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Modified blue TiO2 nanostructures for efficient photo-oxidative removal of harmful NOx gases

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Abstract

Blue TiO2 nanostructures were produced via Lithium/ethylenediamine (Li/EDA) reduction method and applied for photo-oxidative removal of harmful NOx gases under simulated solar light irradiation. Blue TiO2 possesses some unique physicochemical properties such as enhanced visible-light absorption, superficial defects or oxygen vacancies, and the evolution of Ti3+ species. Moreover, the photoluminescence spectra (PL) revealed the efficient separation of photoinduced electron-hole pairs in the modified blue TiO2 nanostructures, enhancing their photocatalytic activities. The results indicated that the blue TiO2 nanostructures exhibited the highest performance towards photo-oxidation of NOx gases, with an efficiency of 72.6% under simulated solar light irradiation.

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Acknowledgements

This research was supported by the Global Research Laboratory Program (Grant Number: 2010-00339) of the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science, and Technology (MEST) of Korea.

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Correspondence to Gobinda Gyawali or Soo Wohn Lee.

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Nguyen, H.H., Gyawali, G., Martinez-Oviedo, A. et al. Modified blue TiO2 nanostructures for efficient photo-oxidative removal of harmful NOx gases. Korean J. Chem. Eng. 37, 1507–1514 (2020). https://doi.org/10.1007/s11814-020-0560-z

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  • DOI: https://doi.org/10.1007/s11814-020-0560-z

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