Abstract
A novel optical probe consistinsg of Ag@PANI (silver-polyaniline) nanocomposites was developed for detection of mercury ions (Hg2+). The poly-dispersed Ag@PANI nanocomposites were synthesized by complexation reaction method. We studied structural and functional properties of polymer nanocomposites thoroughly. Ag@PANI nanocomposites consist of fibrous morphology with a mean particle size of 31.39 nm. Ag@PANI nanocomposites consist of face-centered cubic crystal structure with an average crystallite size of 19.41 nm. Raman spectroscopy was used in sensitive and selective detection of Hg2+ ions in dynamic range of 0.01–0.1 ppm with limit of detection of 0.019 ppm. Ag@PANI nanocomposite sensor for Hg (II) ions has shown some sublime results in pH range 3–5. Ag@PANI-based sensing probe can be beneficial for Hg2+ ions detection in highly sensitive biological, chemical and environmental analysis. Our sensing probe has shown good reproducibility, and all recorded observations revealed that sensing probe consisting of Ag@PANI nanocomposites is well suited for detection of Hg2+ ions.
Acknowledgments
The authors would like to acknowledge Prof. (Dr.) Vinod Yadava (Director, National Institute of Technology, Hamirpur, India) for his constant support.
Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
Research funding: None declared.
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
References
1. Winey, K. I., Richard, A. Vaia. MRS Bull. 2007, 32, 314–322; https://doi.org/10.1557/mrs2007.229.10.1557/mrs2007.229Search in Google Scholar
2. Armstrong, G. Eur. J. Phys. 2015, 36, 063001; https://doi.org/10.1088/0143-0807/36/6/063001.10.1088/0143-0807/36/6/063001Search in Google Scholar
3. Chang, J. Y., Godovsky, D. Y., Han, M. J., Hassan, C. M., Kim, J., Lee, B., Lee, Y., Peppas, N. A., Quirk, R. P., Yoo, T. Biopolymers PVA hydrogels, anionic polymerisation nanocomposites. Springer, Berlin, Heidelberg, 2000; pp. 163–205.10.1007/3-540-46414-X_4Search in Google Scholar
4. Hule, R. A, Darrin, J. P. MRS Bull. 2007, 32, 354–358; https://doi.org/10.1557/mrs2007.235.10.1557/mrs2007.235Search in Google Scholar
5. Njuguna, J., Krzysztof, P. Adv. Eng. Mater. 2003, 5, 769–778; https://doi.org/10.1002/adem.200310101.10.1002/adem.200310101Search in Google Scholar
6. Youssef, A. M. Polym. Plastics Technol. Eng. 2013, 52, 635–660; https://doi.org/10.1080/03602559.2012.762673.10.1080/03602559.2012.762673Search in Google Scholar
7. Huang, J. Pure Appl. Chem. 2006, 78, 15–27; https://doi.org/10.1351/pac200678010015.10.1351/pac200678010015Search in Google Scholar
8. Buschle, W. Diss. University of Cincinnati: Cincinnati, Ohio, USA, 2011.Search in Google Scholar
9. Chandrasekhar, P. Conducting polymers, fundamentals and applications: a practical approach. Springer Science & Business Media: Marlboro, USA, 2013.Search in Google Scholar
10. Huang, J., Virji, S., Weiller, B. H., Kaner, R. B. Chem. A Eur. J. 2004, 10, 1314–1319; https://doi.org/10.1002/chem.200305211.10.1002/chem.200305211Search in Google Scholar PubMed
11. Zhiwei, L., Wanlin, D., Baichen, L., Guangquan, M., Junjun, Z., Jiaping, Y., Jianshan, Y. J. Colloid Interface Sci. 2018, 525, 86–96. https://doi.org/10.1016/j.jcis.2018.04.065.Search in Google Scholar PubMed
12. Anil, D., Brian, E. C., Jingshu, G., Bokwon, Y., Robert, N. B., Bradley, M. M., Kristin, K., Wendell, P. G., Robert, L. W., Uzi, L., Terry, P. B. Nature 2013, 501, 399. https://doi.org/10.1038/nature12523.Search in Google Scholar PubMed
13. Evanoff, D. D.Jr., George, C. ChemPhysChem 2005, 6, 1221–1231; https://doi.org/10.1002/cphc.200500113.10.1002/cphc.200500113Search in Google Scholar
14. Zhang, L., Ming, H. W. Environ. Int. 2007, 33, 108–121; https://doi.org/10.1016/j.envint.2006.06.022.10.1016/j.envint.2006.06.022Search in Google Scholar
15. Schroeder, W. H., Munthe, J. Atmos. Environ. 1998, 32, 809–822. https://doi.org/10.1016/S1352-2310(97)00293-8.Search in Google Scholar
16. Wang, Q., Kima, D., Dionysiou, D. D., Sorial, G. A., Timberlake, D. Environ. Poll. 2004, 131, 323–336; https://doi.org/10.1016/j.envpol.2004.01.010.10.1016/j.envpol.2004.01.010Search in Google Scholar PubMed
17. Kumar, M., Avinash, P. Indian J. Occup. Environ. Med. 2012, 16, 40; https://doi.org/10.4103/0019-5278.111767.10.4103/0019-5278.99696Search in Google Scholar PubMed PubMed Central
18. Kudo, A., Shojiro, M. Water Sci. Technol. 1991, 23, 283–290; https://doi.org/10.2166/wst.1991.0426.10.2166/wst.1991.0426Search in Google Scholar
19. Ramesh, G. V., Radhakrishnan, T. P. ACS Appl. Mater. Interfaces 2011, 3, 988–994; https://doi.org/10.1021/am200023w.10.1021/am200023wSearch in Google Scholar PubMed
20. Wang, X., Shen, Y., Xie, A., Chen, S. Mater. Chem. Phys. 2013, 140, 487–492; https://doi.org/10.1016/j.matchemphys.2013.03.058.10.1016/j.matchemphys.2013.03.058Search in Google Scholar
21. Verma, R., Gupta, B. D. Food Chem. 2015, 568–575; https://doi.org/10.1016/j.foodchem.2014.06.045.10.1016/j.foodchem.2014.06.045Search in Google Scholar PubMed
22. Muthivhi, R., Parani, S., May, B., Oluwafemi, O. S. Nano Struct. Nano Obj. 2018, 13, 132–138; https://doi.org/10.1016/j.nanoso.2017.12.008.10.1016/j.nanoso.2017.12.008Search in Google Scholar
23. Viswanathan, P., Muralidaran, Y., Ragavan, G. In Nanostructures for oral medicine. Elsevier, 2017; pp. 173–201.10.1016/B978-0-323-47720-8.00008-0Search in Google Scholar
24. Bhowmick, B., Mondal, D., Maity, D., Rahaman Mollick, M. M., Kanti Bain, M., Kumar Bera, N., Rana, D., Chattopadhyay, S., Chattopadhyay, D. J. Appl. Polym. Sci. 2013, 129, 3551–3557; https://doi.org/10.1002/app.39124.10.1002/app.39124Search in Google Scholar
25. Poyraz, S., Cerkez, I., Huang, T. S., Liu, Z., Kang, L., Luo, J., Zhang, X. ACS Appl. Mater. Interfaces 2014, 6, 20025–20034; https://doi.org/10.1021/am505571m.10.1021/am505571mSearch in Google Scholar
26. Massoumi, B., Fathalipour, S., Massoudi, A., Hassanzadeh, M., Entezami, A. A. J. Appl. Polym. Sci. 2013, 130, 2780–2789; https://doi.org/10.1002/app.39448.10.1002/app.39448Search in Google Scholar
27. Sridevi, V., Malathi, S., Devi, C. S. Chem. Sci. J. 2011, 26, 1–6.Search in Google Scholar
28. Zeng, X. R., Ko, T. M. Polymer 1998, 39, 1187–1195; https://doi.org/10.1016/s0032-3861(97)00381-9.10.1016/S0032-3861(97)00381-9Search in Google Scholar
29. Fathalipour, S., Ahunbar, S. Polym. Sci. B 2019, 61, 663–669. https://doi.org/10.1134/S1560090419050038.Search in Google Scholar
30. Bogdanovic, U., Pasti, I., Ciric-Marjanovic, G., Mitric, M., Ahrenkiel, S. P., Vodnik, V. ACS Appl Mater. Interfaces 2015, 7, 28393–28403. https://doi.org/10.1021/acsami.5b09145.Search in Google Scholar PubMed
31. Jancy, M. E., Inbathamizh, L. Asian J. Pharmaceut. Clin. Res. 2012, 5, 159–162.Search in Google Scholar
32. Anandalakshmi, K., Venugobal, J., Ramasamy, V. Appl. Nanosci. 2016, 6, 399–408; https://doi.org/10.1007/s13204-015-0449-z.10.1007/s13204-015-0449-zSearch in Google Scholar
33. Monshi, A., Foroughi, M. R., Monshi, M. R. World J. Nano Sci. Eng. 2012, 2, 154–160; https://doi.org/10.4236/wjnse.2012.23020.10.4236/wjnse.2012.23020Search in Google Scholar
34. Wei, X. L., Fahlman, M., Epstein, A. J. Macromolecules 1999, 32, 3114–3117; https://doi.org/10.1021/ma981386p.10.1021/ma981386pSearch in Google Scholar
35. Wang, X., Shen, Y., Xie, A., Li, S., Cai, Y., Wang, Y., Shu, H. Biosens. Bioelectron. 2011, 26, 3063–3067; https://doi.org/10.1016/j.bios.2010.11.044.10.1016/j.bios.2010.11.044Search in Google Scholar
36. Wang, S., Rogachev, А. А., Yarmolenko, M. А., Rogachev, А. V., Xiaohong, J., Gaur, M. S., Luchnikov, P. A., Galtseva, O. V., Chizhik, S. A. Appl. Surf. Sci. 2018, 428, 1070–1078; https://doi.org/10.1016/j.apsusc.2017.09.225.10.1016/j.apsusc.2017.09.225Search in Google Scholar
37. Sen, T., Mishra, S., Shimpi, N. G. RSC Adv. 2016, 6, 42196–42222; https://doi.org/10.1039/c6ra03049a.10.1039/C6RA03049ASearch in Google Scholar
38. Ran, F., Tan, Y., Dong, W., Liu, Z., Kong, L., Kang, L. Polym. Adv. Technol. 2018, 29, 1697–705; https://doi.org/10.1002/pat.4273.10.1002/pat.4273Search in Google Scholar
39. Tamboli, M. S., Kulkarni, M. V., Patil, R. H., Gade, W. N., Navale, S. C., Kale, B. B. Colloids Surf. B Biointerfaces 2012, 92, 35–41; https://doi.org/10.1016/j.colsurfb.2011.11.006.10.1016/j.colsurfb.2011.11.006Search in Google Scholar
40. Khan, M. J., Husain, Q., Ansari, S. A. Appl. Microbiol. Biotechnol. 2013, 97, 1513–1522; https://doi.org/10.1007/s00253-012-4384-6.10.1007/s00253-012-4384-6Search in Google Scholar
41. Do Nascimento, G. M., Temperini, M. R. Int. J. Original Work Aspects Raman Spectrosc. Includ. High. Order Process. Brillouin Rayleigh Scatter. 2008, 39, 772–778; https://doi.org/10.1002/jrs.1841.10.1002/jrs.1841Search in Google Scholar
42. Bernard, C. M., Le Goff, A. H. Synth. Met. 1997, 85, 1145–1146; https://doi.org/10.1016/s0379-6779(97)80187-7.10.1016/S0379-6779(97)80187-7Search in Google Scholar
43. Rohom, A. B., Londhe, P. U., Mahapatra, S. K., Kulkarni, S. K., Chaure, N. B. High Perform. Polym. 2014, 26, 641–646; https://doi.org/10.1177/0954008314538081.10.1177/0954008314538081Search in Google Scholar
44. Darbha, G. K., Singh, A. K., Rai, U. S., Yu, E., Yu, H., Chandra Ray, P. J. Am. Chem. Soc. 2008, 130, 8038–8043; https://doi.org/10.1021/ja801412b.10.1021/ja801412bSearch in Google Scholar PubMed PubMed Central
45. Yu, H., Li, J., Luan, Y. Sci. Rep. 2018, 8, 1–10; https://doi.org/10.1038/s41598-018-19519-3.10.1038/s41598-018-19519-3Search in Google Scholar PubMed PubMed Central
46. Mathew, M., Sureshkumar, S., Sandhyarani, N. Colloids Surf. B Biointerfaces 2012, 93, 143–147; https://doi.org/10.1016/j.colsurfb.2011.12.028.10.1016/j.colsurfb.2011.12.028Search in Google Scholar PubMed
47. Ruecha, N., Rodthongkum, N., Cate, D. M., Volckens, J., Chailapakul, O., Henry, C. S. Anal. Chim. Acta 2015, 874, 40–48; https://doi.org/10.1016/j.aca.2015.02.064.10.1016/j.aca.2015.02.064Search in Google Scholar PubMed
48. Yang, Y., Kang, M., Fang, S., Wang, M., He, L., Zhao, J., Zhang, H., Zhang, Z. Sensor. Actuator. B Chem. 2015, 214, 63–69; https://doi.org/10.1016/j.snb.2015.02.127.10.1016/j.snb.2015.02.127Search in Google Scholar
49. Deshmukh, M. A., Patil, H. K., Bodkhe, G. A., Yasuzawa, M., Koinkar, P., Ramanaviciene, A., Shirsat, M. D., Ramanavicius, A. Sensor. Actuator. B Chem. 2018, 260, 331–338; https://doi.org/10.1016/j.snb.2017.12.160.10.1016/j.snb.2017.12.160Search in Google Scholar
50. Deshmukh, M. A., Patil, H. K., Bodkhe, G. A., Yasuzawa, M., Koinkar, P., Ramanavicius, A., Pandey, S., Shirsat, M. D. Colloid. Surface. Physicochem. Eng. Aspect. 2018, 537, 303–309; https://doi.org/10.1016/j.colsurfa.2017.10.026.10.1016/j.colsurfa.2017.10.026Search in Google Scholar
51. Sadeghi, M. M., Rad, A. S., Ardjmand, M., Mirabi, A. Synth. Met. 2018, 245, 1–9; https://doi.org/10.1016/j.synthmet.2018.08.001.10.1016/j.synthmet.2018.08.001Search in Google Scholar
52. Saikia, A., Karak, N. Mater. Today Commun. 2018, 1, 82–89; https://doi.org/10.1016/j.mtcomm.2017.12.020.10.1016/j.mtcomm.2017.12.020Search in Google Scholar
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