Abstract
Unique sulfur- and carbon- doped silicon nanoparticles, as well as partially oxidized, are obtained by nanosecond laser ablation of silicon in liquid carbon disulfide. Detailed structural, chemical, and optical characterization of these particles was performed by scanning and transmission electron microscopy, IR spectroscopy, energy dispersive X-ray spectroscopy, and Raman scattering spectroscopy. It is shown that the sulfur concentration in particles is on the order of 1 at %, owing to which they demonstrate a considerable absorption in the mid-IR region.
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This work was supported by the Russian Foundation for Basic Research (project nos. 19-32-50047 and 18-29-20022), Program 14P of the Presidium of the Russian Academy of Sciences, and a grant of the Ministry of Science and Higher Education of the Russian Federation for the ITMO University (project no. 074-U01, position S.I.K).
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Nastulyavichus, A.A., Kudryashov, S.I., Smirnov, N.A. et al. Laser Formation of Colloidal Sulfur- and Carbon-Doped Silicon Nanoparticles. Opt. Spectrosc. 128, 897–901 (2020). https://doi.org/10.1134/S0030400X20070140
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DOI: https://doi.org/10.1134/S0030400X20070140