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Magnesium acetate – an effective electrophilic activator of the carbonyl group in transesterification of dialkylaziridine dicarboxylates

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Chemistry of Heterocyclic Compounds Aims and scope

A method for transesterification of the ester groups in dialkylaziridine dicarboxylates by electrophilic activation of the carbonyl group in the presence of magnesium acetate with the preservation of the aziridine ring was developed and the use of modified aziridine dicarboxylates in the synthesis of sterically hindered derivatives of fullerenes C60, 2',5'-disubstituted fulleropyrrolidines, was demonstrated.

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This work was supported by the Russian Science Foundation (project 19-13-00039).

Analytical and spectral studies were performed at the Resource Centers of the Science Park of Saint Petersburg State University: Magnetic Resonance Research Center, Center for X-ray Diffraction Studies, and Chemical Analysis and Materials Research Center.

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Authors and Affiliations

  1. Institute of Chemistry, Saint Petersburg State University, 7/9 University Embankment, Saint Petersburg, 199034, Russia

    Angelina V. Kazakova, Dmitriy V. Androsov, Alexander S. Konev & Alexander F. Khlebnikov

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  1. Angelina V. Kazakova
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  2. Dmitriy V. Androsov
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  3. Alexander S. Konev
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  4. Alexander F. Khlebnikov
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Correspondence to Alexander S. Konev.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, 2020, 56(7), 875–880

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Kazakova, A.V., Androsov, D.V., Konev, A.S. et al. Magnesium acetate – an effective electrophilic activator of the carbonyl group in transesterification of dialkylaziridine dicarboxylates. Chem Heterocycl Comp 56, 875–880 (2020). https://doi.org/10.1007/s10593-020-02744-y

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