Abstract
The structures of ethyl 2,2-bis{[(benzoylcarbamothioyl)oxy]methyl}propanoate and its 1 : 1 complexes with copper(II) and cobalt(II) ions were determined by electronic absorption, IR, and 1H and 13C NMR spectroscopy and elemental analysis. The coordination entity in the complexes includes oxygen and sulfur atoms of the benzoyl and carbamothioyloxy groups of both ligand branches. The copper(II) ion has octahedral configuration with trigonal distortion, and the cobalt(II) ion has five-coordinate square–pyramidal configuration. The thermal behavior of the title compounds was studied by differential scanning calorimetry and thermogravimetric analysis.
Similar content being viewed by others
REFERENCES
Zagar, E. and Zigon, M., Prog. Polym. Sci., 2011, vol. 36, no. 1, p. 53. https://doi.org/10.1016/j.progpolymsci.2010.08.004
Korolev, V.G. and Bubnova, M.L., Giperrazvetvlennye polimery – novyi moshchnyi stimul dal’neishego razvitiya oblasti trekhmernoi polimerizatsii i revolyutsiya v polimernom materialovedenii (Hyperbranched Polymers—A Novel Powerful Impetus for Further Development of Three-dimensional Polymerization and a Revolution in Polymer Materials Science), Moscow: IPKhF RAN, 2006.
Wang, D., Zhao, T., Zhu, X., Yan, D., and Wang, W., Chem. Soc. Rev., 2015, vol. 44, no. 12, p. 4023. https://doi.org/10.1039/C4CS00229F
Yan, D., Gao, C., and Frey, H., Hyperbranched Polymers. Synthesis, Properties, and Applications, Hoboken: Wiley, 2010.
Kutyreva, M.P., Babkina, S.S., Atanasyan, T.K., Ulakhovich, N.A., and Kutyrev, G.A., Novye materialy: biologicheski aktivnye giperrazvetvlennye polimery i ikh metallokompleksy (New Materials: Biologically Active Hyberbranched Polymers and Their Metal Complexes), Moscow: MGPU, 2014.
Wu, W., Tang, R., Li, Q., and Li, Z., Chem. Soc. Rev., 2015, vol. 44, no. 12, p. 3997. https://doi.org/10.1039/C4CS00224e
Abd-El-Aziz, A.S., Carraher, C.E., Jr., Pittman, C.U.Jr., and Zeldin, M., Inorganic and Organometallic Macromolecules, New York: Springer, 2008, vol. 1, p. 21. https://doi.org/10.1007/978-0-387-72947-3
Seiler, M., Rolker, J., and Arlt, W., Macromolecules, 2003, vol. 36, no. 6, p. 2085. https://doi.org/10.1021/ma025994n
Jang, J.G. and Bae, Y.C., J. Chem. Phys., 2001, vol. 114, no. 11, p. 5034. https://doi.org/10.1063/1.1329647
Tziveleka, L-A., Kontoyanni, C., Sideraton, Z., Tsiourvas, D., and Paleos, C.M., Macromol. Biosci., 2006, vol. 6, no. 2, p. 161. https://doi.org/10.1002/mabi.200500181
Kutyreva, M.P., Ulakhovich, N.A., Karataeva, F.K., Rezepova, M.V., and Kutyrev, G.A., Russ. J. Inorg. Chem., 2012, vol. 57. N 9. P. 1244. https://doi.org/10.1134/S0036023612090136
Kutyreva, M.P., Gataulina, A.R., Kutyrev, G.A., Nizamov, I.S., and Ulakhovich, N.A., Russ. J. Gen. Chem. 2011, vol. vol. 81, no. 7, p. 1535. https://doi.org/10.1134/s1070363211070206
Kutyrev, G.A., Gataulina, A.R., Kutyreva, M.P., Usmanova, G.Sh., and Ulakhovich, N.A., Vestn. Kazan. Tekhnol. Univ., 2010, no. 12, p. 428.
Reul, R., Nguyen, J., and Kissel, T., Biomaterials, 2009, vol. 30, no. 29, p. 5815. https://doi.org/10.1016/j.biomaterials.2009.06.057
Nizamov, I.S., Shamilov, R.R., Mart’yanov, E.M., Cherkasov, R.A., Sergeenko, G.G., and Kutyrev, G.A., Russ. J. Gen. Chem., 2008, vol. 78, no. 7, p. 1338. https://doi.org/10.1134/S1070363208070086
Cherkasov, R.A., Shamilov, R.R., Nizamov, I.S., Gataulina, A.R., and Kutyrev, G.A., Phosphorus, Sulfur Silicon Relat. Elem., 2011, vol. 186, no. 4, p. 1001. https://doi.org/10.1080/10426507.2010.509879
Nizamov, I.S., Shamilov, R.R., Cherkasov, R.A., Sergeenko, G.G., and Kutyrev, G.A., Russ. J. Gen. Chem., 2007, vol. 77, no. 12, p. 2205. https://doi.org/10.1134/S1070363207120213
Kutyrev, G.A., Busygina, A.A., Akhmadulina, E.N., Rakhmatullina, L.R., Kutyreva, M.P., and Gataulina, A.R., Vestn. Kazan. Tekhnol. Univ., 2016, vol. 19, no. 14, p. 15.
Kutyreva, M.P., Maksimov, A.F., Ernandes, A.M.P., Zhukova, A.A., Gataulina, A.R., and Kutyrev, G.A., Russ. J. Gen. Chem., 2020, vol. 90, no. 2, p. 268. https://doi.org/10.1134/s1070363220020164
Kutyrev, G.A., Maksimov, A.F., Ernandes, A.-M.P., Kutyreva, M.P., and Gataulina, A.R., Vestn. Kazan. Tekhnol. Univ., 2018, vol. 21, no. 9, p. 69.
Quas, L., Schrӧder, U., Schrӧder, B., Dietze, F., and Beyer, L., Solvent Extr. Ion Exch., 2000, vol. 18, no. 6, p. 1167. https://doi.org/10.1080/07366290008934727
Vallejos, S.T., Erben, M.F., Piro, O.E., Castellano, E.E., and Della Védova, C.O., Polyhedron, 2009, vol. 28, no. 5, p. 937. https://doi.org/10.1016/j.poly.2009.01.022
Plutín, A.M., Suárez, M., Ochoa, E., Machado, T., Mocelo, R., Concellón, J.M., and Rodríguez-Solla, H., Tetrahedron, 2005, vol. 61, no. 24, p 5812. https://doi.org/10.1016/j.tet.2005.04.018
Marquez, H., Loupy, A., Calderon, O., and Pérez, E.R., Tetrahedron, 2006, vol. 62, no. 11, p. 2616. https://doi.org/10.1016/j.tet.2005.12.037
Moustafa, H.Y., Younis, M.A., Azab, M.M., and Khalil, M.I., Bull. Fac. Sci. Zigazig Univ., 2017, vol. 39, p. 149. https://doi.org/10.21608/BFSZU.2017.31048
Hakan, A., Ulrich, F., and Nevzat, K., Spectrochim. Acta, Part A, 2007, vol. 67, nos. 3–4, p. 936. https://doi.org/10.1016/j.saa.2006.09.011
Gölcü, A., Yücesoy, C., and Serin, S., Synth. React. Inorg. Met.-Org. Chem., 2004, vol. 34, no. 7, p. 1259. https://doi.org/10.1081/sim-120039270
Nakomoto, K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, New York: Wiley, 1986, 4th ed.
Lever, E., Inorganic Electronic Spectroscopy, Amsterdam: Elsevier, 1984, 2nd ed.
Structure Determination of Organic Compounds: Tables of Spectral Data, Pretsch, E., Bühlmann, P., and Affolter, C., Eds., Berlin: Springer, 2000, 3rd ed.
Schrӧder, U., Beyer, L., Dietze, R., Richter, R., Schmidt, S., and Hoyer, E., J. Prakt. Chem., 1995, vol. 337, no. 1, p. 184. https://doi.org/10.1002/prac.19953370141
Mohd Nor, N.A.M., Ahmad, J., Abdullah, Z., Halim, S.N.A., Otero-de-la-Roza, A., and Tiekink, E.R.T., Z. Crystallogr. Cryst. Mater., 2015, vol. 230, no. 6, p. 397. https://doi.org/10.1515/zkri-2014-1820
Bleasdale, C., Ellwood, S.B., Golding, B.T., Slaich, P.K., Taylor, D.J., and Watson, W.P., J. Chem. Soc., Perkin Trans. 1, 1994, p. 2859. https://doi.org/10.1039/P19940002859
Beck, M.T. and Nagypal, I., Chemistry of Complex Equilibria, Budapest: Akad. Kiado, 1985.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
No conflict of interest was declared by the authors.
Rights and permissions
About this article
Cite this article
Maksimov, A.F., Zhukova, A.A., Ernandes, AM.P. et al. Synthesis of Ethyl 2,2-Bis{[(benzoylcarbamothioyl)oxy]methyl}propanoate and Its Complexes with Copper(II) and Cobalt(II) Ions. Russ J Gen Chem 90, 1285–1291 (2020). https://doi.org/10.1134/S1070363220070142
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363220070142