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Electrokinetic Characteristics of Bismuth-Containing Materials Based on Porous Glasses

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Abstract

Bismuth-containing composite materials based on high-silica porous glasses (PGs) of various types are prepared. Their structural parameters and electrokinetic potential in 10–2 М KNO3 solutions in the pH range 1.5–8.5 are studied. The results are compared with the analogous properties of matrices not modified with bismuth oxide, as well as the pH dependence of the zeta-potential for SiO2 particles and the sols of synthesized and industrial bismuth(III) oxide. It is determined that modification of larger-pore particles not containing secondary silica with bismuth(III) oxide results in the deviation of the form of the ζ–рН dependences from those intrinsic for high-silica PG and SiO2 particles.

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ACKNOWLEDGMENTS

The authors thank M.A. Girsova for her help in the thermal treatment of the composites and I.G. Polyakova for the X-ray phase analysis of bismuth oxides. The studies were carried out using the equipment of the Resource Centers of the Research Park of St. Petersburg State University “Nanotechnologies” and “Methods of analysis of the composition of a substance.”

Funding

The work was supported by the Russian Foundation for Basic Research (project no. 18-03-01206). The samples of two-phase glass and PG were fabricated as part of a state task (0097-2019-0015) of the Grebenshchikov Institute of Silicate Chemistry of the Russian Academy of Sciences.

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Authors and Affiliations

  1. St. Petersburg State University, 199034, St. Petersburg, Russia

    A. S. Kuznetsova & L. E. Ermakova

  2. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia

    A. S. Kuznetsova, I. N. Anfimova & T. V. Antropova

Authors
  1. A. S. Kuznetsova
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  2. L. E. Ermakova
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  3. I. N. Anfimova
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  4. T. V. Antropova
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Correspondence to A. S. Kuznetsova.

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Translated by A. Muravev

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Kuznetsova, A.S., Ermakova, L.E., Anfimova, I.N. et al. Electrokinetic Characteristics of Bismuth-Containing Materials Based on Porous Glasses. Glass Phys Chem 46, 290–297 (2020). https://doi.org/10.1134/S1087659620030086

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  • DOI: https://doi.org/10.1134/S1087659620030086

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