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A NEW Cu(I) IODIDE COMPLEX SHOWING DEEP-RED LUMINESCENCE

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Abstract

A reaction of a [1,4-C6H4(CH2PPy3)2]Cl2 cationic ligand with CuI (MeCN, r.t.) produces an ionic [C6H4(CH2PPy3)2][C6H4(CH2PPy3Cu3I5)2] complex containing structurally unprecedented [Cu3I5]2– inorganic module in the anionic part. The title complex in the solid manifests a weak deep-red luminescence with λmax = 680 nm and lifetimes of 14 μs and 17 μs at 300 K and 77 K, respectively.

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Funding

This work was supported by the Russian Science Foundation (project No. 19-73-20196). Luminescence measurements were performed in the Center for Optical and Laser Materials Research (St. Petersburg State University, St. Petersburg, Russian Federation).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A V Artem′ev, M I Rakhmanova & K A Brylev

  2. Novosibirsk State University, Novosibirsk, Russia

    A V Artem′ev, M I Rakhmanova, K A Brylev & I Yu Bagryanskaya

  3. Vorozhtsov Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    I Yu Bagryanskaya

Authors
  1. A V Artem′ev
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  2. M I Rakhmanova
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  3. K A Brylev
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  4. I Yu Bagryanskaya
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Correspondence to A V Artem′ev.

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Artem′ev, A.V., Rakhmanova, M.I., Brylev, K.A. et al. A NEW Cu(I) IODIDE COMPLEX SHOWING DEEP-RED LUMINESCENCE. J Struct Chem 61, 1068–1071 (2020). https://doi.org/10.1134/S0022476620070082

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  • DOI: https://doi.org/10.1134/S0022476620070082

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