Skip to main content
SpringerLink
Log in

Synthesis and Electrochemical Properties of 2,5-Disubstituted 1,4-Bis(4,5-diphenyl-1H-imidazol-2-yl)benzene Derivatives

  • Published:
Russian Journal of Organic Chemistry Aims and scope Submit manuscript

Abstract

2,5-Disubstituted 1,4-bis(4,5-diphenyl-1H-imidazol-2-yl)benzenes have been synthesized, and their electrochemical properties have been studied by cyclic voltammetry, in particular the effect of substituents on the redox characteristics has been examined. The reversible electrochemical redox transformation quinone–biradical of the title compounds occurs at positive potentials.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme
Scheme
Fig. 1.
Fig. 2.
Scheme
Scheme
Fig. 3.
Fig. 4.
Scheme

Similar content being viewed by others

REFERENCES

  1. Lu, N.-N., Yoo, S.J., Li, L.-J., Zeng, C.-C., and Little, R.D., Electrochim. Acta, 2014, vol. 142, p. 254. https://doi.org/10.1016/j.electacta.2014.07.105

    Article  CAS  Google Scholar 

  2. Francke, R. and Little, R.D., J. Am. Chem. Soc., 2014, vol. 136, p. 427. https://doi.org/10.1021/ja410865z

    Article  CAS  PubMed  Google Scholar 

  3. Zeng, C.-C., Zhang, N.-T., Lam, C.M., and Little, R.D., Org. Lett., 2012, vol. 14, p. 1314. https://doi.org/10.1021/ol300195c

    Article  CAS  PubMed  Google Scholar 

  4. Englander, F., US Patent no. 4465865, 1984.

  5. Gerrard, W., Green, W.J., Nutkins, R.A., Sykes, A., Tatlow, J.C., Addison, C.C., Lewis, J., Jones, R.L., Le Fèvre, R.J.W., Northcott, J., Hall, R.H., Stern, E.S., Naylor, J.R., Islam, A.M., and Raphael, R.A., J. Chem. Soc., 1952, p. 4076. https://doi.org/10.1039/JR9520004076

  6. Bard, A.J. and Faulkner, L.R., Electrochemical Methods, New York: Wiley, 2001.

  7. Xia, C. and Advincula, R.C., Macromolecules, 2001, vol. 34, p. 6922. https://doi.org/10.1021/ma0100192

    Article  CAS  Google Scholar 

  8. Maeda, K., Sakaino, Y., and Hayashi, T., Nippon Kagaku Kaishi, 1972, vol. 1972, p. 100. https://doi.org/10.1246/nikkashi.1972.100

    Article  Google Scholar 

  9. Sakaino, Y., Kakisawa, H., Kusumi, T., and Maeda, K., J. Org. Chem., 1979, vol. 44, p. 1241. https://doi.org/10.1021/jo01322a010

    Article  CAS  Google Scholar 

Download references

Funding

This study was performed under financial support by the Ministry of Science and Higher Education of the Russian Federation in the framework of state assignment in the field of research activity (project no. 4.4566.2017/8.9).

Author information

Authors and Affiliations

  1. Ogarev Mordovian National Research State University, 430005, Saransk, Russia

    D. B. Chugunov, E. V. Okina, A. S. Timonina, L. A. Klimaeva & Yu. M. Selivanova

Authors
  1. D. B. Chugunov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. V. Okina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. S. Timonina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. A. Klimaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yu. M. Selivanova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to D. B. Chugunov.

Ethics declarations

The authors declare no conflict of interest.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chugunov, D.B., Okina, E.V., Timonina, A.S. et al. Synthesis and Electrochemical Properties of 2,5-Disubstituted 1,4-Bis(4,5-diphenyl-1H-imidazol-2-yl)benzene Derivatives. Russ J Org Chem 56, 1222–1227 (2020). https://doi.org/10.1134/S1070428020070167

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070428020070167

Keywords:

Search

Navigation