Issue 18, 2020

One-pot chemoenzymatic reactions in water enabled by micellar encapsulation

Abstract

The use of micellar conditions to enable one-pot reactions involving both transition metal and enzymatic catalysts is reported. Representative enzymatic transformations under micellar conditions are unaffected by the presence of non-ionic surfactants, including designer surfactants such as TPGS-750-M. Furthermore, the presence of enzymes has a negligible effect on transition metal catalysis under micellar conditions in water. Finally, three one-pot chemoenzymatic reactions in water are reported in which the micelle-forming surfactant TPGS-750-M is a crucial factor for reaction efficiency.

Graphical abstract: One-pot chemoenzymatic reactions in water enabled by micellar encapsulation

Supplementary files

Article information

Article type
Paper
Submitted
12 Jun 2020
Accepted
27 Aug 2020
First published
27 Aug 2020

Green Chem., 2020,22, 6187-6193

One-pot chemoenzymatic reactions in water enabled by micellar encapsulation

C. J. Hastings, N. P. Adams, J. Bushi and S. J. Kolb, Green Chem., 2020, 22, 6187 DOI: 10.1039/D0GC01989E

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