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Thermochemical and Energy Characteristics of N-(2,2-bis(methoxy-NNO-azoxy)ethyl)nitramines

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Combustion, Explosion, and Shock Waves Aims and scope

Abstract

The standard enthalpies of formation of 1,1-bis(methoxy-NNO-azoxy)-3-nitro-3-azabutane and 1,1,8,8-tetrakis (methoxy-NNO-azoxy)-3,6-dinitro-3,6-diazaoctane were experimentally determined to be 87.7 \(\pm\) 3.9 and 283.8 \(\pm\) 6.2 kJ/mol, respectively. Calculations have shown that solid composite propellants containing these two compounds as gasifying components in metal-free compositions based on an active binder and ammonium perchlorate are inferior in the maximum achievable effective impulse at the third stage of the rocket system \(I_{ef}\)(3) to compositions based on HMX, but in designing special compositions with a limited content of organic explosive (not higher than 30–35%), these two compounds provide 5–10 s higher values of \(I_{ef}\)(3) than when using HMX.

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  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Russia

    I. N. Zyuzin, D. B. Lempert, A. V. Nabatova & A. I. Kazakov

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  1. I. N. Zyuzin
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  2. D. B. Lempert
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  3. A. V. Nabatova
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  4. A. I. Kazakov
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Zyuzin, I.N., Lempert, D.B., Nabatova, A.V. et al. Thermochemical and Energy Characteristics of N-(2,2-bis(methoxy-NNO-azoxy)ethyl)nitramines. Combust Explos Shock Waves 56, 464–470 (2020). https://doi.org/10.1134/S0010508220040103

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