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Tetrakis(4-bromophenoxy)phthalocyanine, its metal complexes, and their sulfonated derivatives: the synthesis and spectral properties

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Abstract

Tetrakis(4-bromophenoxy)phthalocyanine and its metal complexes (M = Mg, Co, Cu, Zn) were synthesized. Sulfochlorination of these compounds followed by hydrolysis of the sulfochlorides gave tetrakis(2-sulfo-4-bromophenoxy)phthalocyanine and corresponding sulfonated metallophthalocyanines (except M = Cu). Spectral properties of the compounds synthesized were investigated. It was shown that the introduction of sulfo groups leads to a bathochromic shift of the Q-band in the absorption spectra recorded in DMF and to a hypsochromic shift of the Q-band in the absorption spectra recorded in sulfuric acid.

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Authors and Affiliations

  1. Ivanovo State University of Chemistry and Technology, 7 Sheremetevsky prosp., 153000, Ivanovo, Russian Federation

    A. S. Vashurin, T. V. Tikhomirova, A. A. Filippova, N. A. Futerman, V. E. Maizlish & Yu. S. Marfin

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  1. A. S. Vashurin
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  2. T. V. Tikhomirova
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  3. A. A. Filippova
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  4. N. A. Futerman
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  5. V. E. Maizlish
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  6. Yu. S. Marfin
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Correspondence to T. V. Tikhomirova.

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Based on the materials of the XXI Mendeleev Congress on General and Applied Chemistry (September 9–13, 2019, St. Petersburg, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1349–1354, July, 2020.

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Vashurin, A.S., Tikhomirova, T.V., Filippova, A.A. et al. Tetrakis(4-bromophenoxy)phthalocyanine, its metal complexes, and their sulfonated derivatives: the synthesis and spectral properties. Russ Chem Bull 69, 1349–1354 (2020). https://doi.org/10.1007/s11172-020-2909-1

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  • DOI: https://doi.org/10.1007/s11172-020-2909-1

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