Abstract
Samples of pine wood ozonated with different contents of water are studied via UV diffuse reflectance spectroscopy. It is shown that polyaromatic and stilbene structures, guaiacyl derivatives, and carbonyl- and carboxyl-containing aromatic structures of lignin are destroyed during ozonation of pine wood. The destruction of aromatic structures proceeds efficiently in wood with a moisture content of more than 60–65% in the 2–3 mmol/g range of ozone consumption. When the moisture content is below 40%, ozone treatment of pine wood at low ozone consumption allows us to obtain different modifications of oxygen-containing aromatic and polyaromatic structures on surfaces of lignocellulosic material (LCM). IR absorption spectra of dioxane lignin obtained from the initial and ozonated wood samples confirm the different direction of lignin transformations, depending on the content of moisture in the wood.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
S. D. Razumovskii and G. E. Zaikov, Ozone and Its Reactions with Organic Compounds (Elsevier, Amsterdam, 1984).
G. Audran, S. R. A. Marque, and M. Santelli, Tetrahedron 74, 6221 (2018).
V. A. Demin, V. V. Shereshovets, and Yu. B. Monakov, Russ. Chem. Rev. 68, 937 (1999).
M. B. Roncero, J. F. Colom, and T. Vidal, Carbohydr. Polym. 51, 243 (2003).
C. Li, L. Wang, Z. Chen, Y. Li, et al., Bioresour. Technol. 183, 240 (2015).
R. Travaini, M. D. M. Otero, M. Coca, et al., Biores. Technol. 133, 332 (2013).
E. M. Ben’ko, D. G. Chukhchin, and V. V. Lunin, Russ. J. Phys. Chem. A 91, 2092 (2017).
E. M. Ben’ko, N. A. Mamleeva, D. G. Chukhchin, et al., Russ. J. Phys. Chem. A 94, 1153 (2020).
N. A. Mamleeva, A. N. Kharlanov, D. G. Chukhchin, et al., Khim. Rastit. Syr’ya, No. 1, 85 (2019). https://doi.org/10.14258/jcprm.2019015143
N. A. Mamleeva, S. A. Autlov, N. G. Bazarnova, and V. V. Lunin, Russ. J. Bioorg. Chem. 42, 694 (2016).
J. E. Holladay, J. J. Bozell, J. F. White, and D. Johnson, Top Value-Added Chemicals from Biomass (USA, 2007), Vol. 2. http://www.ntis.gov/ordering.htm.
N. A. Mamleeva, N. A. Babayeva, A. N. Kharlanov, and V. V. Lunin, Russ. J. Phys. Chem. A 93, 28 (2019).
K. G. Bogolitsyn and I. Lindberg, Khim. Drev., No. 4, 56 (1986).
N. R. Popova and K. G. Bogolitsyn, Physicochemistry of Lignin, Ed. by K. G. Bogolitsyn and V. V. Lunin (Arkhang. Gos. Tekh. Univ., Arkhangel’sk, 2009) [in Russian].
K. G. Bogolitsyn, Zh. Prikl. Spektrosk. 46, 1024 (1987).
M. Schwanninger, J. C. Rodrigues, H. Pereira, and B. Hinterstoisser, Vibr. Spectrosc. 36, 23 (2004).
V. V. Kovaleva, N. A. Mamleeva, E. M. Ben’ko, E. G. Bekker, A. N. Mitrofanova, A. N. Pryakhin, and V. V. Lunin, Russ. J. Phys. Chem. A 75, 49 (2001).
N. A. Mamleeva, A. L. Kustov, and V. V. Lunin, Russ. J. Phys. Chem. A 92, 1675 (2018).
P. S. Bailey, in Ozonation in Organic Chemistry, Vol. 2: Nonolefinic Compounds (Academic, New York, 1982), p. 31.
V. V. Lunin, M. P. Popovich, and S. N. Tkachenko, Physical Chemistry of Ozone (Mosk. Gos. Univ., Moscow, 1998) [in Russian].
N. A. Mamleeva, A. V. Shumyantsev, and V. V. Lunin, Russ. J. Phys. Chem. A 94, 526 (2020).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by G. Levit
Rights and permissions
About this article
Cite this article
Mamleeva, N.A., Kharlanov, A.N. & Lunin, V.V. Features of Lignin Destruction in Wood under the Action of Ozone. Russ. J. Phys. Chem. 94, 1780–1785 (2020). https://doi.org/10.1134/S0036024420090186
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024420090186