Abstract
Nanostructures of oxides of 3d—5d transient metals: copper, zinc, zirconium, molybdenum, tungsten, and vanadium are synthesized by laser ablation of pure metals in water. Electro-optical and X-ray studies showed that the layered material composing nanostructures is mostly in an amorphous state and apparently consists of molecular clusters no larger than 1—2 nm. The structures of studied oxides are similar and are shaped as conglomerates of nanoscale solid and hollow spheroids, plates, threads, and foam formations.
Similar content being viewed by others
REFERENCES
A. A. Eliseev and A. V. Lukashin, Functional Nanomaterials, Ed. by Yu. D. Tret’yakov (Fizmalit, Moscow, 2010). ISBN 978-5-9221-1120-1
I. R. Nabiev, R. G. Efremov, and G. D. Chumanov, “Surface-Enhanced Raman Scattering and its Application to the Study of Biological Molecules,” Sov. Phys. Usp. 31, 241 (1988). https://doi.org/10.1070/PU1988v031n03ABEH005720
S. D. Khanin, Problems of Electrophysics of Metal-Oxide Capacitor Dielectrics: Reviews on Electronic Engineering (Elektronika, Moscow, 1990).
A. Yu. Varaksin, “Gas-Solid Flow Past Bodies,” High Temp. 56, 275 (2018). https://doi.org/10.1134/S001815X18020220
V. T. Karpukhin, M. M. Malikov, T. I. Borodina, G. E. Val’yano, and O. A. Gololobova, “An Investigation of the Effect of Surface-Enhanced Raman Scattering on Zirconium and Molybdenum Nanostructures Synthesized by Laser Ablation in a Liquid Environment,” in Laser Ablation:Advances in Research and Applications (Nova Science, New York, 2017). ISBN: 978-153612405-7.
V. A. Novozhenov, Introduction into Inorganic Chemistry (Altai State Univ., Barnaul, 2001).
C. N. Rao, “Transition Metal Oxides,” Annu. Rev. Phys. Chem. No. 40, 291 (1989). https://doi.org/10.1146/annurev.pc.40.100189.001451
V. S. Zuev, “Surface Polaritons and Plasmons: Spontaneous Emission of Atom near a Small-Size Body,” Preprint No. 3, FIAN (Lebedev Physical Institute, Russian Academy of Sciences, Moscow, 2012).
P. M. S. Monk, R. J. Mortimer, and D. R. Rosseinsky, Electrochromism: Fundamentals and Applications (VCH: Weinheim, 1995). https://doi.org/10.1017/CBO9780511550959
D. F. Kirienko, “Switching and Electrochromic Effect in Nano and Microstructures Based on Transition Metal Oxides,” Candidate’s Dissertation in Mathematics and Physics (Petrozavodsk, 2013).
S. A. Kostylev and V. A. Shkut, Electronic Switching in Amorphous Semiconductors (Naukova Dumka, Kiev, 1978).
A. L. Pergament, G. B. Stefanovich, and F. A. Chudnovskii, “Metal—Semiconductor Phase Transition and Switching Effect in Transition Metal Oxides,” Fiz. Tverd. Tela 36, 2988 (1994).
A. Madan and M. P. Shaw, Physics and Application of Amorphous Semiconductors (Academic, Boston, 1988). ISBN 0-12-464960-2
G. W. Yang, “Laser Ablation in Liquids: Application in Synthesis of Nanocrystalls,” Progr. Mater. Sci. 52, 648 (2007). https://doi.org/10.1016/j.pmatsci.2006.10.016
V. M. Batenin, P. A. Bokhan, V. V. Buchanov, G. S. Evtushenko, M. A. Kazaryan, V. T. Karpukhin, I. I. Klimovskii, and M. M. Malikov, Metal Atom Self-Terminating Lasers (Fizmatlits, Moscow, 2011), Vol. 2. ISBN 978-5-9221-1298-7
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by A. Kazantsev
About this article
Cite this article
Borodina, T.I., Val’yano, G.E., Karpukhin, V.T. et al. Structural Features and General Morphology of Copper, Zinc, Zirconium, Molybdenum, Tungsten, and Vanadium Oxide Nanostructures Synthesized by Laser Ablation Method in Water. Bull. Lebedev Phys. Inst. 47, 191–196 (2020). https://doi.org/10.3103/S1068335620070039
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S1068335620070039