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Study of Adsorption Properties of Zeolites NaX, CaA, and CaNaA in Separation of Air Components

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Abstract

The volumetric method has been used to study the adsorption properties of zeolites CaA, NaX, and CaNaA; adsorption isotherms and adsorption capacities for nitrogen, oxygen, and air have been obtained. The nitrogen/oxygen selectivity values of zeolites have been determined. The experimental adsorption isotherm of air has been compared with the adsorption isotherm obtained for the pure components. The experiments have revealed that the most promising zeolite for use in a membrane–adsorption oxygen concentrator is zeolite CaNaA.

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REFERENCES

  1. Yu. V. Miroshnichenko, R. A. Enikeeva, and E. M. Kassu, Vestn. Ross. Voen.-Med. Akad., No. 2, 157 (2016).

  2. E. N. Ivanova, Candidate’s Dissertation in Engineering (Moscow, 2016).

  3. A. A. Tishin and V. N. Gurkin, J. Phys., Conf. Ser. 1368, 042043 (2019).

    Article  CAS  Google Scholar 

  4. D. M. Frolov, G. A. Dibrov, and G. G. Kagramanov, Usp. Khim. Khim. Tekhnol. 29 (2), 161 (2015).

    Google Scholar 

  5. Yu. I. Dytnerskii, V. P. Brykov, and G. G. Kagramanov, Membrane Gas Separation (Khimiya, Moscow, 1991) [in Russian].

    Google Scholar 

  6. M. B. Alekhina and T. V. Kon’kova, Vestn. Voronezh. Gos. Univ., Ser. Khim. Biol. Farm., No. 2, 67 (2011).

  7. V. G. Matveikin, V. A. Pogonin, S. B. Putin, and S. A. Skvortsov, Mathematical Modeling and Controlling of Pressure Swing Adsorption Process (Mashinostroenie-1, Moscow, 2007) [in Russian].

  8. Yu. V. Nikiforov, S. D. Glukhov, and A. A. Kazakova, Vestn. Mosk. Gos. Tekh. Univ., Ser. Mashinostr., No. 6, 99 (2014).

  9. S. N. Purtov and E. Yu. Tarasova, Tekh. Gazy, No. 2, 38 (2009).

    Google Scholar 

  10. E. I. Akulinin, A. A. Ermakov, D. S. Dvoretskii, and S. I. Simanenkov, Vestn. Tambov. Gos. Tekh. Univ. 14 (3) (2008).

  11. A. Yu. Okunev, Acad., Arkhitekt. Stroit., No. 5, 476 (2009).

  12. M. Suzuki, T. Suzuki, A. Sakoda, and J. Izumi, Adsorption 2, 111 (1996).

    Article  Google Scholar 

  13. S. Sircar and A. L. Myers, Handbook of Zeolite Science and Technology, Ed. by. S. M. Auerbach, K. A. Carrado, and P. K. Dutta (Marcel Dekker, New York, 2003), Ch. 22.

    Google Scholar 

  14. J. C. Santos, F. D. Magalh es, and A. Mendes, Ind. Eng. Chem. Res. 47, 6197 (2008).

    Article  CAS  Google Scholar 

  15. J. A. Mason, et al., Energy Environ. Sci. 4, 3030 (2011).

    Article  CAS  Google Scholar 

  16. N. Hedin, et al., Appl. Energy 104, 418 (2013).

    Article  CAS  Google Scholar 

  17. J. C. Santos, et al., Ind. Eng. Chem. Res. 46, 591 (2007).

    Article  CAS  Google Scholar 

  18. C. W. Skarstrom, US Patent No. 2944627 (1958).

  19. C. W. Skarstrom, US Patent No. 3237377 (1962).

  20. E. I. Akulinin, N. F. Gladyshev, and S. I. Dvoretskii, Vestn. Tambov. Gos. Tekh. Univ. 23 (1) (2017).

  21. Yu. I. Shumyatskii and Yu. M. Afanas’ev, Adsorption: A Process with Unlimited Capabilities (Vysshaya Shkola, Moscow, 1998) [in Russian].

    Google Scholar 

  22. E. I. Akulinin, Candidate’s Dissertation in Engineering (Tambov, 2010) [in Russian].

  23. Yu. I. Shumyatskii, Industrial Adsorption Processes (KolosS, Moscow, 2009) [in Russian].

    Google Scholar 

  24. D. Breck, Zeolite Molecular Sieves (Wiley, New York, 1974).

    Google Scholar 

  25. Handbook of Zeolite Science and Technology, Ed. by S. M. Auerbach, K. A. Carrado, and P. K. Dutta (CRC, Boca Raton, 2003).

    Google Scholar 

  26. A. A. Tishin, V. N. Gurkin, N. I. Laguntsov, and I. M. Kurchatov, Pet. Chem. 58, 338 (2018).

    Article  CAS  Google Scholar 

  27. A. Jayaraman, et al., Adsorption 8, 271 (2002).

    Article  CAS  Google Scholar 

  28. A. A. Tishin, et al., Pet. Chem. 58, 157 (2018).

    Article  CAS  Google Scholar 

  29. A. P. Karnaukhov, Adsorption: Texture of Disperse and Porous Materials (Nauka, Novosibirsk, 1999) [in Russian].

    Google Scholar 

  30. A. A. Tishin, N. I. Laguntsov, and I. Kurchatov, Phys. Procedia 72, 122 (2015).

    Article  CAS  Google Scholar 

  31. PU Patent No. 188323 (2019); Byull., No. 10 (2019).

  32. S. Sircar, M. B. Rao, and T. C. Golden, Stud. Surf. Sci. Catal. 120, 395 (1999).

    Article  Google Scholar 

  33. M. N. Kostina and M. B. Alekhina, Usp. Khim. Khim. Tekhnol. 22 (9), 79 (2008).

    Google Scholar 

  34. E. A. Ustinov, Russ. J. Phys. Chem. A 81, 246 (2007).

    Article  CAS  Google Scholar 

  35. A. A. Tishin, V. N. Gurkin, and N. I. Laguntsov, Pet. Chem. 59, 887 (2019).

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

The author thank Anvar Kurmukov for assistance in processing the results.

Funding

This work was supported by the “Foundation for Promotion of Development of Small Forms of Enterprises in the Scientific and Technical Sphere” (Innovation Promotion Fund), agreement no. 13707GU/2018 of April 01, 2019.

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Correspondence to A. A. Tishin.

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Translated by V. Avdeeva

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Tishin, A.A. Study of Adsorption Properties of Zeolites NaX, CaA, and CaNaA in Separation of Air Components. Pet. Chem. 60, 964–970 (2020). https://doi.org/10.1134/S0965544120080149

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