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Synthesis and Red Emission of Eu3+-DOPED NaLaMo2O8 Phosphors

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Journal of Applied Spectroscopy Aims and scope

Eu3+-doped NaLaMo2O8 phosphors were synthesized by a conventional solid-state reaction. The phase and luminescent properties of the synthesized phosphors were investigated in the current work. In NaLaMo2O8, Eu3+ ions replace La3+ ions and form solid compound. This substitution induces the 2θ angles of diffraction peaks to shift to larger values. Under excitation at 395 nm, NaLaMo2O8:Eu3+ phosphors exhibit emission bands in the range of 550–725 nm originating from 5D07FJ transitions (J = 0, 1, 2, 3, 4) of Eu3+. The strongest emission band corresponds to the 5D07F2 transition, which indicates a site of Eu3+ without inversion symmetry in NaLaMo2O8. The Eu3+ concentration has obvious influence on the luminescent properties of NaLaMo2O8:Eu3+ phosphors. NaLaMo2O8:6 mol%Eu3+ has the strongest excitation and emission intensities.

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References

  1. X. Qin, X. Liu, W. Huang, M. Bettinelli, and X. Liu, Chem. Rev., 117, 4488–4527 (2017).

    Article  Google Scholar 

  2. M. P. Hehlen, M. G. Brik, and K. W. Krämer, J. Lumin., 136, 221–239 (2013).

    Article  Google Scholar 

  3. L. van Pieterson, M. F. Reid, R. T. Wegh, and A. Meijerink, J. Lumin., 9495, 79–83 (2001).

  4. M. Shang, C. Li, and J. Lin, Chem. Soc. Rev., 43, 1372–1386 (2014).

    Article  Google Scholar 

  5. Y. Yang, J. Li, B. Liu, Y. Zhang, X. Lv, L. Wei, X. Wang, J. Xu, H. Yu, Y. Hu, H. Zhang, L. Ma, and J. Wang, Chem. Phys. Lett., 685, 89–94 (2017).

    Article  ADS  Google Scholar 

  6. S. Mishra, R. Rajeswari, N. Vijayan, V. Shanker, M. K. Dalai, C. K. Jayasankar, S. S. Babu, and D. Haranath, J. Mater. Chem. C, 1, 5849–5855 (2013).

    Article  Google Scholar 

  7. A. M. Kaczmarek and R. V. Deun, Chem. Soc. Rev., 42, 8835–8848 (2013).

    Article  Google Scholar 

  8. Y. Liu, X. Yue, K. Cai, H. Deng, M. Zhang, Energy, 93, 1413–1417 (2015).

    Article  Google Scholar 

  9. Y. Liu, Z.-G. Lu, Y-Y. Gu, and W. Li, J. Lumin., 132, 1220–1225 (2012).

    Article  Google Scholar 

  10. D. Huang, Y. Zhou, W. Xu, Z. Yang, Z. Liu, M. Hong, Y. Lin, and J. Yu, J. Alloys Compd., 554, 312–318 (2013).

    Article  Google Scholar 

  11. Y. Tian, B. Chen, R. Hua, N. Yu, B. Liu, J. Sun, L. Cheng, H. Zhang, X. Li, J. Zhang, B. Tian, and H. Zhong, Cryst. Eng. Commun., 14, 1760–1769 (2012).

    Article  Google Scholar 

  12. B. Krishnan, J. Thirumalai, S. Thomas, and M. Gowri, J. Alloys Compd., 604, 20–30 (2014).

    Article  Google Scholar 

  13. L. Kong, X. Xiao, J. Yu, D. Mao, and G. Lu, J. Mater. Sci., 52, 6310–6321 (2017).

    Article  ADS  Google Scholar 

  14. J. Liu, B. Xu, C. Song, H. Luo, X. Zou, L. Han, and X. Yu, Cryst. Eng. Commun., 14, 2936–2943 (2012).

    Article  Google Scholar 

  15. Y. Liu, Y. Wang, L. Wang, Y. Y. Gu, S. H. Yu, Z. G. Lu, and R. Sun, RSC Adv., 4, 4754–4762 (2014).

    Article  Google Scholar 

  16. R. Cao, C. Liao, F. Xiao, G. Zheng, W. Hu, Y. Guo, and X. Ye, Dyes Pigments, 149, 574–580 (2018).

    Article  Google Scholar 

  17. D. He, C. Guo, S. Zhou, L. Zhang, Z. Yang, C. Duan, and M. Yin, Cryst. Eng. Commun., 17, 7745–7753 (2015).

    Article  Google Scholar 

  18. T. Li, C. Guo, P. Zhao, L. Li, and J. H. Jeong, J. Am. Ceram. Soc., 96, 1193–1197 (2013).

    Article  Google Scholar 

  19. S. Brahma, R. N. P. Choudhary, A. K. Thakur, and S. A. Shivashankar, New J. Glass Ceram., 2, 7–12 (2012).

    Article  Google Scholar 

  20. L. Li, Y. Liu, R. Li, Z. Leng, and S. Gan, RSC Adv., 5, 7049–7057 (2015).

    Article  Google Scholar 

  21. Y. Yang, X. Wang, and B. Liu, Nano, 9, 1450008 (2014).

    Article  Google Scholar 

  22. B. Liu, Y. Yang, and X. Wang, Nanosci. Nanotech. Lett., 5, 1298–1301 (2013).

    Article  Google Scholar 

  23. Y. Yang, Mater. Sci. Eng. B, 178, 807–810 (2013).

    Article  Google Scholar 

  24. S. G. Prasanna Kumara, R. Hari Krishna, N. Kottam, P. Krishna Murthy, C. Manjunatha, R. Preetham, C. Shivakumara, and T. Thomas, Dyes Pigments, 150, 306–314 (2018).

    Article  Google Scholar 

  25. D. L. Dexter and J. H. Schulman, J. Chem. Phys. 22, 1063–1070 (1954).

    Article  ADS  Google Scholar 

  26. L. G. Van Uitert, J. Electrochem. Soc., 114, 1048–1053 (1967).

    Article  Google Scholar 

  27. R. Yu, S. Zhong, N. Xue, H. Li, and H. Ma, Dalton Tran., 43, 10969–10976 (2014).

    Article  Google Scholar 

  28. Y. Chang, Z. Shi, Y. Tsai, S. Wu, and H. Chen, Opt. Mater., 33, 375–380 (2011).

    Article  ADS  Google Scholar 

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Correspondence to Q. Li.

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Abstract of article is published in Zhurnal Prikladnoi Spektroskopii, Vol. 87, No. 4, p. 680, July–August, 2020.

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Sun, J., Li, Q. & Zhou, Q. Synthesis and Red Emission of Eu3+-DOPED NaLaMo2O8 Phosphors. J Appl Spectrosc 87, 753–757 (2020). https://doi.org/10.1007/s10812-020-01065-4

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  • DOI: https://doi.org/10.1007/s10812-020-01065-4

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