Skip to main content
Log in

Concentration of anionic surfactants from aqueous solutions on sorbents of various nature

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The sorption isotherms of anionic surfactants (AS) from the aqueous solution on eight polar and nonpolar sorbents were obtained. The equilibrium characteristics of sorption were determined. The SV-50 activated carbon is recommended for the effective recovery of AS based on the values of maximum adsorption and concentration equilibrium constants. It has been established that, when the content of AS is much higher than the maximum permissible concentrations, adsorption proceeds via a monomolecular mechanism, and the onset of multilayer formation corresponds to half of the critical micelle concentration. A sorbent layer consisting of activated carbon SV-50 and ion exchange fiber FIBAN AK-22-1 is proposed for the concentration of AS from aqueous solutions. 0.1 M Solution of sodium sulfate is selected as a solution for elution. The concentration was carried out using sodium dodecyl sulfate as an example. An elution curve was obtained, and the characteristics of the concentration were calculated for AS. The proposed sorption extraction allows to reduce the detection limit of AS for the determination by ion-selective electrodes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. E. V. Alekseev, Fiziko-khimicheskaya ochistka stochnykh vod [Physico-Chemical Wastewater Treatment], Association of Building Construction Universities, Moscow, 2007, 248 pp. (in Russian).

    Google Scholar 

  2. P. A. Perov, Analiticheskii kontrol soderzhaniya PAV i soputstvuyushchikh komponentov v proizvodstvennykh i stochnykh vodakh [Analytical Control of the Content of Surfactants and Related Components in Industrial and Waste Water], ZNIITEneftechim, Moscow, 1990, Issue 1, 75 pp. (in Russian).

    Google Scholar 

  3. A. L. Lobachev, A. A. Kolotvin, Sorbtsionnye i khromatograficheskie protsessy [Sorbtion and Chromatography Processes], 2006, 6, 89 (in Russian).

    Google Scholar 

  4. N. M. Makarova, E. G. Kulapina, A. A. Kolotvin, E. S. Pogorelova, J. Anal. Chem. (Engl. Transl.), 2017, 72, 87.

    CAS  Google Scholar 

  5. Ya. R. Bazel, I. P. Antal, V. M. Lavra, Zh. A. Kormosh, J. Anal. Chem. (Engl. Transl.), 2014, 69, 211.

    CAS  Google Scholar 

  6. E. D. Shchukin, A. V. Pertsov, E. A. Amelina, Kolloidnaya khimiya [Colloid Chemistry], Visshaya shkola, Moscow, 2004, p. 121 (in Russian).

    Google Scholar 

  7. A. A. Kurilkin, Uspekhi khimii i khim. tekhnologii [Advances in Chemistry and Chemical Technology], 2008, 13, 54 (in Russian).

    Google Scholar 

  8. M. G. Ivanets, T. A. Savitskaya, T. N. Nevar, D. D. Grinshpan, Russ. J. Phys. Chem. A., 2012, 86, 1710.

    Article  CAS  Google Scholar 

  9. O. V. Kurenkova, G. V. Slavinskaya, Sorbtsionnye i khromatograficheskie protsessy [Sorbtion and Chromatography Processes], 2014, 14, 832 (in Russian).

    CAS  Google Scholar 

  10. Yu. A. Karbainov, E. S. Puchkovskaya, S. N. Karbainova, G. B. Slepchenko, Izv. Tomsk. Politekh. Un-ta [Bull. Tomsk Polytechnic University], 2006, 3, 118 (in Russian).

    Google Scholar 

  11. E. V. Grigorova, L. P. Bondareva, T. S. Kornienko, D. V. Ovsyannikova, Sorbtsionnye i khromatograficheskie protsessy [Sorbtion and Chromatography Processes], 2010, 10, 749 (in Russian).

    Google Scholar 

  12. N. V. Mironenko, V. F. Selemenev, Russ. J. Phys. Chem. A., 2018, 92, 2296.

    Article  CAS  Google Scholar 

  13. Russian Standard 31857-2012, Interstate Standard. Drinking Water. Methods for Determination of Surfactant Content, Standartinform, Moscow, 2014, 17 pp. (in Russian).

    Google Scholar 

  14. V. D. Yagodovsky, Adsobtsiya [Adsoption], BINOM, Laboratoriya znanii, Moscow, 2015, 219 pp. (in Russian).

    Google Scholar 

  15. A. I. Rusanov, Mitselloobrazovanie v rastvorakh poverkhnostno-aktivnykh veshchestv [Micellization in Surfactant Solutions], Khimiya, St-Petersburg, 1992, p. 77 (in Russian).

    Google Scholar 

  16. A. Ebadi, J. S. S. Mohammadzadeh, A. Khudiev, Adsorption, 2009, 15, 65.

    Article  CAS  Google Scholar 

  17. E. G. Kulapina, Obzornyi zhurnal po khimii [Review J. in Chemistry], 2013, 3, 297 (in Russian).

    Google Scholar 

  18. E. G. Kosandrovich, V. S. Soldatov, Fibrous Ion Exchangers, in Ion Exchange Technology I: Theory and Materials, Springer, New York—London, 2012, p. 299.

    Book  Google Scholar 

  19. O. S. Zueva, O. N. Makshakova, B. Z. Idiyatullin, D. A. Faizullin, N. N. Benevolenskaya, A. O. Borovskaya, E. A. Sharipova, Yu. N. Osin, V. V. Salnikov, Yu. F. Zuev, Russ. Chem. Bull., 2016, 65, 1208.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to L. P. Bondareva.

Additional information

Based on the materials of the XXI Mendeleev Congress on General and Applied Chemistry (September 9–13, 2019, St. Petersburg, Russia).

Published in Russian in Izyestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1311–1315, July, 2020.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bondareva, L.P., Prushinskaya, A.G. Concentration of anionic surfactants from aqueous solutions on sorbents of various nature. Russ Chem Bull 69, 1311–1315 (2020). https://doi.org/10.1007/s11172-020-2903-7

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-020-2903-7

Key words

Navigation