Eu3+-doped NaLaMo2O8 phosphors were synthesized by a conventional solid-state reaction. The phase and luminescent properties of the synthesized phosphors were investigated in the current work. In NaLaMo2O8, Eu3+ ions replace La3+ ions and form solid compound. This substitution induces the 2θ angles of diffraction peaks to shift to larger values. Under excitation at 395 nm, NaLaMo2O8:Eu3+ phosphors exhibit emission bands in the range of 550–725 nm originating from 5D0 → 7FJ transitions (J = 0, 1, 2, 3, 4) of Eu3+. The strongest emission band corresponds to the 5D0 → 7F2 transition, which indicates a site of Eu3+ without inversion symmetry in NaLaMo2O8. The Eu3+ concentration has obvious influence on the luminescent properties of NaLaMo2O8:Eu3+ phosphors. NaLaMo2O8:6 mol%Eu3+ has the strongest excitation and emission intensities.
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X. Qin, X. Liu, W. Huang, M. Bettinelli, and X. Liu, Chem. Rev., 117, 4488–4527 (2017).
M. P. Hehlen, M. G. Brik, and K. W. Krämer, J. Lumin., 136, 221–239 (2013).
L. van Pieterson, M. F. Reid, R. T. Wegh, and A. Meijerink, J. Lumin., 94–95, 79–83 (2001).
M. Shang, C. Li, and J. Lin, Chem. Soc. Rev., 43, 1372–1386 (2014).
Y. Yang, J. Li, B. Liu, Y. Zhang, X. Lv, L. Wei, X. Wang, J. Xu, H. Yu, Y. Hu, H. Zhang, L. Ma, and J. Wang, Chem. Phys. Lett., 685, 89–94 (2017).
S. Mishra, R. Rajeswari, N. Vijayan, V. Shanker, M. K. Dalai, C. K. Jayasankar, S. S. Babu, and D. Haranath, J. Mater. Chem. C, 1, 5849–5855 (2013).
A. M. Kaczmarek and R. V. Deun, Chem. Soc. Rev., 42, 8835–8848 (2013).
Y. Liu, X. Yue, K. Cai, H. Deng, M. Zhang, Energy, 93, 1413–1417 (2015).
Y. Liu, Z.-G. Lu, Y-Y. Gu, and W. Li, J. Lumin., 132, 1220–1225 (2012).
D. Huang, Y. Zhou, W. Xu, Z. Yang, Z. Liu, M. Hong, Y. Lin, and J. Yu, J. Alloys Compd., 554, 312–318 (2013).
Y. Tian, B. Chen, R. Hua, N. Yu, B. Liu, J. Sun, L. Cheng, H. Zhang, X. Li, J. Zhang, B. Tian, and H. Zhong, Cryst. Eng. Commun., 14, 1760–1769 (2012).
B. Krishnan, J. Thirumalai, S. Thomas, and M. Gowri, J. Alloys Compd., 604, 20–30 (2014).
L. Kong, X. Xiao, J. Yu, D. Mao, and G. Lu, J. Mater. Sci., 52, 6310–6321 (2017).
J. Liu, B. Xu, C. Song, H. Luo, X. Zou, L. Han, and X. Yu, Cryst. Eng. Commun., 14, 2936–2943 (2012).
Y. Liu, Y. Wang, L. Wang, Y. Y. Gu, S. H. Yu, Z. G. Lu, and R. Sun, RSC Adv., 4, 4754–4762 (2014).
R. Cao, C. Liao, F. Xiao, G. Zheng, W. Hu, Y. Guo, and X. Ye, Dyes Pigments, 149, 574–580 (2018).
D. He, C. Guo, S. Zhou, L. Zhang, Z. Yang, C. Duan, and M. Yin, Cryst. Eng. Commun., 17, 7745–7753 (2015).
T. Li, C. Guo, P. Zhao, L. Li, and J. H. Jeong, J. Am. Ceram. Soc., 96, 1193–1197 (2013).
S. Brahma, R. N. P. Choudhary, A. K. Thakur, and S. A. Shivashankar, New J. Glass Ceram., 2, 7–12 (2012).
L. Li, Y. Liu, R. Li, Z. Leng, and S. Gan, RSC Adv., 5, 7049–7057 (2015).
Y. Yang, X. Wang, and B. Liu, Nano, 9, 1450008 (2014).
B. Liu, Y. Yang, and X. Wang, Nanosci. Nanotech. Lett., 5, 1298–1301 (2013).
Y. Yang, Mater. Sci. Eng. B, 178, 807–810 (2013).
S. G. Prasanna Kumara, R. Hari Krishna, N. Kottam, P. Krishna Murthy, C. Manjunatha, R. Preetham, C. Shivakumara, and T. Thomas, Dyes Pigments, 150, 306–314 (2018).
D. L. Dexter and J. H. Schulman, J. Chem. Phys. 22, 1063–1070 (1954).
L. G. Van Uitert, J. Electrochem. Soc., 114, 1048–1053 (1967).
R. Yu, S. Zhong, N. Xue, H. Li, and H. Ma, Dalton Tran., 43, 10969–10976 (2014).
Y. Chang, Z. Shi, Y. Tsai, S. Wu, and H. Chen, Opt. Mater., 33, 375–380 (2011).
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Abstract of article is published in Zhurnal Prikladnoi Spektroskopii, Vol. 87, No. 4, p. 680, July–August, 2020.
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Sun, J., Li, Q. & Zhou, Q. Synthesis and Red Emission of Eu3+-DOPED NaLaMo2O8 Phosphors. J Appl Spectrosc 87, 753–757 (2020). https://doi.org/10.1007/s10812-020-01065-4
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DOI: https://doi.org/10.1007/s10812-020-01065-4