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Effect of the O-Alkylation of Brown Coal with n-Butanol on the Yield and Composition of Bitumoids

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Abstract

The effect of the destructive O-alkylation of the organic matter of brown coal from the Tyulgan deposit in the South Ural basin on the yield and component composition of bitumoids was studied. The positive effect of alkylation with n-butanol on an increase in the yield of aliphatic lignite bitumoid fractions was found. The process of O-alkylation was optimized in terms of the weight yield of bitumoids; a number of adequate regression equations were obtained for the dependences of the yield of bitumen fractions on the parameters of the test process. The following biologically active substances were detected in the composition of bitumoids and their fractions: ferruginol, betulin, n-tetracosanol-1, etc.

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REFERENCES

  1. Zherebtsov, S.I., Doctoral (Chem.) Dissertation, Moscow: Mendeleev Univ. Chem. Technol., 2017.

  2. Zherebtsov, S.I., Ugol’, 2009, no. 7, p. 63.

  3. Zherebtsov, S.I., Tr.nauchno-tekhnicheskoi konferentsii (Proc. Sci.-Techn. Conf.), Kemerovo: Izd. Inst. Uglya i Uglekhimii, Sib. Otd. Ross. Akad. Nauk, 1998, p. 258.

  4. Bel’kevich, P.I., Bitumy torfa i burogo uglya (Peat and Brown Coal Bituments), Minsk: Nauka i Tekhnika, 1989.

  5. Zherebtsov, S.I. and Moiseev, A.I., Solid Fuel Chem., 2009, vol. 43, no. 2. p. 71. https://doi.org/10.3103/S0361521909020037

    Article  Google Scholar 

  6. Shpakodraev, K.M., Zherebtsov, S.I., Smotrina, O.V., Malyshenko, N.V., and Ismagilov, Z.R., Khim. Interesakh Ustoich. Razvit., 2018, no. 6, p. 707.

  7. Shpakodraev, K.M., Zherebtsov, S.I., Smotrina, O.V., Malyshenko, N.V., Sotnikova, L.V., and Ismagilov, Z.R., Khim. Interesakh Ustoich. Razvit., 2019, no. 4, p. 431.

  8. Draper, N.R. and Smith, H., Applied Regression Analysis, New York: Wiley, 1998.

    Book  Google Scholar 

  9. Zherebtsov, S.I. and Ismagilov, Z.R., Solid Fuel Chem., 2012, vol. 46 no. 4. p. 241. https://doi.org/10.3103/S0361521912040131

    Article  CAS  Google Scholar 

  10. Taits, E.M. and Andreeva, I.A., Metody analiza i ispytaniya uglei (Coal Analysis and Testing Methods), Moscow: Nedra, 1983.

  11. Romanenko, V.N., Orlov, A.G., and Nikitina, G.V., Kniga dlya nachinayushchego issledovatelya khimika (Book for a Novice Chemist Researcher), Leningrad: Khimiya, 1987.

  12. Rode, V.V. and Papirova, E.A., Khim. Tverd. Topl. (Moscow), 1981, no. 6, p. 52.

  13. Structure Determination of Organic Compounds: Tables of Spectral Data, Pretsch, E. , Eds., Berlin: Springer, 2009.

    Google Scholar 

  14. Interpreting Infrared, Raman, and NMR Spectra, Nyquist, R.A., Ed., San Diego: Academic, 2001, vol. 1.

    Google Scholar 

  15. Spectrometric Identification of Organic Compounds, Silverstein, R.M., , Eds. New York: Wiley, 2005.

    Google Scholar 

  16. PubChem. https://pubchem.ncbi.nlm.nih.gov

  17. PubMed. https://pubmed.ncbi.nlm.nih.gov/

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Funding

This work was supported by the Russian Foundation for Basic Research (project no. 19-33-90079).

The study was carried out with the use of the equipment of the Center of Collective Use at the Federal Research Center of Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences.

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Authors and Affiliations

  1. Federal Research Center of Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences, 650000, Kemerovo, Russia

    K. M. Shpakodraev, S. I. Zherebtsov, N. V. Malyshenko & Z. R. Ismagilov

Authors
  1. K. M. Shpakodraev
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  2. S. I. Zherebtsov
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  3. N. V. Malyshenko
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  4. Z. R. Ismagilov
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Corresponding authors

Correspondence to K. M. Shpakodraev, S. I. Zherebtsov, N. V. Malyshenko or Z. R. Ismagilov.

Additional information

Translated by V. Makhlyarchuk

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Shpakodraev, K.M., Zherebtsov, S.I., Malyshenko, N.V. et al. Effect of the O-Alkylation of Brown Coal with n-Butanol on the Yield and Composition of Bitumoids. Solid Fuel Chem. 54, 219–227 (2020). https://doi.org/10.3103/S0361521920040059

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  • DOI: https://doi.org/10.3103/S0361521920040059

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