Abstract
The proposed relations describe the pressure of saturated and superheated vapor of simple and nonpolar substances. It is shown that the noncovalent, long-range, chemical bonding forces—the Mendeleev forces—make the dominant contribution to the energy of interaction of vapor particles. The binding energy is proportional to the critical temperature of the substance.
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Neruchev, Y.A., Bolotnikov, M.F. Supramolecular Aspects in Intermolecular Interaction. High Temp 58, 444–447 (2020). https://doi.org/10.1134/S0018151X20030141
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DOI: https://doi.org/10.1134/S0018151X20030141