SCHEDULED MAINTENANCE
A spinel ferrite catalyst for efficient electroreduction of dinitrogen to ammonia†
Abstract
Ambient electrocatalytic N2 reduction reaction (NRR) provides an eco-friendly way for artificial NH3 production, while an efficient NRR process requires active and stable electrocatalysts. In this communication, we exploit the spinel ferrite NiFe2O4 as a promising NRR catalyst. The developed NiFe2O4 nanocubes/reduced graphene oxide (NiFe2O4/RGO) exhibited an appealing NRR performance with an NH3 yield of 32.2 μg h−1 mg−1 and a faradaic efficiency (FE) of 9.8% at −0.5 V (RHE), as well as a high catalytic durability. Mechanistic investigations revealed that the surface Fe atoms serve as key NRR active sites for favorable N2 adsorption and H+ suppression. These findings may facilitate the understanding and exploration of Earth-abundant spinel ferrite catalysts for electrochemical dinitrogen fixation.
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