Abstract
The zeolite membrane as a corrosion-resistant membrane has green environmental protection, high-temperature resistance, high-mechanical strength, and other characteristics, which has attracted much attention. However, due to the very different surface properties between metals and inorganics, the embodiment of high-binding force membrane is a major difficulty in the current zeolite membrane synthesis technology. Research has been conducted on the silane (YDH-151)/zeolite (TS-1) composite anticorrosive membrane in Ti-6Al-4V alloy surface, and on the modification effect by using graphene oxide (GO), as well as the membrane formation mechanism after being modified. Scanning electron microscope and 3D laser confocal microscope (3D LCSM) were used to study the effect of GO on the modified silane/zeolite composite anticorrosion membrane, and electrochemical methods, contact angle, bonding force, Fourier transform infrared ray were used to study the modification effect and the membrane formation mechanism and process after being modified. Microscopic observations show that GO causes the zeolite particles to accelerate to accumulate, hinders the lateral membrane formation of TS-1 zeolite which forms thus non-negligible pores or defects. It also reduces the density of the zeolite membrane, and the hydrophobicity and binding force of the composite membrane. However, GO can effectively decrease the corrosion current density and greatly enhance the corrosion resistance of the membrane. YDH-151 undergoes dehydration condensation reaction with metal surface and zeolite, and graft reaction with GO, forming a dense YDH-151/GO/TS-1 composite membrane on the surface of Ti-6Al-4V alloy, with a corrosion resistance rate of 99.8%.
Similar content being viewed by others
References
D. Song, X. Jing, J. Wang et al., Corrosion-Resistant ZSM-5 Zeolite Coatings Formed on Mg-Li Alloy by Hot-Pressing, Corros. Sci., 2011, 53(5), p 1732–1737
L. Bonaccorsi, L. Calabrese, and E. Prpverbio, Low temperature single-step synthesis of zeolite Y coatings on aluminium substrates, Microporous Mesoporous Mater., 2011, 144, p 40–45
J. Du, Y. Liu, X. Li et al., Preparation of Silicalite-1 Molecular Sieve Composite Anticorrosive Film on Stainless Steel Surfaces and Its Anticorrosion Performance and Mechanism, J. Mater. Eng. Perform., 2020, 29(4), p 2720–2730
L. Xiaofei, Y. Yanwei, Z. Junjia, Y. Yushan, and W. Zhengbao, Solvent-Free Secondary Growth of Highly b-Oriented MFI, Zeolite Films from Anhydrous Synthetic Powder, J. Am. Chem. Soc., 2019, 141(7), p 2916–2919
F. Banihashemi, A.F.M. Ibrahim, A.A. Babaluo, and J.Y.S. Lin, Template-Free Synthesis of Highly b-Oriented MFI-Type Zeolite Thin Membranes by Seeded Secondary Growth, Angewandte Chemie (Int. Ed. Engl.), 2019, 58(8), p 2519–2523
D.H. Xia, C. Pan, Z. Qin et al., Covalent Surface Modification of LY12 Aluminum Alloy Surface by Self-Assembly Dodecyl Phosphate Film Towards Corrosion Protection, Prog. Org. Coat., 2020, 143, p 105638
S.A. Morshed, A. Sinha, Q. Zhang, and J. Tatar, Hygrothermal Conditioning of Wet-Layup CFRP-Concrete Adhesive Joints Modified with Silane Coupling Agent and Core-Shell Rubber Nanoparticles, Constr. Build. Mater., 2019, 227, p 116531
Y. Lv and T. Zhu, Polyethyleneimine-Modified Porous Aromatic Framework and Silane Coupling Agent Grafted Graphene Oxide Composite Materials for Determination of Phenolic Acids in Chinese Wolfberry Drink by HPLC, J. Sep. Sci., 2020, 43(4), p 774–781
D. Song, X. Jing, J. Wang et al., The Assembly of ZSM-5 Layer on Mg-Li Alloy by Hot-Pressing Using Silane Coupling Agent as Bond and Its Corrosion Resistance, J. Alloys Compd., 2012, 510(1), p 66–70
W. Xiao, R. Man, C. Miu et al., Study on Corrosion Resistance of the BTESPT Silane Cooperating with Rare Earth Cerium on the Surface of Aluminum-Tube, J. Chin. Rare Earth Soc., 2010, 000(001), p 117–122
V. Dalmoro, J.H.Z. Dos Santos, E. Armelin et al., Phosphonic Acid/Silica-Based Films: A Potential Treatment for Corrosion Protection, Corros. Sci., 2012, 60, p 173
J.M. Hu, L. Liu, J.Q. Zhang et al., Electrodeposition of Silane Films on Aluminum Alloys for Corrosion Protection, Prog. Org. Coat., 2007, 58, p 265
M.F. Montemor, R. Pinto, and M.G.S. Ferreira, Chemical Composition and Corrosion Protection of Silane Membranes Modified with CeO2 Nanoparticles, Electrochim. Acta, 2009, 54, p 5179–5189
M.G. Olivier, M. Fedel, V. Sciamanna, C. Vandermiers, C. Motte, M. Poelman, and F. Deflorian, Study of the Effect of Nanoclay Incorporation on the Rheological Properties and Corrosion Protection by a Silane Layer, Prog. Org. Coat., 2011, 72, p 15–20
M.L. Zheludkevich, R. Serra, M.F. Montemor, K.A. Yasakau, I.M.M. Salvado, and M.G.S. Ferreira, Nanostructured Sol-Gel Coatings Doped with Cerium Nitrate as Pre-treatments for AA2024-T3, Electrochim. Acta, 2005, 51, p 208–217
S. Yangyang, C. Guanggui, Z. Zhongqiang, D. Jianning, G. Liqiang, Z. Wei, and L. Zhiyong, Preparation and Properties of Anticorrosive Films on Aluminum Alloy Surfaces, Rare Met. Mater. Eng., 2016, 45(04), p 952–956
Y.C. Dun and Y. Zuo, Preparation and Characterization of a GPTMS/Graphene Coating on AA-2024 Alloy, Appl. Surf. Sci., 2017, 416, p 492–502
D. Prasai, J.C. Tuberquia, R.R. Harl et al., Graphene: Corrosion Inhibiting Coating, ACS Nano, 2012, 6, p 1102–1108
A.S. Kousalya, A. Kumar, R. Paul et al., Graphene: An Effective Oxidation Barrier Coating for Liquid and Two-Phase Cooling Systems, Corros. Sci., 2013, 69, p 5–10
Y. Lihang, TS-1 Zeolite Membrane Synthesis and Microwave Fenton Oxidation Removal of Template, Tianjin University, Tianjin, 2014
T.C. Pham, T.H. Nguyen, and K.B. Yoon, Gel-Free Secondary Growth of Uniformly Oriented Silica MFI, Zeolite Membranes and Application for Xylene Separation, Angewandte Chemie (Int. Ed. Engl.), 2013, 52(33), p 8855–8860
X. Lu, Y. Peng, Z. Wang, and Y. Yan, A Facile Fabrication of Highly b-Oriented MFI, Zeolite Membranes in the TEOS-TPAOH-H2O System Without Additives, Microporous Mesoporous Mater., 2016, 230, p 49–57
X. Li, Z. Wang, J. Zheng, S. Shao, Y. Wang, and Y. Yan, Dynamic Hydrothermal Synthesis of a b-Oriented MFI, Zeolite Membrane, Chin. J. Catal., 2011, 32(1–2), p 217–223
G.P. Barbosa, H.S. Debone, P. Severino, E.B. Souto, and C.F. da Silva, Design and Characterization of Chitosan/Zeolite Composite Membranes—Effect of Zeolite Type and Zeolite Dose on the Membrane Properties, Mater. Sci. Eng., C, 2016, 60, p 246–254
A. Said, H. Nouali, L. Limousy, P. Dutournié, L. Josien, J. Toufaily, T. Hamieh, and T.J. Daou, Synthesis of Mono- and Bi-layer Zeolite Membranes on Alumina Substrates, C. R. Chim., 2016, 19(4), p 486–495
L. Jing, Z. Zhishou, W. Xinnan, F. Yue, S. Guoqiang, and Z. Liwei, Fatigue Crack Propagation Behavior of TC4-DT Alloy with Quasi-β Heat Treatment, Chin. J. Rare Met., 2017, 41(7), p 745–750
A. Said, L. Limousy, H. Nouali, L. Michelin, J. Halawani, J. Toufaily, T. Hamieh, P. Dutournié, and T.J. Daou, Synthesis of Mono- and Bi-layer MFI, Zeolite Membranes on Macroporous Alumina Tubular Supports: Application to Nanofiltration, J. Cryst. Growth, 2015, 428, p 486–495
F. Jiang, J. Huang, L. Niu, and G. Xiao, Atomic Layer Deposition of ZnO Thin Membranes on ZSM-5 Zeolite and Its Catalytic Performance in Chichibabin Reaction, Catal. Lett., 2015, 145(3), p 947–954
L. Lakiss, S. Thomas, P. Bazin, V. de Waele, and S. Mintova, Metal Loaded Zeolite Membranes with Bi-modal Porosity for Selective Detection of Carbon Monoxide, Microporous Mesoporous Mater., 2014, 200, p 326–333
T.J. Daou, N. Lauridant, G. Arnold, L. Josien, D. Faye, and J. Patarin, Synthesis of MFI/EMT Zeolite Bi-layer Membranes for Molecular Decontamination, Chem. Eng. J., 2013, 234, p 66–73
Q. Chu and L. Lin, Y Zhao (2019) Hyperbranched Polyethylenimine Modified with Silane Coupling Agent as Shale Inhibitor for Water-Based Drilling Fluids, J. Pet. Sci. Eng., 2019, 182, p 106333
Z. Wei, T. Chao, X. Jufang, and G. Yingang, Micro-scale Effects of Nano-SiO2 Modification with Silane Coupling Agents on the Cellulose/Nano-SiO2 Interface, Nanotechnology, 2019, 30(44), p 445701
D.H. Xia, S. Song, Y. Behnamian, W. Hu, Y.F. Cheng, J.L. Luo, and F. Huet, Review-Electrochemical Noise Applied in Corrosion Science: Theoretical and Mathematical Models towards Quantitative Analysis, J. Electrochem. Soc., 2020, 167(8), p 081507
Acknowledgments
This work was supported by Tianjin Municipal Education Commission Scientific Research Project (2019KJ136).
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Du, J., Qingmao, L., Li, X. et al. Research on the Modification of Silane/Zeolite Composite Anticorrosive Membrane on Ti-6Al-4V Alloy Surface by Graphene Oxide and Its Mechanism. J. of Materi Eng and Perform 29, 6130–6138 (2020). https://doi.org/10.1007/s11665-020-05089-x
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11665-020-05089-x