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AnSen (An = Th, U, Np, Pu, Am, or Cm) Coordination Polyhedra in Crystal Structures

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Abstract

Voronoi–Dirichlet (VD) polyhedra have been used to make a crystal-chemical analysis of compounds containing in their crystal structure coordination polyhedra AnSen (An = Th, U, Np, Pu, Am, or Cm). It was found that atoms An(II), An(III), An(IV), and An(V) occur in selenides. These atoms coordinate from 6 to 10 selenium atoms in the form of Se2– or Se–. It was shown that the VD polyhedra make it possible to determine the valence state of An atoms in structures of crystalline substances and reveal errors in the crystal-structural information. A dependence of the multiplicity of Se–Se bonds on their length in 0D, 1D, and 2D groups composed of only selenium atoms was determined.

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REFERENCES

  1. Gaunt, A.J., Reilly, S.D., Enriquez, A.E., Scott, B.L., Ibers, J.A., Sekar, P., Ingram, K.I.M., Kaltsoyannis, N., and Neu, M.P., Inorg. Chem., 2008, vol. 47, no. 1, p. 29. https://doi.org/10.1021/ic701618a

    Article  CAS  PubMed  Google Scholar 

  2. Jones, M.B., Gaunt, A.J., Gordon, J.C., Kaltsoyannis, N., Neu, M.P., and Scott, B.L., Chem. Sci., 2013, vol. 4, no. 3, p. 1189. https://doi.org/10.1039/C2SC21806B

    Article  CAS  Google Scholar 

  3. Behrle, A.C., Kerridge, A., and Walensky, J.R., Inorg. Chem., 2015, vol. 54, no. 24, p. 11625. https://doi.org/10.1021/acs.inorgchem.5b01342

    Article  CAS  PubMed  Google Scholar 

  4. Macor, J.A., Brown, J.L., Cross, J.N., Daly, S.R., Gaunt, A.J., Girolami, G.S., Janicke, M.T., Kozimor, S.A., Neu, M.P., Olson, A.C., Reilly, S.D., and Scott, B.L., Dalton Trans., 2015, vol. 44, no. 43, p. 18923. https://doi.org/10.1039/C5DT02976G

    Article  CAS  PubMed  Google Scholar 

  5. Cross, J.N., Macor, J.A., Berte, J.A., Ferrier, M.G., Girolami, G.S., Kozimor, S.A., Maassen, J.R., Scott, B.L., Shuh, D.K., Stein, B.W., and Stieber, S.C.E., Angew. Chem., Int. Ed., 2016, vol. 55, no. 41, p. 12755. https://doi.org/10.1002/anie.201606367

    Article  CAS  Google Scholar 

  6. Wells, A.F., Structural Inorganic Chemistry, Oxford: Clarendon, 1986.

    Google Scholar 

  7. Vainshtein, B.K., Fridkin, V.M., and Indenbom, V.L., Struktura kristallov (Structure of Crystals), Moscow: Nauka, 1979.

    Google Scholar 

  8. Bugaris, D.E., Copping, R., Tyliszczak, T., Shuh, D.K., and Ibers, J.A., Inorg. Chem., 2010, vol. 49, no. 5, p. 2568. https://doi.org/10.1021/ic902503n

    Article  CAS  PubMed  Google Scholar 

  9. Bugaris, D.E., Wells, D.M., Jiyong, Yao, Skanthakumar, S., Haire, R.G., Soderholm, L., and Ibers, J.A., Inorg. Chem., 2010, vol. 49, no. 18, p. 8381. https://doi.org/10.1021/ic1008895

    Article  CAS  PubMed  Google Scholar 

  10. Ward, M.D., Mesbah, A., Minasian, S.G., Shuh, D.K., Tyliszczak, T., Lee, M., Choi, E.S., Lebègue, S., and Ibers, J.A., Inorg. Chem., 2014, vol. 53, no. 13, p. 6920. https://doi.org/10.1021/ic500721d

    Article  CAS  PubMed  Google Scholar 

  11. Mesbah, A., Prakash, J., Beard, J.C., Lebègue, S., Malliakas, C.D., and Ibers, J.A., Inorg. Chem., 2015, vol. 54, no. 18, p. 9138. https://doi.org/10.1021/acs.inorgchem.5b01566

    Article  CAS  PubMed  Google Scholar 

  12. Mesbah, A., Prakash, J., and Ibers, J.A., Dalton Trans., 2016, vol. 45, no. 41, p. 16067. https://doi.org/10.1039/C6DT02540D

    Article  CAS  PubMed  Google Scholar 

  13. Jin Geng Bang, Hu Yung-Jin, Bellott, B., Skanthakumar, S., Haire, R.G., Soderholm, L., and Ibers, J.A., Inorg. Chem., 2013, vol. 52, no. 15, p. 9111. https://doi.org/10.1021/ic401384t

    Article  CAS  PubMed  Google Scholar 

  14. Inorganic Crystal Structure Database, Gmelin-Institut für Anorganische Chemie & FIC Karlsruhe, 2018.

  15. Cambridge Structural Database System, Cambridge Crystallographic Data Centre, 2018.

  16. Serezhkin, V.N., Savchenkov, A.V., Pushkin, D.V., and Serezhkina, L.B., Appl. Solid State Chem., 2018, vol. 2(3), p. 2. https://doi.org/10.18572/2619-0141-2018-2-3-2-16

    Article  Google Scholar 

  17. Serezhkin, V.N. and Serezhkina, L.B., Radiochemistry, 2018, vol. 60, no. 1, p. 3. https://doi.org/10.1134/S1066362218010010

    Article  Google Scholar 

  18. Serezhkin, V.N., Pushkin, D.V., and Serezhkina, L.B., Radiochemistry, 2018, vol. 60, no. 3, p. 193. https://doi.org/10.1134/S1066362218030013

    Article  Google Scholar 

  19. Serezhkin, V.N. and Serezhkina, L.B., Radiochemistry, 2018, vol. 60, no. 4, p. 289. https://doi.org/10.1134/S106636221804001X

    Article  Google Scholar 

  20. Serezhkin, V.N., Mikhailov, Yu.N., and Buslaev, Yu.A., Zh. Neorg. Khim., 1997, vol. 42, no. 12, p. 203.

    CAS  Google Scholar 

  21. Serezhkin, V.N., Structural Chemistry of Inorganic Actinide Compounds, Krivovichev, S.V., Burns, P.C., and Tananaev, I.G., Eds., Amsterdam: Elsevier, 2007.

    Google Scholar 

  22. Serezhkin, V.N., Medvedkov, Ya.A., Serezhkina, L.B., and Pushkin, D.V., Russ. J. Phys. Chem. A, 2015, vol. 89, no. 6, p. 1018. https://doi.org/10.1134/S0036024415060254

    Article  CAS  Google Scholar 

  23. Mesbah, A., Prakash, J., Beard, J.C., Pozzi, E.A., Tarasenko, M.S., Lebègue, S., Malliakas, C.D., Van Duyne, R.P.,and Ibers, J.A., Inorg. Chem., 2015, vol. 54, no. 6, p. 2851. https://doi.org/10.1021/ic5029806

    Article  CAS  PubMed  Google Scholar 

  24. Oh, G.N., Choi, E.S., and Ibers, J.A., Inorg. Chem. 2012, vol. 51, p. 4224. https://doi.org/10.1021/ic202704

    Article  CAS  PubMed  Google Scholar 

  25. Marcon, J.P. and Pascard, R., J. Inorg. Nucl. Chem., 1966, vol. 28, p. 2551. https://doi.org/10.1016/0022-1902(66)80379-2

    Article  CAS  Google Scholar 

  26. Wells, D.M., Skanthakumar, S., and Soderholm, L., Acta Crystallogr., Sect. E, 2009, vol. 65, no. 3, p. i14. https://doi.org/10.1107/S160053680900395X

    Article  CAS  Google Scholar 

  27. Prakash, J., Tarasenko, M.S., Mesbah, A., Lebègue, S., Malliakas, C.D., and Ibers, J.A., Inorg. Chem., 2014, vol. 53, no. 21, p. 11626. https://doi.org/10.1021/ic501795w

    Article  CAS  PubMed  Google Scholar 

  28. Chan, B.C., Hulvey, Z., Abney, K.D., and Dorhout, P.K., Inorg. Chem., 2004, vol. 43, no. 8, p. 2453. https://doi.org/10.1021/ic0353209

    Article  CAS  PubMed  Google Scholar 

  29. Olsen, J.S., Gerward, L., Benedict, U., Luo, H., and Vogt, O., High Temp.-High Press., 1988, vol. 20, no. 5, p. 553.

    CAS  Google Scholar 

  30. Ellert, G.V., Kuz'micheva, G.M., Eliseev, A.A., Slovyanskikh, V.K., and Morozov, S.P., Russ. J. Inorg. Chem., 1974, vol. 19, p. 1548.

    Google Scholar 

  31. Kohlmann, H. and Beck, H.P., Z. Kristallogr., 1999, vol. 214, no. 6, p. 341. https://doi.org/10.1524/zkri.1999.214.6.341

    Article  CAS  Google Scholar 

  32. Chondroudis, K. and Kanatzidis, M.G., J. Am. Chem. Soc., 1997, vol. 119, no. 10, p. 2574. https://doi.org/10.1021/ja963673j

    Article  CAS  Google Scholar 

  33. Briggs Piccoli, P.M., Abney, K.D., Schoonover, J.D., and Dorhout, P.K., Inorg. Chem., 2001, vol. 40, no. 19, p. 4871. https://doi.org/10.1021/ic001103l

    Article  CAS  PubMed  Google Scholar 

  34. Rogers, E., Dorenbos, P., and van der Kolk, E., New J. Phys., 2011, vol. 13, p. 093038. https://doi.org/10.1088/1367-2630/13/9/093038

    Article  CAS  Google Scholar 

  35. Serezhkin, V.N., Albakajaji, M., and Serezhkina, L.B., Russ. J. Phys. Chem. A, 2019, vol. 93, no. 2, p. 288. https://doi.org/10.1134/S0036024419020250

    Article  CAS  Google Scholar 

  36. Serezhkin, V.N., Albakajaji, M., and Serezhkina, L.B., Russ. J. Inorg. Chem., 2019, vol. 64, no. 8, p. 984. https://doi.org/10.1134/S0036023619080126

    Article  CAS  Google Scholar 

  37. Cherin, P. and Unger, P., Acta Crystallogr., Sect. B, 1972, vol. 28, no. 1, p. 313. https://doi.org/10.1107/S056774087200224

    Article  CAS  Google Scholar 

  38. Marsh, R.E., Pauling, L., and McCullough, J.D., Acta Crystallogr., 1953, vol. 6, no. 1, p. 71. https://doi.org/10.1107/S0365110X53000168

    Article  CAS  Google Scholar 

  39. Foss, O. and Janickis, V., Dalton Trans., 1980, no. 4, p. 624. https://doi.org/10.1039/DT9800000624

    Article  Google Scholar 

  40. Cernosek, Z., Růzicka, A., Holubová, J., and Cernosková, E., Main Group Met. Chem., 2007, vol. 30, no. 5, p. 231. https://doi.org/10.1515/MGMC.2007.30.5.231

    Article  CAS  Google Scholar 

  41. Prakash, J., Mesbah, A., Beard, J.C., Lebègue, S., Malliakas C.D., and Ibers, J.A., J. Solid State Chem., 2015, vol. 231, no. 1, p. 163. https://doi.org/10.1016/j.jssc.2015.08.012

    Article  CAS  Google Scholar 

  42. Briggs Piccoli, P.M., Abney, K.D., Schoonover, J.R., and Dorhout, P.K., Inorg. Chem., 2000, vol. 39, no. 14, p. 2970. https://doi.org/10.1021/ic990767w

    Article  CAS  Google Scholar 

  43. Choi, K.S., Iordanidis, L., Chondroudis, K., and Kanatzidis, M.G.,Inorg. Chem., 1997, vol. 36, no. 18, p. 3804. https://doi.org/10.1021/ic970224r

    Article  CAS  Google Scholar 

  44. Noel, H., J. Inorg. Nucl. Chem., 1980, vol. 42, no. 12, p. 1715. https://doi.org/10.1016/0022-1902(80)80146-14

    Article  CAS  Google Scholar 

  45. Prakash, J., Mesbah, A., Lebegue, S., and Kanatzidis, M.G., J. Solid State Chem., 2015, vol. 230, no. 1, p. 70. https://doi.org/10.1016/j.jssc.2015.06.033

    Article  CAS  Google Scholar 

  46. Ward, M.D., Lee, M., Choi, E.S., and Ibers, J.A., J. Solid State Chem., 2015, vol. 226, no. 1, p. 307. https://doi.org/10.1016/j.jssc.2015.03.011

    Article  CAS  Google Scholar 

  47. Choi, K.-S. and Kanatzidis, M.G., Chem. Mater., 1999, vol. 11, no. 9, p. 2613. https://doi.org/10.1021/cm990320l

    Article  CAS  Google Scholar 

  48. Sutorik, A.S. and Kanatzidis, M.G., J. Am. Chem. Soc., 1991, vol. 113, no. 12, p. 7754. https://doi.org/10.1021/ja00020a043

    Article  CAS  Google Scholar 

  49. Slovyanskikh, V.K., Kuznetsov, N.T., and Gracheva, N.V., Russ. J. Inorg. Chem., 1989, vol. 34, no. 6, p. 900.

    Google Scholar 

  50. Grønvold, F., Haraldsen, H., Thurmann-Moe, T., and Tufte, T., J. Inorg. Nucl. Chem., 1968, vol. 30, no. 8, p. 2117. https://doi.org/10.1016/0022-1902(68)80206-4

    Article  Google Scholar 

  51. Ben Salem, A., Meerschaut, A., and Rouxel, J., C. R. Hebdomad. Seances Acad. Sci., Ser. 2, 1984, vol. 299, no. 10, p. 617.

    CAS  Google Scholar 

  52. Bellott, B.J., Haire, R.G., and Ibers, J., Z. Anorg. Allg. Chem., 2012, vol. 638, no. 11, p. 1777. https://doi.org/10.1002/zaac.201200214

    Article  CAS  Google Scholar 

  53. Choi, K-S., Patschke, R., Billinge, S.J.L., Waner, M.J., Dantus, M., and Kanatzidis, M.G., J. Am. Chem. Soc., 1998, vol. 120, p. 10706. https://doi.org/10.1021/ja981675t

    Article  CAS  Google Scholar 

  54. Mizoguchi, H., Gray, D., Huang, F.-Q., and Ibers, J.A., Inorg. Chem., 2006, vol. 45, no. 8, p. 3307. https://doi.org/10.1021/ic052140l

    Article  CAS  PubMed  Google Scholar 

  55. Damien, D. and Jove, J., Inorg. Nucl. Chem. Lett., 1971, vol. 7, no. 7, p. 685. https://doi.org/10.1016/0020-1650(71)80055-7

    Article  CAS  Google Scholar 

  56. Pearson, W.B., Z. Kristallogr., 1985, vol. 171, nos. 1–4, p. 23. https://doi.org/10.1524/zkri.1985.171.14.23

    Article  CAS  Google Scholar 

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Funding

The study was financially supported by the Russian Foundation for Basic Research under research project no. 19003-00048 a.

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  1. Samara National Research University named after Academician S.P. Korolev, 443011, Samara, Russia

    V. N. Serezhkin, M. Albakajaji, D. V. Pushkin & L. B. Serezhkina

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Serezhkin, V.N., Albakajaji, M., Pushkin, D.V. et al. AnSen (An = Th, U, Np, Pu, Am, or Cm) Coordination Polyhedra in Crystal Structures. Radiochemistry 62, 454–464 (2020). https://doi.org/10.1134/S1066362220040025

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