Skip to main content
SpringerLink
Log in

Fabrication of Au–Pd NPs@CNSs/GO Nanocomposites and Their High Catalytic Properties

  • CHEMICAL KINETICS AND CATALYSIS
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

Au–Pd NPs@CNSs/GO nanocomposites have been fabricated by the in situ growth of Au–Pd nanoparticles on carbon nanospheres (CNSs) using ascorbic acid as reducing agent and diethylenetriamine (DETA) as a coupling linker and the subsequent assembly of the Au–Pd NPs@CNSs on graphene oxide (GO). In the nanocomposites, the Au–Pd NPs alloys have an average particle diameter of less than 10 nm. The nanocomposites show excellent catalytic activity for methylene blue with a high degradation efficiency above 99% in the presence of NaBH4 in aqueous solution, which is attributed to the effects of Au–Pd NPs alloys in the nanocomposites. In addition, the catalyst exhibits good selectivity for methylene blue in the presence of other organic dyes. Meanwhile, the catalytic activity remains unchanged for nine cycles. Such features ensure a very promising application of nanocomposites in the selective degradation of methylene blue in dyes mixtures.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1.
Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.

Similar content being viewed by others

REFERENCES

  1. J. Liu, D. Guo, Y. Zhou, Z. Wu, W. Li, F. Zhao, and X. Zheng, J. Archaeol. Sci. 385, 1763 (2011).

    Article  Google Scholar 

  2. M. A. Ahmed, E. E. El-Katori, and Z. H. Gharni, J. Alloys Compd. 553, 19 (2013).

    Article  CAS  Google Scholar 

  3. R. D. Combes and R. B. Havelandsmith, Mutat. Res. 98, 101 (1982).

    Article  CAS  Google Scholar 

  4. A. S. Alzaydien, Am. J. Environ. Sci. 5, 197 (2009).

    Article  CAS  Google Scholar 

  5. L. Liu, Y. Z. Wan, Y. D. Xie, R. Zhai, B. Zhang, and J. D. Liu, Chem. Eng. J. 187, 210 (2012).

    Article  CAS  Google Scholar 

  6. T. Ito, Y. Adachi, Y. Yamanashi, and Y. Shimada, Water Res. 100, 458 (2016).

    Article  CAS  Google Scholar 

  7. T. Varadavenkatesan, R. Selvaraj, and R. Vinayagam, J. Mol. Liq. 221, 1063 (2016).

    Article  CAS  Google Scholar 

  8. X. Chen, G. Wu, J. Chen, X. Chen, Z. Xie, and X. Wang, J. Am. Chem. Soc. 133, 3693 (2011).

    Article  CAS  Google Scholar 

  9. N. A. M. Barakat, K. A. Khalil, L. H. Mahmoud, M. A. Kanjwal, F. A. Sheikh, and H. Y. Kim, J. Phys. Chem. C. 114, 15589 (2010).

    Article  CAS  Google Scholar 

  10. C. M. Cobley, J. Chen, E. C. Cho, L. V. Wang, and Y. Xia, Chem. Soc. Rev. 40, 44 (2011).

    Article  CAS  Google Scholar 

  11. B. Lim, M. Jiang, J. Tao, P. H. C. Camargo, Y. Zhu, and Y. Xia, Adv. Funct. Mater. 19, 189 (2009).

    Article  CAS  Google Scholar 

  12. Y. Deng, Y. Cai, Z. Sun, J. Liu, C. Liu, J. Wei, W. Li, C. Liu, Y. Wang, and D. Zhao, J. Am. Chem. Soc. 132, 8466 (2010).

    Article  CAS  Google Scholar 

  13. B. Lim, M. Jiang, P. H. C. Camargo, E. C. Cho, J. Tao, X. Zhu, and Y. Xia, Science (Washington, DC, U. S.) 324 (5932), 1302 (2009).

    Article  CAS  Google Scholar 

  14. L. Kuai, B. Geng, S. Wang, and Y. Sang, Chem.-Eur. J. 18, 9423 (2012).

    Article  CAS  Google Scholar 

  15. W. He, X. Wu, J. Liu, X. Hu, K. Zhang, S. Hou, W. Zhou, and S. Xie, Chem. Mater. 22, 2988 (2010).

    Article  CAS  Google Scholar 

  16. P. Zhang, Z. A. Qiao, and S. Dai, Chem. Commun. 51, 9246 (2015).

    Article  CAS  Google Scholar 

  17. M. Asad and M. H. Sheikhi, Sens. Actuators, B 198, 134 (2014).

    Article  CAS  Google Scholar 

  18. T. R. Rashid, D. T. Phan, and G. S. Chung, Sens. Actuators, B 185, 777 (2013).

    Article  CAS  Google Scholar 

  19. T. Gan, Z. Lv, N. Liu, Z. X. Shi, J. Y. Sun, and Y. M. Liu, J. Electrochem. Soc. 162, H200 (2015).

    Article  CAS  Google Scholar 

  20. Y. Lu, N. Zhang, Q. Zhao, J. Liang, and J. Chen, Nanoscale 7, 2770 (2015).

    Article  CAS  Google Scholar 

  21. H. Xiong, L. L. Jewell, and N. J. Coville, ACS Catal. 5, 2640 (2015).

    Article  CAS  Google Scholar 

  22. H. Xiong, M. A. M. Motchelaho, M. Moyo, L. L. Jewell, and J. N. Coville, J. Catal. 278, 26 (2011).

    Article  CAS  Google Scholar 

  23. X. Wang, L. Zhi, and K. Muellen, Nano Lett. 8, 323 (2008).

    Article  CAS  Google Scholar 

  24. P. Sun, S. Kuga, M. Wu, and Y. Huang, Cellulose 1, 2469 (2014).

    Article  Google Scholar 

  25. C. T. J. Low, F. C. Walsh, M. H. Chakrabarti, M. A. Hashim, and Hussain, Carbon 54, 1 (2013).

    Article  CAS  Google Scholar 

  26. K. Parvez, Z. S. Wu, and R. J. Li, J. Am. Chem. Soc. 136, 6083 (2014).

    Article  CAS  Google Scholar 

  27. W. S. Hummer and R. E. Offeman, J. Am. Chem. Soc. 80, 1339 (1958).

    Article  Google Scholar 

  28. J. Liu, X. Huo, T. R. Li, Z. Y. Yang, P. X. Xi, and B. D. Wang, Chem.-Eur. J. 20, 11549 (2014).

    Article  CAS  Google Scholar 

  29. Y. W. Lee, M. Kim, Z. H. Kim, and S. W. Han, J. Am. Chem. Soc. 131, 17036 (2009).

    Article  CAS  Google Scholar 

  30. H. Chen, Y. Li, G. Zhang, and X. Fan, J. Mater. Chem. 21, 17658 (2011).

    Article  CAS  Google Scholar 

  31. S. Tang, Y. Tang, S. Vongehr, X. Zhao, and X. Meng, Appl. Surf. Sci. 255, 6011 (2009).

    Article  CAS  Google Scholar 

  32. B. Lim, H. Kobayashi, T. Yu, J. Wang, M. J. Kim, Z. Li, M. Rycenga, and Y. Xia, J. Am. Chem. Soc. 132, 2506 (2010).

    Article  CAS  Google Scholar 

  33. Z. Jin, D. Nackashi, W. Lu, C. Kittrell, and J. M. Tour, Chem. Mater. 22, 5695 (2010).

    Article  CAS  Google Scholar 

Download references

ACKNOWLEDGMENTS

The work was supported by the National Natural Science Foundation of China (21761019).

Author information

Authors and Affiliations

  1. School of Petrochemical Engineering, Lanzhou University of Technology, 730050, Lanzhou, China

    Ce Su, Xuelian Huang, Qili Wang, Zhaoyang Shang, Yunbiao Wei, Guanbin Li & Siliang Li

Authors
  1. Ce Su
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Xuelian Huang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Qili Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Zhaoyang Shang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yunbiao Wei
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Guanbin Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Siliang Li
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Ce Su or Siliang Li.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ce Su, Huang, X., Wang, Q. et al. Fabrication of Au–Pd NPs@CNSs/GO Nanocomposites and Their High Catalytic Properties. Russ. J. Phys. Chem. 94, 1804–1810 (2020). https://doi.org/10.1134/S0036024420090277

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024420090277

Keywords:

Search

Navigation