Abstract
The volumetric method has been used to study the adsorption properties of zeolites CaA, NaX, and CaNaA; adsorption isotherms and adsorption capacities for nitrogen, oxygen, and air have been obtained. The nitrogen/oxygen selectivity values of zeolites have been determined. The experimental adsorption isotherm of air has been compared with the adsorption isotherm obtained for the pure components. The experiments have revealed that the most promising zeolite for use in a membrane–adsorption oxygen concentrator is zeolite CaNaA.
Similar content being viewed by others
REFERENCES
Yu. V. Miroshnichenko, R. A. Enikeeva, and E. M. Kassu, Vestn. Ross. Voen.-Med. Akad., No. 2, 157 (2016).
E. N. Ivanova, Candidate’s Dissertation in Engineering (Moscow, 2016).
A. A. Tishin and V. N. Gurkin, J. Phys., Conf. Ser. 1368, 042043 (2019).
D. M. Frolov, G. A. Dibrov, and G. G. Kagramanov, Usp. Khim. Khim. Tekhnol. 29 (2), 161 (2015).
Yu. I. Dytnerskii, V. P. Brykov, and G. G. Kagramanov, Membrane Gas Separation (Khimiya, Moscow, 1991) [in Russian].
M. B. Alekhina and T. V. Kon’kova, Vestn. Voronezh. Gos. Univ., Ser. Khim. Biol. Farm., No. 2, 67 (2011).
V. G. Matveikin, V. A. Pogonin, S. B. Putin, and S. A. Skvortsov, Mathematical Modeling and Controlling of Pressure Swing Adsorption Process (Mashinostroenie-1, Moscow, 2007) [in Russian].
Yu. V. Nikiforov, S. D. Glukhov, and A. A. Kazakova, Vestn. Mosk. Gos. Tekh. Univ., Ser. Mashinostr., No. 6, 99 (2014).
S. N. Purtov and E. Yu. Tarasova, Tekh. Gazy, No. 2, 38 (2009).
E. I. Akulinin, A. A. Ermakov, D. S. Dvoretskii, and S. I. Simanenkov, Vestn. Tambov. Gos. Tekh. Univ. 14 (3) (2008).
A. Yu. Okunev, Acad., Arkhitekt. Stroit., No. 5, 476 (2009).
M. Suzuki, T. Suzuki, A. Sakoda, and J. Izumi, Adsorption 2, 111 (1996).
S. Sircar and A. L. Myers, Handbook of Zeolite Science and Technology, Ed. by. S. M. Auerbach, K. A. Carrado, and P. K. Dutta (Marcel Dekker, New York, 2003), Ch. 22.
J. C. Santos, F. D. Magalh es, and A. Mendes, Ind. Eng. Chem. Res. 47, 6197 (2008).
J. A. Mason, et al., Energy Environ. Sci. 4, 3030 (2011).
N. Hedin, et al., Appl. Energy 104, 418 (2013).
J. C. Santos, et al., Ind. Eng. Chem. Res. 46, 591 (2007).
C. W. Skarstrom, US Patent No. 2944627 (1958).
C. W. Skarstrom, US Patent No. 3237377 (1962).
E. I. Akulinin, N. F. Gladyshev, and S. I. Dvoretskii, Vestn. Tambov. Gos. Tekh. Univ. 23 (1) (2017).
Yu. I. Shumyatskii and Yu. M. Afanas’ev, Adsorption: A Process with Unlimited Capabilities (Vysshaya Shkola, Moscow, 1998) [in Russian].
E. I. Akulinin, Candidate’s Dissertation in Engineering (Tambov, 2010) [in Russian].
Yu. I. Shumyatskii, Industrial Adsorption Processes (KolosS, Moscow, 2009) [in Russian].
D. Breck, Zeolite Molecular Sieves (Wiley, New York, 1974).
Handbook of Zeolite Science and Technology, Ed. by S. M. Auerbach, K. A. Carrado, and P. K. Dutta (CRC, Boca Raton, 2003).
A. A. Tishin, V. N. Gurkin, N. I. Laguntsov, and I. M. Kurchatov, Pet. Chem. 58, 338 (2018).
A. Jayaraman, et al., Adsorption 8, 271 (2002).
A. A. Tishin, et al., Pet. Chem. 58, 157 (2018).
A. P. Karnaukhov, Adsorption: Texture of Disperse and Porous Materials (Nauka, Novosibirsk, 1999) [in Russian].
A. A. Tishin, N. I. Laguntsov, and I. Kurchatov, Phys. Procedia 72, 122 (2015).
PU Patent No. 188323 (2019); Byull., No. 10 (2019).
S. Sircar, M. B. Rao, and T. C. Golden, Stud. Surf. Sci. Catal. 120, 395 (1999).
M. N. Kostina and M. B. Alekhina, Usp. Khim. Khim. Tekhnol. 22 (9), 79 (2008).
E. A. Ustinov, Russ. J. Phys. Chem. A 81, 246 (2007).
A. A. Tishin, V. N. Gurkin, and N. I. Laguntsov, Pet. Chem. 59, 887 (2019).
ACKNOWLEDGMENTS
The author thank Anvar Kurmukov for assistance in processing the results.
Funding
This work was supported by the “Foundation for Promotion of Development of Small Forms of Enterprises in the Scientific and Technical Sphere” (Innovation Promotion Fund), agreement no. 13707GU/2018 of April 01, 2019.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by V. Avdeeva
Rights and permissions
About this article
Cite this article
Tishin, A.A. Study of Adsorption Properties of Zeolites NaX, CaA, and CaNaA in Separation of Air Components. Pet. Chem. 60, 964–970 (2020). https://doi.org/10.1134/S0965544120080149
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0965544120080149