Skip to main content

Advertisement

Log in

Mineral chemistry of high-Al chromian spinel from ultramafic rocks of the Babina–Prithvipur transect, Bundelkhand Craton, central India: Implication for petrogenesis and tectonic setting

  • Published:
Journal of Earth System Science Aims and scope Submit manuscript

Abstract

Bundelkhand Craton is an important Archaean cratonic nuclei of the Central Indian Shield and comprises two greenstone complexes, i.e., the Babina–Mauranipur Greenstone Belt and the Girar–Madawara Greenstone Belt. The E–W trending Babina–Mauranipur Greenstone Belt in the central part of the craton, encloses several isolated lensoid shaped ultramafic bodies which has suffered various degrees of alteration and metamorphism. As per modal mineral analysis, the ultramafic rocks of the Babina–Prithvipur section belong to harzburgite and also contain high-Al chromian spinel along with olivine, ortho-pyroxene and amphibole. Mineral chemistry reveals that the spinels are of high Al and Cr poor variety, where Al2O3 and Cr2O3 contents range from 40.06 to 54.34 wt.% and 9.05 to 14.89 wt.%, respectively. The TiO2 content is extremely low (average ≈0.07 wt.%). The Cr# value of the spinel is <0.2, whereas Mg# ranges from 0.495 to 0.633. The forsterite contents of the olivine ranges from 86.088 to 88.105 wt.%. Average CaO and NiO contents of the olivine stand 0.03 and 0.24 wt.%, respectively. Composition of the analyzed ortho-pyroxene belongs to En84.20–87.75Wo0.15–0.39 with low CaO content of 0.080 to 0.207 wt.%. As per mineral chemistry, these harzburgite rocks of the Babina–Prithvipur section belong to mantle peridotite. Melt calculation for the spinel also suggests a least differentiated magmatic product, which is also supported by the olivine spinel mantle array diagram as all the samples are plotted within the mantle array field very close to the fertile mantle source. Low TiO2 and high Al contents of spinel also reflect the MORB type peridotite characteristics for these ultramafic rocks which probably originated from least differentiated plagioclase free mantle derived harzburgite/lherzolitic magma in a rift related spreading centre. As a whole these ultramafic rocks appear to be the remnant of the early crust that existed during the Archaean time.

This is a preview of subscription content, log in via an institution to check access.

Access this article

We’re sorry, something doesn't seem to be working properly.

Please try refreshing the page. If that doesn't work, please contact support so we can address the problem.

Institutional subscriptions

Figure 1
Figure 2
Figure 3
Figure 4
Figure 5
Figure 6
Figure 7
Figure 8
Figure 9
Figure 10
Figure 11
Figure 12
Figure 13
Figure 14

Similar content being viewed by others

References

  • Agata T and Adachi M 2014 Chrome spinel in normal MORB type greenstones from the Paleozoic–Mesozoic Minoterrane, East Takayama area, central Japan: Crystallization course with a U-turn; Island Arc. 23(1) 62–73.

    Google Scholar 

  • Ahmed A H, Arai S, Abdel-Aziz Y M and Rahimi A 2005 Spinel composition as a petrogenetic indicator of the mantle section in the Neo-proterozoic Bou Azzer ophiolite, Anti-Atlas, Morocco; Precamb. Res. 138(3–4) 225–234.

    Google Scholar 

  • Ahmed A H, Arai S and Attia A K 2001 Petrological characteristics of podiform chromitites and associated peridotites of the Pan African proterozoic ophiolite complexes of Egypt; Miner. Deposita 36 72–84.

    Google Scholar 

  • Allan J F, Sack R O and Batiza R 1988 Cr-rich spinels as petrogenetic indicators; MORB-type lavas from the Lamont seamount chain, Eastern Pacific; Am. Miner. 73(7–8) 741–753.

    Google Scholar 

  • Arai S 1987 An estimation of the least depleted spinel peridotite on the basis of olivine-spinel mantle array; N. Jb. Miner. Mh. 8 347–354.

    Google Scholar 

  • Arai S 1992 Chemistry of chromian spinel in volcanic rocks as a potential guide to magma chemistry; Miner. Mag. 56(383) 173–184.

    Google Scholar 

  • Arai S 1994 Characterization of spinel peridotites by olivine-spinel compositional relationships: Review and interpretation; Chem. Geol. 113(3–4) 191–204.

    Google Scholar 

  • Arai S and Kida M 2000 Origin of fine-grained peridotite xenoliths from Iraya volcano of Batan Island, Philippines: De-serpentinization or metasomatism at the wedge mantle beneath an incipient arc?; Island Arc. 9 458–471.

    Google Scholar 

  • Arai S, Kadoshima K and Morishita T 2006 Widespread arc-related melting in the mantle section of the northern Oman Ophiolite as inferred from detrital chromian spinels; J. Geol. Soc. 163(5) 869–879.

    Google Scholar 

  • Arai S, Okamura H, Kadoshima K, Tanaka C, Suzuki K and Ishimaru S 2011 Chemical characteristics of chromian spinel in plutonic rocks: Implications for deep magma processes and discrimination of tectonic setting; Island Arc. 20(1) 125–137.

    Google Scholar 

  • Balaram V, Singh S P, Satyanarayanan M and Anjaiah K V 2013 Platinum group elements geochemistry of ultramafic and associated rocks from Pindar in Madawara igneous complex, Bundelkhand massif, Central India; J. Earth Syst. Sci. 122(1) 79–91.

    Google Scholar 

  • Barnes S J 2000 Chromite in komatiites: II. Modifications during greenschist to mid-amphibolite facies metamorphism; J. Petrol. 41(3) 387–409.

    Google Scholar 

  • Barnes S J and Roeder P L 2001 The range of spinel compositions in terrestrial mafic and ultramafic rocks; J. Petrol. 42(12) 2279–2302.

    Google Scholar 

  • Basu A K 1986 Geology of parts of the Brundelkhand granite massif Central India; Rec. Geol. Surv. India 117(2) 61–124.

    Google Scholar 

  • Basu A K 2001 Some characteristics of the Precambrian crust in the northern part of central India; Geol. Surv. India, Spec. Publ. 55 181–204.

    Google Scholar 

  • Bhattacharya A R and Singh S P 2013 Proterozoic crustal scale shearing in the Bundelkhand massif with special reference to Quartz Reefs; J. Geol. Soc. India 82 474–484.

    Google Scholar 

  • Bodinier J L and Godard M 2004 Orogenic, Ophiolitic and Abyssal Peridotites; In: Treatise on Geochemistry (eds) Holland H D and Turrekian K K, Elsvier, Amsterdam, The Netherlands, 2 103–170.

  • Boudier F and Nicolas A 1985 Harzburgite and lherzolite subtypes in ophiolitic and oceanic environments; Earth Planet. Sci. Lett. 76(1–2) 84–92.

    Google Scholar 

  • Cookenboo H O, Bustin R M and Wilks K R 1997 Detrital chromian spinel compositions used to reconstruct the tectonic setting of provenance: Implications for orogeny in the Canadian Cordillera; J. Sedim. Res. 67(1) 116–123.

    Google Scholar 

  • Debari S, Mahlburg Kay S and Kay R W 1987 Ultramafic Xenoliths from Adagdak Volcano, Adak, Aleutian Islands, Alaska: Deformed igneous cumulates from the Moho of an Island Arc; J. Geol. 95 329–341.

    Google Scholar 

  • De Hoog J, Gall L and Cornell D H 2010 Trace-element geochemistry of mantle olivine and application to mantle petrogenesis and geothermobarometry; Chem. Geol. 270(1) 196–215.

    Google Scholar 

  • Dick H J B 1989 Abyssal peridotites, very slow spreading ridges and ocean ridge magmatism; Geol. Soc. Lond., Spec. Publ. 42(1) 71–105.

  • Dick H J and Bullen T 1984 Chromian spinel as a petrogenetic indicator in Abyssal and Alpine-type peridotites and spatially associated lavas; Contrib. Miner. Petrol. 86(1) 54–76.

    Google Scholar 

  • Dilek Y and Polat A 2008 Supra subduction zone ophiolites and Archean tectonics; Geology 36(5) 431–432.

    Google Scholar 

  • Droop G T R 1987 A general equation for estimating Fe3+ concentrations in ferromagnesian silicates and oxides from microprobe analyses, using stoichiometric criteria; Miner. Mag. 51(361) 431–435.

    Google Scholar 

  • Fabries J 1979 Spinel-olivine geothermometry in peridotites from ultramafic complexes; Contrib. Miner. Petrol. 69(4) 329–336.

    Google Scholar 

  • Farooqui S A and Singh A K 2006 Platinum mineralization in Ikauna area, Lalitpur district, Uttar Pradesh; J. Geol. Soc. India 68(4) 582–584.

    Google Scholar 

  • Franz L and Wirth R 2000 Spinel inclusions in olivine of peridotite xenoliths from TUBAF seamount (Bismarck Archipelago/Papua New Guinea): Evidence for the thermal and tectonic evolution of the oceanic lithosphere; Contrib. Miner. Petrol. 140(3) 283–295.

    Google Scholar 

  • Furuyarna K, Hari K R and Santosh M 2001 Crystallization history of primitive Beccan Basalt from Pavagadh Hill, Gujarat, Western India; Gondwana Res. 4(3) 427–436.

    Google Scholar 

  • Hellebrand E, Snow J E and Mühe R 2002 Mantle melting beneath Gakkel Ridge (Arctic Ocean): Abyssal peridotite spinel compositions; Chem. Geol. 182(2–4) 227–235.

    Google Scholar 

  • Hellebrand E, Snow J E, Dick H J and Hofmann A W 2001 Coupled major and trace elements as indicators of the extent of melting in mid-ocean-ridge peridotites; Nature 410(6829) 677–681.

    Google Scholar 

  • Himmelberg G R and Loney R A 1995 Characteristics and petrogenesis of Alaskan-type ultramafic–mafic intrusions, southeastern Alaska; US Government Printing Office 56.

  • Irvine T N 1965 Chromian spinel as a petrogenetic indicator. Part 1: Theory; Can. J. Earth Sci. 2(6) 648–672.

    Google Scholar 

  • Irvine T N 1967 Chromian spinel as a petrogenetic indicator. Part 2: Petrologic Applications; Can. J. Earth Sci. 4(1) 71–103.

    Google Scholar 

  • Ishii T, Robinson P T, Maekawa H and Fiske R 1992 Petrological studies of peridotites from diapiric serpentinite seamounts in the Izu–Ogasawara–Mariana Forearc, Leg 125; In: Proceedings of the Ocean Drilling Program, Scientific Results (eds) Fryer P, Pearce J A and Stokking L B; Ocean Drilling Program, College Station 125 445–485.

  • Jaques A L and Green D H 1980 Anhydrous melting of peridotite at 0–15 kb pressure and the genesis of tholeiitic basalts; Contrib. Miner. Petrol. 73(3) 287–310.

    Google Scholar 

  • Joshi K B, Bhattacharjee J, Rai G, Halla J, Ahmad T, Kurhila M, Heilimo E and Choudhary A K 2017 The diversification of granitoids and plate tectonic implications at the Archaean–Proterozoic boundary in the Bundelkhand Craton, central India; Geol. Soc. Lond., Spec. Publ. 449(1) 123–157.

    Google Scholar 

  • Kamentsky V S, Crawford A J and Meffre S 2001 Factors controlling chemistry of magmatic spinel: An empirical study of associated olivine, Cr-spinel and melt inclusions from primitive rocks; J. Petrol. 42(4) 655–671.

    Google Scholar 

  • Kaur P, Zeh A and Chaudhri N 2014 Characterisation and U–Pb–Hf isotope record of the 3.55 Ga felsic crust from the Bundelkhand Craton, northern India; Precamb. Res. 255 236–244.

    Google Scholar 

  • Kaur P, Zeh A, Chaudhri N and Eliyas N 2016 Unravelling the record of Archaean crustal evolution of the Bundelkhand Craton, northern India using U–Pb zircon–monazite ages, Lu–Hf isotope systematics, and whole-rock geochemistry of granitoids; Precamb. Res. 281 384–413.

    Google Scholar 

  • Liipo J, Vuollo J, Nykänen V, Piirainen T, Pekkarinen L and Tuokko I 1995 Chromites from the early Proterozoic Outokumpu–Jormuaophiolite belt: A comparison with chromites from Mesozoic ophiolites; Lithos 36(1) 15–27.

    Google Scholar 

  • Malviya V P, Arima M, Pati J K and Kaneko Y 2006 Petrology and geochemistry of metamorphosed basaltic pillow lava and basaltic komatiite in the Mauranipur area: Subduction related volcanism in the Archean Bundelkhand craton, Central India; J. Miner. Petrol. Sci. 101(4) 199–217.

    Google Scholar 

  • Michael P J and Bonatti E 1985 Peridotite composition from the North Atlantic: Regional and tectonic variations and implications for partial melting; Earth Planet. Sci. Lett. 73(1) 91–104.

    Google Scholar 

  • Mohan M R, Singh S P, Santosh M, Siddiqui M A and Balaram V 2012 TTG suite from the Bundelkhand craton, Central India: Geochemistry, petrogenesis and implications for Archean crustal evolution; J. Asian Earth Sci. 58 38–50.

    Google Scholar 

  • Mohanty N, Singh S P, Satyanarayanan M, Jayananda M, Korakoppa M M and Hiloidari S 2019 Chromian spinel compositions from Madawara ultramafics, Bundelkhand Craton: Implications on petrogenesis and tectonic evolution of the southern part of Bundelkhand Craton, central India; Geol. J. 54(4) 2099–2123.

    Google Scholar 

  • Mondal M E A, Goswami J N, Deomurari M P and Sharma K K 2002 Ion microprobe 207Pb/206Pb ages of zircons from the Bundelkhand massif, northern India: Implications for crustal evolution of the Bundelkhand–Aravalli protocontinent; Precamb. Res. 117(1–2) 85–100.

    Google Scholar 

  • Morimoto N, Fabries J, Fergusson A K, Ginzburg I V, Ross M, Seifert F A, Zussman J, Aoki K and Gottard G 1988 Nomenclature of pyroxenes; Am. Miner. 73 1123–1133.

    Google Scholar 

  • Naqvi S M and Rogers J J W 1987 Precambrian Geology of India; Oxford Univ. Press, New York, 223p.

    Google Scholar 

  • Niu Y and Hekinian R 1997 Spreading-rate dependence of the extent of mantle melting beneath ocean ridges; Nature 385(6614) 326.

    Google Scholar 

  • Ohara Y and Ishii T 1998 Peridotites from the southern Mariana forearc: Heterogeneous fluid supply in mantle wedge; Island Arc. 7(3) 541–558.

    Google Scholar 

  • Ozawa K 1983 Evaluation of olivine-spinel geothermometry as an indicator of thermal history for peridotites; Contrib. Miner. Petrol. 82(1) 52–65.

    Google Scholar 

  • Ozawa K 1988 Ultramafic tectonite of the Miyamori ophiolitic complex in the Kitakami Mountains, Northeast Japan: Hydrous upper mantle in an Island arc; Contrib. Miner. Petrol. 99(2) 159–175.

    Google Scholar 

  • Pal T 2011 Petrology and geochemistry of the Andaman ophiolite: Melt–rock interaction in a suprasubduction-zone setting; J. Geol. Soc. Lond. 168(4) 1031–1045.

    Google Scholar 

  • Pandey U K, Sastry D V L N, Pandey B K, Roy M, Rawat T P S, Ranjan R and Shrivastava V K 2012 Geochronological (Rb–Sr and Sm–Nd) studies on intrusive gabbros and dolerite dykes from parts of northern and central Indian cratons: Implications for the age of onset of sedimentation in Bijawar and Chhattisgarh basins and uranium mineralisation; J. Geol. Soc. India 79(1) 30–40.

    Google Scholar 

  • Pati J K, Patel S C, Pruseth K L, Malviya V P, Arima M, Raju S, Pati P and Prakash K 2007 Geology and geochemistry of giant quartz veins from the Bundelkhand craton, central India and their implications; J. Earth Syst. Sci. 116(6) 497.

    Google Scholar 

  • Pearce J A, Barker P F, Edwards S J, Parkinson I J and Leat P T 2000 Geochemistry and tectonic significance of peridotites from the South Sandwich arc–basin system, South Atlantic; Contrib. Miner. Petrol. 139(1) 36–53.

    Google Scholar 

  • Pradhan V R, Meert J G, Pandit M K, Kamenov G and Mondal M E A 2012 Paleomagnetic and geochronological studies of the mafic dyke swarms of Bundelkhand craton, central India: Implications for the tectonic evolution and paleogeographic reconstructions; Precamb. Res. 198 51–76.

    Google Scholar 

  • Putirka K, Ryerson F J, Perfit M and Ian Ridley W 2011 Mineralogy and composition of oceanic mantle; J. Petrol. 52(2) 279–313.

    Google Scholar 

  • Ray J S 2006 Age of the Vindhyan supergroup: A review of recent finding; J. Earth Syst. Sci. 115(1) 149–160.

    Google Scholar 

  • Raza A and Mondal M E A 2019 Geochemistry of the mafic metavolcanic rocks of Mauranipur–Babina Greenstone Belt, Bundelkhand Craton, central India: Implication for tectonic settings during the Archaean; In: Geological Evolution of the Precambrian Indian Shield (ed.) Mondal M E A, Soc. Earth Sci. Series 22 577–607.

  • Roeder P L and Campbell I H 1985 The effect of post-cumulus reactions on compositions of chrome-spinels from the Jimberlana intrusion; J. Petrol. 26 763–786.

    Google Scholar 

  • Roeder P L and Reynolds I 1991 Crystallization of chromite and chromium solubility in basaltic melts; J. Petrol. 32(5) 909–934.

    Google Scholar 

  • Rollinson H 1995 Composition and tectonic settings of chromite deposits through time; discussion; Econ. Geol. 90(7) 2091–2092.

    Google Scholar 

  • Rollinson H 2008 The geochemistry of mantle chromitites from the northern part of the Oman ophiolite: Inferred parental melt compositions; Contrib. Miner. Petrol. 156(3) 273–288.

    Google Scholar 

  • Saha L, Frei D, Gerdes A, Pati J K, Sarkar S, Patole V, Bhandari A and Nasipuri P 2016 Crustal geodynamics from the Archaean Bundelkhand craton, India: Constraints from zircon U–Pb–Hf isotope studies; Geol. Mag. 153(1) 179–192.

    Google Scholar 

  • Sarkar A, Trivedi J R, Gopalan K, Singh P N, Das A K and Paul D K 1984 Rb–Sr geochronology of the Bundelkhand granitic complex in the Jhansi–Babina–Talbehat sector, UP, India; Indian J. Earth Sci. CEISM Seminar Volume, pp. 64–72.

  • Satyanarayanan M, Singh S P, Balaram V and Niranjan M 2015 Geochemistry of the Madawara igneous complex, Bundelkhand craton, Central India: Implications for PGE metallogeny; Open Geosci. 7(1) 836–853.

    Google Scholar 

  • Seo J, Oh C W, Choi S G and Rajesh V J 2013 Two ultramafic rock types in the Hongseong area, South Korea: Tectonic significance for Northeast Asia; Lithos 175 30–39.

    Google Scholar 

  • Sharma K K and Rahman A 2000 The early Archaean–Paleoproterozoic crustal growth of the Bundelkhand Craton, Northern Indian Shield; In: Crustal Evolution and Metallogeny in the Northwestern Indian Shield, Narosa Publishing House, New Delhi, pp. 51–72.

  • Sharma R S 2009 Cratons of the Indian Shield; Springer, Berlin, Heidelberg, pp. 41–115.

    Google Scholar 

  • Sigurdsson H 1977 Spinels in leg 37 basalts and peridotites: Phase chemistry and zoning; Initial Rep. Deep Sea Drill. Proj. 37 883–891.

    Google Scholar 

  • Simkin T and Smith J V 1970 Minor-element distribution in olivine; J. Geol. 8 304–325.

    Google Scholar 

  • Singh V K and Slabunov A 2016 Two types of Archaean Supracrustal Belts in the Bundelkhand Craton, India: Geology, geochemistry, age and implication for craton crustal evolution; J. Geol. Soc. India 88 539–548.

    Google Scholar 

  • Singh S P, Balaram V, Satyanarayanan M, Sarma D S, Subramanyam K S V, Anjaiah K V and Kharia A 2011 Platinum group minerals from the Madawara ultramafic–mafic complex, Bundelkhand massif, Central India: A preliminary note; J. Geol. Soc. India 78 281–283.

    Google Scholar 

  • Singh S P, Singh M M, Srivastava G S and Basu A K 2007 Crustal evolution in Bundelkhand area, Central India; J. Him. Geol. 28 79–101.

    Google Scholar 

  • Singh S P, Subramanyam K S V, Manikyamba C, Santosh M, Singh M R and Kumar B C 2018 Geochemical systematics of the Mauranipur–Babina greenstone belt, Bundelkhand Craton, central India: Insights on Neoarchean mantle plume-arc accretion and crustal evolution; Geosci. Front. 9(3) 769–788.

    Google Scholar 

  • Singh V K and Slabunov A 2013 The Greenstone belts of the Bundelkhand craton, central India: new geochronological data and geodynamic setting. In: International Association for Gondwana Research Conference Series, 3rd International Conference Precambrian Continental Growth and Tectonism, Jhansi, India, 16 170–171.

  • Singh V K and Slabunov A 2015 The Central Bundelkhand Archaean greenstone complex, Bundelkhand craton, central India: Geology, composition, and geochronology of supracrustal rocks; Int. Geol. Rev. 57(11–12) 1349–1364.

    Google Scholar 

  • Stevens R E 1944 Composition of some chromites of the western hemisphere; Am. Miner. J. Earth Planet. Mat. 29(1–2) 1–34.

    Google Scholar 

  • Streckeisen A 1976 To each plutonic rock its proper name; Earth-Sci. Rev. 12(1) 1–33.

    Google Scholar 

  • Suita F T M and Strieder A J 1996 Cr-Spinels from Brazilian mafic–ultramafic complexes: metamorphic modifications; Int. Geol. Rev. 38(3) 245–267.

    Google Scholar 

  • Takahashi E 1986 Origin of basaltic magmas-implications from peridotite melting experiments and olivine fractionation model; Bull. Volcanol. Soc. Jpn. 30 17–S40.

    Google Scholar 

  • Thomas H, Verma C B, Jain Anjali and Ackerman L 2019 Spinel chemistry from Madawara mafic–ultramafic complex, Lalitpur District, Uttar Pradesh, India; J. Nepal Geol. Soc. 58 53–59.

    Google Scholar 

  • Verma S K, Verma S P, Oliveira E P, Singh V K and Moreno J A 2016 LA-SF-ICP-MS zircon U–Pb geochronology of granitic rocks from the central Bundelkhand greenstone complex, Bundelkhand craton, India; J. Asian Earth Sci. 118 125–137.

    Google Scholar 

  • Whitney D L and Evans B W 2010 Abbreviations for rock forming minerals; Am. Miner. 95 185–187.

    Google Scholar 

  • Zaeimnia F, Arai S and Mirmohammadi M 2017 Na-rich character of metasomatic/metamorphic fluids inferred from preiswerkite in chromitite pods of the Khoyophiolite in Iran: Role of chromitites as capsules of trapped fluids; Lithos 268 351–363.

    Google Scholar 

  • Zhou M F, Robinson P T and Bai W J 1994 Formation of podiform chromitites by melt/rock interaction in the upper mantle; Miner. Deposita 29(1) 98–101.

    Google Scholar 

Download references

Acknowledgements

The authors are thankful to the Director, National Institute of Technology, Raipur for providing necessary facilities to carry out this work. The first author (AS) is thankful to NIT, Raipur for the financial assistance in the form of Institutional Fellowship. Prof. N V Chalapathi Rao is also acknowledged for extending the EPMA facility. The authors are thankful to Dr K R Hari for guidance and constant encouragement. Thanks are also due to anonymous reviewers for their constructive comments and valuable suggestions which improved the manuscript.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Neeraj Vishwakarma.

Additional information

Communicated by N V Chalapathi Rao

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sahu, A., Vishwakarma, N., Singh, Y. et al. Mineral chemistry of high-Al chromian spinel from ultramafic rocks of the Babina–Prithvipur transect, Bundelkhand Craton, central India: Implication for petrogenesis and tectonic setting. J Earth Syst Sci 129, 182 (2020). https://doi.org/10.1007/s12040-020-01448-3

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s12040-020-01448-3

Keywords

Navigation