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Application of Nanoheterogeneous Molybdenum Sulfide Catalysts to the Hydrofining of the Semicoking Tar of Coal from the Shubarkul Deposit

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Abstract

The hydrofining of semicoking coal tar from the Shubarkul deposit (Republic of Kazakhstan) in the presence of nanoheterogeneous molybdenum sulfide catalyst systems (Mo content, 0.025–0.12%) was studied in order to intensify processing technology. The catalysts were in situ prepared in the coal tar with the addition of a sulfidizing agent—elemental sulfur in an amount of 0.03 –0.09 wt % on a raw material basis. It was found that the effective Mo content of the catalyst was 0.025%, and the amount of sulfur was 0.03%, which made it possible to obtain a maximum yield of total liquid products (76.8%), which mainly contained diesel fuel fractions, at 5 MPa and 400°C.

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Funding

This development work was supported by the Ministry of Education and Science of the Republic of Kazakhstan (project no. AR05132699).

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Correspondence to N. T. Smagulova, Zh. K. Kairbekov, A. S. Maloletnev or L. K. Kudreeva.

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Translated by V. Makhlyarchuk

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Smagulova, N.T., Kairbekov, Z.K., Maloletnev, A.S. et al. Application of Nanoheterogeneous Molybdenum Sulfide Catalysts to the Hydrofining of the Semicoking Tar of Coal from the Shubarkul Deposit. Solid Fuel Chem. 54, 214–218 (2020). https://doi.org/10.3103/S0361521920040060

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  • DOI: https://doi.org/10.3103/S0361521920040060

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