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Oxidation Resistance of Plasma-Sprayed Double-Layered LC/YSZ Coatings with Different Thickness Ratios at High Temperatures

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Abstract

This study aims to enhance the oxidation resistance of ceramic coatings through designing and optimizing microstructure. A series of double-layered lanthanum–cerium oxide (LC) and 8 wt% yttria-partially-stabilized zirconia (YSZ) coatings with different thickness ratios were tailored. The isothermal oxidation experiment and molecular dynamics simulation results suggested that due to the lower oxygen ionic diffusion coefficient, double-layered LC/YSZ coatings exhibited an excellent antioxidation property compared to the single-layer YSZ coating. However, with the increase of LC layer thickness in LC/YSZ coatings, sintering-induced vertical cracks were easily formed within LC layer, which significantly shortened the oxidation resistance of LC/YSZ coatings by a burner rig test at 1225 °C. The equivalent thermal growth oxide thickness manifested that the optimum thickness ratio between LC and YSZ layers was 1:2.

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Acknowledgements

This work was supported by National Key R&D Program of China (No. 2018YFB2004002), Natural Science Foundation of Shaanxi Province (Nos. 2019TD-020 and 2019JQ-586), China Postdoctoral Science Foundation (No. 2019M653598), Shanxi Province Science Foundation for Youths (No. 201901D211258) and Science Foundation of North University of China (No. XJJ201920).

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Author notes

  1. L. Zhang and W. Fan contribute equally to this work.

Authors and Affiliations

  1. State Key Laboratory for Mechanical Behavior of Materials, Xi’an Jiaotong University, Xi’an, 710049, People’s Republic of China

    L. Zhang, Y. Wang, Z. Z. Wang & Y. Bai

  2. School of Energy and Power Engineering, North University of China, Taiyuan, 030051, People’s Republic of China

    W. Fan

  3. State Key Laboratory of Electrical Insulation and Power Equipment, Xi’an Jiaotong University, Xi’an, 710049, People’s Republic of China

    Y. Wang

  4. Mechanical and Electrical Engineering Institute, Zhengzhou University of Light Industry, Zhengzhou, 450000, People’s Republic of China

    K. Liu

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  1. L. Zhang
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  2. W. Fan
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  3. Y. Wang
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  4. K. Liu
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  5. Z. Z. Wang
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  6. Y. Bai
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Correspondence to Y. Wang or Y. Bai.

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Zhang, L., Fan, W., Wang, Y. et al. Oxidation Resistance of Plasma-Sprayed Double-Layered LC/YSZ Coatings with Different Thickness Ratios at High Temperatures. Oxid Met 94, 397–408 (2020). https://doi.org/10.1007/s11085-020-09998-z

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  • DOI: https://doi.org/10.1007/s11085-020-09998-z

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