Skip to main content
Log in

Thermodynamic Estimating the Mass Transfer of Compounds of Rare Metals under Conditions of a Filtration Combustion Wave

  • Physicochemical Studies of Systems and Processes
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

A thermodynamic calculation of the possibility of mass transfer of metal compounds in conditions of filtration combustion of metal-containing mixtures was carried out. According to the results the metals were divided into two groups: the first group includes metals that form both condensed and gaseous phases, and the second group includes metals that are only in the condensed phase. Under conditions of filtration combustion wave due to continuous evaporation and condensation, it is possible to organize mass transfer of compounds of the first group metals in order to concentrate them in a specific zone of the reactor. Metals of the second group do not participate in mass transfer under the conditions of a filtration combustion wave and will remain in solid combustion products (in ash). Their concentration is possible only if there is a large amount of a combustible component in the initial mixture. In this case, due to the burnout of the combustible part and the preservation of metal compounds in the ash residue, their concentration will occur. Concentration of metals will allow performing their further economically justified recovery by traditional methods.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.

Similar content being viewed by others

REFERENCES

  1. Jowitt, S.M., Werner, T.T., Weng, Z., and Mudd, G.M., Curr. Opin. Green Sustainable Chem., 2018, vol. 13, pp. 1–7. https://doi.org/10.1016/j.cogsc.2018.02.008

    Article  Google Scholar 

  2. Anjum, F., Shahid, M., and Akcil, A., Hydrometallurgy, 2012, vol. 117–118, pp. 1–12. https://doi.org/10.1016/j.hydromet.2012.01.007

    Article  CAS  Google Scholar 

  3. Brombacher, C., Bachofen, R., and Brandl, H., Appl. Microbiol. Biot., 1997, vol. 48, no. 5, pp. 577–587. https://doi.org/10.1007/s002530051099

    Article  CAS  Google Scholar 

  4. Sethurajan, M., Lens, P.N., Horn, H.A., Figueiredo, L., H.A., and van Hullebusch, E.D., Sustainable Heavy Metal Remediation, 2017, pp. 161–206. https://doi.org/10.1007/978-3-319-61146-4_6

    Article  Google Scholar 

  5. Sethurajan, M., van Hullebusch, E.D., and Nancharaiah, Y.V., J. Environ. Manage, 2018, vol. 211, pp. 138–153. https://doi.org/10.1016/j.jenvman.2018.01.035

    Article  CAS  PubMed  Google Scholar 

  6. Akcil, A., Erust, C., Gahan, C.S., Ozgun, M., Sahin, M., and Tuncuk, A., Waste Manag., 2015, vol. 45, pp. 258–271. https://doi.org/10.1016/j.wasman.2015.01.017

    Article  CAS  PubMed  Google Scholar 

  7. Lu, Y. and Xu, Z., Resour. Conserv. Recy., 2016, vol. 113, pp. 28–39. https://doi.org/10.1016/j.resconrec.2016.05.007

    Article  Google Scholar 

  8. Dai, S.F. and Finkelman, R.B., Int. J. Coal Geol., 2018, vol. 186, pp. 155–164. https://doi.org/10.1016/j.coal.2017.06.005

    Article  CAS  Google Scholar 

  9. Hennebel, T., Boon, N., Maes, S., and Lenz, M., New Biotech., 2015, vol. 32, no. 1, pp. 121–127. https://doi.org/10.1016/j.nbt.2013.08.004

    Article  CAS  Google Scholar 

  10. Nancharaiah, Y.V., Mohan, S.V., and Lens, P.N., Bioresour. Technol., 2015, vol. 195, pp. 102–114. https://doi.org/10.1016/j.biortech.2015.06.058

    Article  CAS  PubMed  Google Scholar 

  11. Lutsenko, N.A., Int. J. Heat Mass. Transf., 2014, vol. 72, pp. 602–608. https://doi.org/10.1016/j.ijheatmasstransfer.2014.01.046

    Article  Google Scholar 

  12. Toledo, M., Ripoll, N., Cespedes, J., Zbogar-Rasic, A., Fedorova, N., Jovicic, V., and Delgado, A., Energ. Convers. Manage., 2018, vol. 172, pp. 381–390. https://doi.org/10.1016/j.enconman.2018.07.046

    Article  CAS  Google Scholar 

  13. Salganskii, E.A., Fursov, V.P., Glazov, S.V., Salganskaya, M.V., and Manelis, G.B., Combustion, Explosion and Shock Waves, 2006, vol. 42, pp. 55–62. https://doi.org/10.1007/s10573-006-0007-9

    Article  Google Scholar 

  14. Ruiz, G., Ripoll, N., Fedorova, N., Zbogar-Rasic, A., Jovicic, V., Delgado, A., and Toledo, M., Int. J. Heat Mass. Transf., 2019, vol. 136, pp. 383–392. https://doi.org/10.1016/j.ijheatmasstransfer.2019.03.009

    Article  CAS  Google Scholar 

  15. Salganskii, E.A., Fursov, V.P., Glazov, S.V., Salganskaya, M.V., and Manelis, G.B., Combust. Explos. Shock Waves, 2003, vol. 39, no. 1, pp. 37–42. https://doi.org/10.1023/A:1022193117840

    Article  Google Scholar 

  16. Strizhak, P.A., Volkov, R.S., Castanet, G., Lemoine, F., Rybdylova, O., and Sazhin, S.S., Int. J. Heat Mass. Transf., 2018, vol. 127, pp. 92–106. https://doi.org/10.1016/j.ijheatmasstransfer.2018.06.103

    Article  Google Scholar 

  17. Korotkikh, A.G., Slyusarskiy, K.V., Ditts A. A., Russ. J. Phys. Chem. B, 2016, vol. 10, no. 4, pp. 576–581. https://doi.org/10.1134/S1990793116040059.

    Article  CAS  Google Scholar 

  18. Manelis, G.B., Glazov, S.V., Salgansky, E.A., Lempert, D.B., Gudkova, I.Yu., Domashnev, I.A., Kolesnikova, A.M., Kislov, V.M., Kolesnikova, Yu.Yu., Int. J. Heat Mass. Transf., 2016, vol. 92, pp. 744–750. https://doi.org/10.1016/j.ijheatmasstransfer.2015.09.056

    Article  CAS  Google Scholar 

  19. Zaslavskii, G.E., Lempert, D.B., and Manelis, G.B., Khim. Fizika, 2014, vol. 33, no. 1, pp. 14–19. https://doi.org/10.7868/S0207401X14010142

    Article  CAS  Google Scholar 

  20. Lempert, D.B., Glazov, S.V., and Manelis, G.B., Mass Transfer in Filtration Combustion Processes, Rijeka, Croatia: InTech, 2011. https://doi.org/10.5772/14526

    Book  Google Scholar 

  21. Trusov, B.G., Inzh. Zh.: Nauka Innovatsii, 2012, no. 1, pp. 240–249. https://doi.org/10.18698/2308-6033-2012-1-31

    Article  Google Scholar 

Download references

Funding

The research was carried out with the financial support of the Russian Foundation for Basic Research within the framework of scientific project no. 18-29-24029-MK and state assignment no. 0089-2019-0018, state registration number АААА-А19-119-022690098-3.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to E. A. Salgansky.

Ethics declarations

The authors declare that they have no conflicts of interest requiring disclosure in this article.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Salgansky, E.A., Podlesniy, D.N., Tsvetkov, M.V. et al. Thermodynamic Estimating the Mass Transfer of Compounds of Rare Metals under Conditions of a Filtration Combustion Wave. Russ J Appl Chem 93, 1096–1101 (2020). https://doi.org/10.1134/S1070427220070228

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427220070228

Keywords:

Navigation