Abstract
It is shown that the formation of anodic oxides in the galvanostatic mode of electrolytic anodizing of Si, SiC, and Si3N4 proceeds with the activation control of the process. It is suggested that the limiting stage of the oxidation process of these materials is the anodic reaction of the formation of intermediate monoxide SiO.
Similar content being viewed by others
REFERENCES
Mileshko, L.P., Inorg. Mater., 2009, vol. 45, no. 13, pp. 1494–1510.
Baranov, I.L., Tabulina, L.V., Stanovaya, L.S., and Rusal’skaya, T.G., Russ. J. Electrochem., 2006, vol. 42, no. 3, pp. 320–325.
Baranov, I.L., Tabulina, L.V., Stanovaya, L.S., Rusal’skaya, T.G., and Shostak, Yu.A., Russ. Microelectron., 2008, vol. 37, no. 5, pp. 302–307.
Zhang, X.G., Electrochemistry of Silicon and Its Oxide, New York: Springer-Verlag, 2001.
Mileshko, L.P. and Varzarev, Yu.N., Fiz. Khim. Obrab. Mater., 2000, no. 2, pp. 45–48.
Varzarev, Yu.N., Makharinets, A.V., and Mileshko, L.P. Fiz. Khim. Obrab. Mater., 2015, no. 3, pp. 44–48.
Gunterschulze, A. and Betz, G., Elektrolyt-Kondensatoren, Berlin: Herbert Cram, 1937.
Young, L., Anodic Oxide Films, New York: Academic, 1961.
Mileshko, L.P., Fiz. Khim. Obrab. Mater., 2004, no. 3, pp. 81–92.
Maminova, S.P. and Odynets, L.L., Elektrokhimiya, 1966, vol. 2, no. 3, pp. 346–350.
Alkhasov, S.S. and Mileshko, L.P. Fiz. Khim. Obrab. Mater., 2012, no. 6, pp. 51–53.
Vas’ko, A.T. and Kovach, S.K., Elektrokhimiya tugoplavkikh metallov (Electrochemistry of Refractory Metals), Kiev: Tekhnika, 1983.
Mileshko, L.P. and Varzarev, Yu.N., Fiz. Khim. Obrab. Mater., 2002, no. 3, pp. 38–44.
Makharinets, A.V., Varzarev, Yu.N., and Mileshko, L.P., Fiz. Khim. Obrab. Mater., 2015, no. 2, pp. 41–46.
Mileshko, L.P., Sorokin, I.N., and Chistyakov, Yu.D., Aktiviruemye protsessy tekhnologii mikroelektroniki (Activated Processes of Microelectronic Technology), Moscow: Mosk. Inst. Elektron. Tekh., 1980, pp. 29–40.
ACKNOWLEDGMENTS
I am grateful to the reviewer for helpful comments that allowed for improving the work’s quality.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare to have no conflict of interest.
Additional information
Translated by M. Myshkina
About this article
Cite this article
Mileshko, L.P. Similarity in the Kinetics and Mechanisms of Galvanostatic Anodic Oxidation of Silicon, Silicon Carbide, and Nitride. Surf. Engin. Appl.Electrochem. 56, 453–456 (2020). https://doi.org/10.3103/S1068375520040109
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S1068375520040109