Abstract
Present work analyzes the behavior of several gas-liquid-liquid systems for carbon dioxide separation using chemical absorption. The type of amine center in a solvent with two liquid phases (organic and aqueous) shows a high importance in relation to the overall behavior. The experimental results for these solvents have been compared with a previous study using octylamine in the chemical solvent because it has shown suitable results for carbon dioxide loading, absorption rate and energy cost associated to solvent regeneration. Present study analyzes the carbon dioxide absorption mechanism in multiphasic reactors (specifically G-L-L) using different types of amines in order to understand the overall behavior that involves steps of mass transfer and chemical reaction.
Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
Research funding: None declared.
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
References
Azhgan, M., M. Farsi, and R. Eslamloueyan. 2016. “Solubility of Carbon Dioxide in Aqueous Solution of 1,5-Diamino-2-Methylpentane: Absorption and Desorption Property.” International Journal of Greenhouse Gas Control 51: 409–14, https://doi.org/10.1016/j.ijggc.2016.05.014.Search in Google Scholar
Barzagli, F., F. Mani, and M. Peruzzini. 2017. “Novel Water-free Biphasic Absorbents for Efficient CO2 Capture.” International Journal of Greenhouse Gas Control 60: 100–9, https://doi.org/10.1016/j.ijggc.2017.03.010.Search in Google Scholar
Benítez, J. J., M. A. San-Miguel, S. Domínguez-Meister, J. A. Heredia-Guerrero, and M. Salmeron. 2011. “Structure and Chemical State of Octadecylamine Self-Assembled Monolayers on Mica.” Journal of Physical Chemistry C 115: 19716–23, https://doi.org/10.1021/jp203871g.Search in Google Scholar
Bonenfant, D., M. Mimeault, and R. Hausler. 2005. “Comparative Analysis of the Carbon Dioxide Absorption and Recuperation Capacities in Aqueous 2-(2-aminoethylamino)ethanol (AEE) and Blends of Aqueous AEE and N-Methyldiethanolamine Solutions.” Industrial and Engineering Chemistry Research 44: 3720–5, https://doi.org/10.1021/ie040253r.Search in Google Scholar
Bougie, F., and M. C. Iliuta. 2010. “Analysis of Regeneration of Sterically Hindered Alkanolamines Aqueous Solutions with and without Activator.” Chemical Engineering Science 65: 4746–50, https://doi.org/10.1016/j.ces.2010.05.021.Search in Google Scholar
Brea, U., D. Gómez-Díaz, J. M. Navaza, and A. Rumbo, 2019. “Carbon Dioxide Chemical Absorption in Non-Aqueous Solvents by the Presence of Water.” Journal of Taiwan Institute of Chemical Engineers 102: 250–8, https://doi.org/10.1016/j.jtice.2019.06.009.Search in Google Scholar
Carrera, M., D. Gómez-Díaz, and J. M. Navaza. 2018. “Switchable Hydrophilicity Solvents for Carbon Dioxide Chemical Absorption.” Journal of Industrial and Engineering Chemistry 59: 304–9, https://doi.org/10.1016/j.jiec.2017.10.036.Search in Google Scholar
Feng, B., M. Du, T. J. Dennis, K. Anthony, and M. J. Perumal. 2010. “Reduction of Energy Requirement of CO2 Desorption by Adding Acid into CO2-loaded Solvent.” Energy & Fuels 24: 213–9, https://doi.org/10.1021/ef900564x.Search in Google Scholar
Gantert, S., and D. Möller. 2012. “Ultrasonic Desorption of CO2-a New Technology to Save Energy and Prevent Solvent Degradation.” Chemical Engineering and Technology 35: 576–8, https://doi.org/10.1002/ceat.201100395.Search in Google Scholar
Gómez-Díaz, D., and J. M. Navaza. 2008. “Carbon Dioxide Mass Transfer to Non-linear Alkanes.” Canadian Journal of Chemical Engineering 86: 719–24, https://doi.org/10.1002/cjce.20035.Search in Google Scholar
Heldebrant, D. J., P. K. Koech, J. E. Rainbolt, F. Zheng, T. Smurthwaite, C. J. Freeman, M. Oss, and I. Leito. 2011. “Performance of Single-Component CO2-binding Organic Liquids (CO2BOLs) for Post Combustion CO2 Capture.” Chemical Engineering Journal 171: 794–800.10.1016/j.cej.2011.02.012Search in Google Scholar
Kossmann, A., S. Rehfeldt, P. Moser, and H. Klein. 2015. “Process Study for Stripping Components in Absorption–Desorption Processes for CO2-Removal from Power Plant Flue Gases.” Chemical Engineering Research and Design 9: 236–47, https://doi.org/10.1016/j.cherd.2015.04.012.Search in Google Scholar
Li, J., C. You, L. Chen, Y. Ye, Z. Qi, and K. Sundmacher. 2012. “Dynamics of CO2 Absorption and Desorption Processes in Alkanolamine with Cosolvent Polyethylene Glycol.” Industrial and Engineering Chemistry Research 51: 12081–8, https://doi.org/10.1021/ie301164v.Search in Google Scholar
Lin, P. H., and D. S. H. Wong. 2014. “Carbon Dioxide Capture and Regeneration with Amine/Alcohol/Water Blends.” International Journal of Greenhouse Gas Control 26: 69–75, https://doi.org/10.1016/j.ijggc.2014.04.020.Search in Google Scholar
Ling, H., S. Liu, T. Wang, H. Gao, and Z. Liang. 2019. “Characterization and Correlations of CO2 Absorption Performance into Aqueous Amine Blended Solution of Monoethanolamine (MEA) and N,N-Dimethylethanolamine (DMEA) in a Packed Column.” Energy & Fuels 33: 7614–25, https://doi.org/10.1021/acs.energyfuels.9b01764.Search in Google Scholar
Mores, P., N. Scenna, and S. Mussati. 2012. “CO2 Capture Using Monoethanolamine (MEA) Aqueous Solution: Modeling and Optimization of the Solvent Regeneration and CO2 Desorption Process.” Energy 45: 1042–58, https://doi.org/10.1016/j.energy.2012.06.038.Search in Google Scholar
Rahimi, K., S. Riahi, M. Abbasi, and Z. Fakhroueian. 2019. “Modification of Multi-Walled Carbon Nanotubes by 1,3-Diaminopropane to Increase CO2 Adsorption Capacity.” Journal of Environmental Management 242: 81–9, https://doi.org/10.1016/j.jenvman.2019.04.036.Search in Google Scholar PubMed
Rahimi, K., S. Riahi, and M. Abbasi. 2020. “Effect of Host Fluid and Hydrophilicity of Multi-Walled Carbon Nanotubes On Stability and CO2 Absorption of Amine-Based and Water-Based Nanofluids.” Journal of Environmental Chemical Engineering 8: 103580, https://doi.org/10.1016/j.jece.2019.103580.Search in Google Scholar
Schach, M. O., R. Schneider, H. Schramm, and J. U. Repke. 2010. “Technoeconomic Analysis of Post Combustion Processes for the Capture of Carbon Dioxide from Power Plant Flue Gas.” Industrial and Engineering Chemistry Research 49: 2363–70, https://doi.org/10.1021/ie900514t.Search in Google Scholar
Um, I. H., E. J. Lee, and S. E. Jeon. 2002. “Effect of Solvent on Reactivity and Basicity: Aminolyses of P-Nitrophenyl Acetate in H2O and in DMSO.” Journal of Physical Organic Chemistry 15: 561–5, https://doi.org/10.1002/poc.483.Search in Google Scholar
Wang, Y., L. Zhao, A. Otto, M. Robinius, and D. Stolten. 2017. “A Review of Post-Combustion CO2 Capture Technologies from Coal-Fired Power Plants.” Energy Procedia 114: 650–65, https://doi.org/10.1016/j.egypro.2017.03.1209.Search in Google Scholar
Wang, L., Y. Zhang, R. Wang, Q. Li, S. Zhang, M. Li, J. Liu, and B. Chen. 2018. “Advanced Monoethanolamine Absorption Using Sulfolane as a Phase Splitter for CO2 Capture.” Environmental Science & Technology 52: 14556–63, https://doi.org/10.1021/acs.est.8b05654.Search in Google Scholar PubMed
Xu, Y., B. Jin, X. Chen, and Y. Zhao. 2019. “Performance of CO2 Absorption in a Spray Tower Using Blended Ammonia and Piperazine Solution: Experimental Studies and Comparisons.” International Journal of Greenhouse Gas Control 82: 152–61, https://doi.org/10.1016/j.ijggc.2019.01.008.Search in Google Scholar
Ye, Q., X. Wang, and Y. Lu. 2015. “Screening and Evaluation of Novel Biphasic Solvents for Energy-Efficient Post-combustion CO2 Capture.” International Journal of Greenhouse Gas Control 39: 205–14, https://doi.org/10.1016/j.ijggc.2015.05.025.Search in Google Scholar
Zhang, X. M., K. Huang, S. Xia, Y. L. Chen, Y. T. Wu, and X. B. Hu. 2015. “Low-Viscous Fluorine-Substituted Phenolic Ionic Liquids with High Performance for Capture of CO2.” Chemical Engineering Journal 274: 30–8, https://doi.org/10.1016/j.cej.2015.03.052.Search in Google Scholar
Zhang, S., Y. Shen, L. Wang, J. Chen, and Y. Lu. 2019. “Phase Change Solvents for Post-Combustion CO2 Capture: Principle, Advances, and Challenges.” Applied Energy 239: 876–97, https://doi.org/10.1016/j.apenergy.2019.01.242.Search in Google Scholar
© 2020 Walter de Gruyter GmbH, Berlin/Boston
