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Licensed Unlicensed Requires Authentication Published by De Gruyter August 26, 2020

Single-crystal investigation of Ce5AgxGe4−x (x = 0.1−1.08) with Sm5Ge4 type

  • Bohdana Belan , Dorota Kowalska , Mariya Dzevenko EMAIL logo , Mykola Manyako and Roman Gladyshevskii

Abstract

The crystal structure of the phase Ce5AgxGe4−x (x = 0.1−1.08) has been determined using single-crystal X-ray diffraction data for Ce5Ag0.1Ge3.9. This phase is isotypic with Sm5Ge4: space group Pnma (No. 62), Pearson code oP36, Z = 4, a = 7.9632(2), b = 15.2693(5), c = 8.0803(2) Å; R1 = 0.0261, wR2 = 0.0460, 1428 F2 values and 48 variables. The two crystallographic positions 8d and 4c show Ge/Ag mixing, leading to a slight increase in the lattice parameters as compared to those of the pure binary compound Ce5Ge4.


Corresponding author: Mariya Dzevenko, Chemical Faculty, Ivan Franko National University of Lviv, Kyryla i Mefodiya Street 6, UA-79005 Lviv, Ukraine, E-mail:

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2020-05-27
Accepted: 2020-07-14
Published Online: 2020-08-26
Published in Print: 2020-09-25

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