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Phase equilibria in the sea-water Na, K, Mg//Cl, SO4–H2O quinary system at 0 °C

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Abstract

The phase equilibria in the quinary Na, K, Mg//Cl, SO4–H2O sea-water system at 0 °C were determined and a total phase equilibria diagram for the system was constructed by means of the translation method consistent with available literature data. There are seven points, 21 curves and 22 fields saturated, respectively, with 4, 3 and 2 equilibrium solid phases, for the quinary composition of the system. The constructed total phase equilibria diagram of the system was fragmented into divariant co-crystallization fields of two different solid phases and trivariant crystallization volumes of each of the solid phases at equilibrium. The structures of nine Janecke dry-salt phase diagrams were obtained by fragmentation of the total phase equilibria diagram into crystallization volumes. The comparison with the available literature data shows that, the obtained crystallization volume for halite agrees well with the available experimental data.

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References

  • Balarew C (1993) Solubilities in seawater-type systems: Some technical and environmental friendly applications. Pure Appl Chem 65(2):213–218

    Article  CAS  Google Scholar 

  • Cohen-Adad R, Balarew Chr, Tepavitcharova S, Rabadjieva D (2002) Sea-water solubility phase diagram. Application to an extractive process. Pure Appl Chem 74:1811–1821

  • Cui R, Sang S, Wang D (2016) Liquid-Solid Equilibria in the Quinary Na, K//Br, SO4, B4O7–H2O System at 298K. Russ J Inorg Chem 61:1325–1330

    Article  CAS  Google Scholar 

  • D'Ans J, Bertsch A, Gessner A (1915) Researches on the salt systems of oceanic salt deposits. Kali 14:217–222

    Google Scholar 

  • D’Ans J, Bertsch A, Gessner A (1915a) Studies on the salt systems of oceanic salt deposits. Kali 11:165

    Google Scholar 

  • D’Ans J, Bertsch A, Gessner A (1915b) Studies on the salt systems of oceanic salt deposits. Kali 12:181

    Google Scholar 

  • D’Ans J, Bertsch A, Gessner A (1915d) Studies on the salt systems of oceanic salt deposits. Kali 15:233 (16:245)

  • Emons HH, Fortsch R, Holldorf H (1975a) Contribution to the quinary system Na+,K+,Mg2+/Cl-,SO42-//H2O. Z Anorg Allg Chem 413:27–36

  • Emons HH, Fortsch R, Holldorf H (1975b) The polytherms of the quinary system Na+, K+, Mg2+ / Cl−, SO42−//H2O in the range of + 25 ° to −10 °C. Z Anorg Allg, Chem 413:85–93

  • Frederick HS (1963) Data of geochemistry, Chapter Y, marine evaporates, 6th edn. United States Government Printing Office, Washington (1963)

  • Frowein F, Von Muhlendahl E (1926) The solutions of the double-ternary salt mixture. Z Anorg Chem 39:1488–1500

    CAS  Google Scholar 

  • Goroshchenko YG, Soliev L (1982) Phase equilibria in the system Na, K, Mg//Cl, SO4–H2O at 0°C. Ukr Chem J 48:695–699

    CAS  Google Scholar 

  • Goroshchenko YG (1982) The centroid method for imaging multicomponent systems; Naukova Dumka Kiev (in Russian)

  • Kwok KS, Ng KM, Taboada ME, Cisternas LA (2008) Thermodynamics of salt lake system: Representation, experiments, and visualization. AIChEJ 54:706–727

    Article  CAS  Google Scholar 

  • Kurnakov NS, Zhemchuzhnyi SF (1919) Equilibrium of reciprocal system sodium chloride—magnesium sulfate regarding to natural brines. Izv Sect Fiz Khim Anal AN SSSR 1:185–243

  • Meng L, Gruszkiewicz MS, Deng T, Guo Y, Li D (2015) Isothermal evaporation process simulation using the Pitzer model for the quinary system LiCl–NaCl–KCl–SrCl2–H2O at 298.15 K. Ind Eng Chem Res 54:8311–8318

    Article  CAS  Google Scholar 

  • Motoyama M, Kadota M, Oka S (1975) Equilibrium in the quinary system NaCl–KCl–MgCl2–CaCl2–H2O system at 0 °C. Bull Soc Sea Water Sci Jpn 28:327–333

    CAS  Google Scholar 

  • Mayerhoffer W, Saunders A (1899a) About reciprocal salt pairs II. The equilibrium phenomena of reciprocal salt pairs with the simultaneous presence of a double salt. Z Phys Chem 28:453–493

  • Mayerhoffer W, Saunders A (1899b) About reciprocal salt pairs II. The equilibrium phenomena of reciprocal salt pairs in the simultaneous presence of a double salt. Part II. Z Phys Chem 31 370–389

  • Sang SH, Hui-an Y, Ming-lin T (2005) (Liquid+Solid) equilibria in the quinary system Li+ + Na+ + K+ + CO32-, B4O72- + H2O at 288K. J Chem Eng Data 50:1557–1559

    Article  CAS  Google Scholar 

  • Sang SH, Jiang P (2010) (Solid-Liquid) equilibria in the quinary Na+, Mg2+, K+//SO42-, B4O72–H2O system at 288K. CALPHAD 34:64–67

    Article  CAS  Google Scholar 

  • Soliev L (1987) Prediction of the structure of phase equilibria diagrams of multicomponent water-salt systems by means of translation method. VINITI, Academy of sciences of USSR, Moscow

    Google Scholar 

  • Soliev L (2000) Prediction of marine—type multicomponent system phase equilibria by means of translation method, Book I. Tajik State Pedagogical University, Dushanbe

    Google Scholar 

  • Soliev L, Tursunbadalov S (2008) Phase equilibria in the Na, K//SO4, CO3, HCO3–H2O system at 25 °C. Russ J Inorg Chem 53:805–811

    Article  Google Scholar 

  • Soliev L, Tursunbadalov S (2010) Phase equilibria in the Na, K//SO4, CO3, HCO3–H2O system at 0 °C. Russ J Inorg Chem 55:1295–1300

    Article  CAS  Google Scholar 

  • Soliev L, Tursunbadalov S (2013) Phase equilibria in quinary Na, K//SO4, CO3, HCO3–H2O system at 50 °C. IOP Conf. Ser.: Mater. Sci. Eng. vol 47. Web Sep.3, 2018

  • Tursunbadalov S, Soliev L (2016) Phase equilibria in multicomponent water-salt systems. J Chem Eng Data 61:2209–2220

    Article  CAS  Google Scholar 

  • Tursunbadalov S, Soliev L (2017a) Crystallization and dissolution in multicomponent water-salt systems. J Chem Eng Data 62:3053–3063

    Article  CAS  Google Scholar 

  • Tursunbadalov S, Soliev L (2017b) Determination of phase equilibria and construction of comprehensive phase diagram for quinary Na, K//Cl, SO4, B4O7–H2O system at 25 °C. J Chem Eng Data 62:698–703

    Article  CAS  Google Scholar 

  • Tursunbadalov S, Soliev L (2015) Phase equilibria in the Na, K//SO4, CO3, HCO3–H2O system at 75 °C. J Solut Chem 44:1626–1639

    Article  CAS  Google Scholar 

  • Tursunbadalov S, Soliev L (2018) Investigation of phase equilibria in quinary water-salt systems. J Chem Eng Data 63:598–612

    Article  CAS  Google Scholar 

  • Tursunbadalov S, Soliev L (2019) Phase equilibria in quinary Na, K, Mg//Cl, SO4–H2O system at 25 °C. J Chem Eng Data. https://doi.org/10.1021/acs.jced.9b00617

    Article  Google Scholar 

  • Usdowski E, Dietzel M (1998) Atlas and data of solid-solution equilibria of marine evaporites. Springer, Berlin, Heidelberg

    Book  Google Scholar 

  • Voigt W (2007) Solubility of inorganic salts and their industrial importance in development and applications in solubility. In: Letcher TM (ed). RSC Publishing (2007)

  • Voigt W (2015) What we know and still not know about oceanic salts. Pure Appl Chem 87:1099–1126

    Article  CAS  Google Scholar 

  • Wang, R., and Zeng, Y., Metastable Phase Equilibrium of the Quinary Aqueous System Li+ + K+ + Cl− + CO32− + B4O72− + H2O at 273.15 K. J. Chem. Eng. Data, 59, 903−911 (2014).

  • Will TM (1998) Phase equilibria in methamorphic rocks: thermodynamic background and petrological applications. Springer, New York

    Google Scholar 

  • Xudong Y, Ying Z, Shanshan G, Yujuan Z (2014) Stable phase equilibrium and phase diagram of the quinary system Li+, K+, Rb+, Mg2+//Borate‑H2O at T = 348.15 K. J Chem Eng Data 59:4173−4178

  • Yanat’eva OK, Orlova VT (1958) Crystallization volume of schoenite in sea-water K, Na, Mg, Cl, SO4–H2O system at 0 °C. Russ J Inorg Chem 3:2408–2413

  • Yanat’eva OK, Orlova VT (1959a) Glaserite in the K, Na, Mg, Cl, SO4–H2O system at 0 °C. Russ J Inorg Chem 4:861–864

  • Yanat’eva OK, Orlova VT (1959b) Sea-water K, Na, Mg, Cl, SO4–H2O system at 0 °C. Russ J Appl Chem 32:2397–2405

  • Yang Z, Hong BX, Chang LL, Yi Z, Li LP, Peng HQ, Jun HH, Ke HL (2013) Phase equilibria of Na+, NH4+// SO42−, HCO3−, Cl−−H2O quinary system. J Chem Eng Data 58:2095–2099

    Article  Google Scholar 

  • Zdanovskiy AB, Soloveva EF, Lyakhovskaya EI, Shestakov NE, Shleymovich RE, Abutkova AB, Cheromnikh LM, Kulikova TA (2003) Handbook of experimental data on solubility in multicomponent water-salt systems, volume I. Khimizdat: Saint Petersburg (in Russian)

  • Zdanovskiy AB, Soloveva EF, Lyakhovskaya EI, Shestakov NE, Shleymovich RE, Abutkova AB, Cheromnikh LM, Kulikova TA (2004) Handbook of experimental data on solubility in multicomponent water-salt systems; olume II, Khimizdat: Saint Petersburg (in Russian)

  • Zeng Y, Lin X (2009) Solubility and Density Measurements of Concentrated L2B4O7 + Na2B4O7 + K2B4O7 + Li2SO4 + Na2SO4 + K2SO4 + H2O Solution at 273.15K. J Chem Eng Data 54:2054–2059

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Natural and Applied Sciences, Nile University of Nigeria, Plot 681, Cadastral Zone C-OO, Research and Institution Area, Abuja FCT, 900001, Nigeria

    Sherali Tursunbadalov

  2. Department of General and Inorganic Chemistry, Faculty of Chemistry, Tajik State Pedagogical University, Rudaki 121, Dushanbe, Tajikistan

    Lutfullo Soliev

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  1. Sherali Tursunbadalov
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  2. Lutfullo Soliev
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Correspondence to Sherali Tursunbadalov.

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Tursunbadalov, S., Soliev, L. Phase equilibria in the sea-water Na, K, Mg//Cl, SO4–H2O quinary system at 0 °C. Braz. J. Chem. Eng. 37, 577–593 (2020). https://doi.org/10.1007/s43153-020-00054-6

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  • DOI: https://doi.org/10.1007/s43153-020-00054-6

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