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CRYSTAL STRUCTURE OF METAL-ORGANIC FRAMEWORKS BASED ON TERBIUM AND 1,4-NAPHTHALENEDICARBOXYLIC ACID

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Abstract

The interaction of terbium nitrate pentahydrate and 1,4-naphthalenedicarboxylic acid (H2ndc) in a solvent mixture under solvothermal conditions yields two new metal-organic frameworks: ((CH3)2NH2)2[Tb3(H2O)(HCOO)(ndc)5]∙3DMF (1) and [Tb4(DMF)(NMP)6(ndc)6] (2) (ndc2– is 1,4-naphthalenedicarboxylate, DMF is N,N-dimethylformamide, NMP is N-methyl-2-pyrrolidone). The crystal structures of compounds 1 and 2 are established by the single crystal X-ray diffraction analysis. Compound 1 is a negatively charged 3D framework in which dimethyl ammonium cations act as counterions. The remaining volume available for solvent molecules is filled with DMF. Compound 2 has a dense layered structure. The luminescence spectrum contains one emission band corresponding to π*– π transitions in the ligand.

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Funding

The study was supported by the Russian Science Foundation (project No. 19-73-00169).

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Correspondence to V P Fedin.

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Barsukova, M.O., Samsonenko, D.G. & Fedin, V.P. CRYSTAL STRUCTURE OF METAL-ORGANIC FRAMEWORKS BASED ON TERBIUM AND 1,4-NAPHTHALENEDICARBOXYLIC ACID. J Struct Chem 61, 1090–1096 (2020). https://doi.org/10.1134/S0022476620070112

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  • DOI: https://doi.org/10.1134/S0022476620070112

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