Materials Science and Metallurgical Engineering, Guizhou University, 550025, Guiyang, China

    Qian Zhao, Yi-Kai Zhan, Yu-Fei Liu, Min He & Yong-Ji Gong

  2. National Engineering Research Center for Compounding and Modification of Polymeric Materials, 550000, Guiyang, China

    Yu-Fei Liu

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  1. Qian Zhao
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Correspondence to Qian Zhao.

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Qian Zhao, Zhan, YK., Liu, YF. et al. Synthesis of Functionalized Poly(N-(3-carboxyphenyl)maleimide-alt-styrene) and Its Heat-Resistance Mechanism. Polym. Sci. Ser. B 62, 368–374 (2020). https://doi.org/10.1134/S1560090420040119

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