Abstract
Successive reactions of pentafluoronitrobenzene with resorcinol, orcinol, and tetrafluororesorcinol in acetonitrile in the presence of triethylamine afforded polyfluorinated ABAB and ABAC tetraoxacalix[4]arenes. Analysis of the1H and 19F NMR spectra of the synthesized oxacalixarenes indicated high conformational mobility of the resorcinol and tetrafluororesorcinol fragments of their molecules due to interaction with the solvent.
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ACKNOWLEDGMENTS
The authors thank the Joint Chemical Service Center, Siberian Branch, Russian Academy of Sciences, for providing facilities for analytical and spectral studies.
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H. Han thanks the State Fellowship Committee of the People Republic of China for financial support.
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Kovtonyuk, V.N., Han, H. & Gatilov, Y.V. Synthesis of Polyfluorinated Tetraoxacalix[4]arenes by Reaction of Pentafluoronitrobenzene with Resorcinol, Orcinol, and Tetrafluororesorcinol. Russ J Org Chem 56, 1153–1159 (2020). https://doi.org/10.1134/S1070428020070052
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DOI: https://doi.org/10.1134/S1070428020070052