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Structural Characterization and Photoluminescent Behavior of CO3 Intercalated Zn-Fe Layered Double Hydroxide (LDH) and its Colloids

  • Asian Consortium ACCMS–International Conference ICMG 2020
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Abstract

Carbonate intercalated Zn-Fe layered double hydroxide (LDH) with Zn2+/Fe3+ molar ratios 2, 3 and 4 were synthesized by coprecipitation in order to study the photoluminescent (PL) properties of their colloids with various wt.% of LDH in formamide. These synthesized LDHs were characterized by various techniques including x-ray diffraction analysis (XRD), Fourier-transform infrared spectroscopy (FTIR), field emission scanning electron mMicroscopy (FE-SEM), energy-dispersive x-ray spectroscopy (EDS), high-resolution transmission electron microscopy (HR-TEM), and photoluminescence spectroscopy (PL). The rhombohedral phase and crystallite size of Zn-Fe LDH were confirmed by XRD. Crystallite size plays an important role in the PL mechanism. HR-TEM showed hexagonal nanosheets with 5–6 nm average particle size. To investigate the PL mechanism of pristine LDH and their colloids, these prepared Zn-Fe LDHs were exfoliated in formamide by varying their Zn2+/Fe3+ molar ratios (2,3, 4) and LDH concentration (0.2 wt.%, 0.4 wt.%, 0.6 wt.%, 0.8 wt.% of LDH). Results revealed that surface charge density and surface defects are the main reasons for PL generation in LDH colloids.

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References

  1. J.S. Valente, F. Tzompantzi, J. Prince, G.H. Jose, and C.R. Gomez, Appl. Catal. B: Environ. 90, 330 (2009).

    Article  CAS  Google Scholar 

  2. E. Dvininova, M. Ignata, P. Barvinschib, M.A. Smithersc, and E. Popovicia, J. Hazard. Mater. 177, 150 (2010).

    Article  CAS  Google Scholar 

  3. Z.M. Ni, S.J.L. Xia, F.F. Wang, and G.P. Xing, J. Colloid Interface Sci. 316, 284 (2007).

    Article  CAS  Google Scholar 

  4. C. Nethravathi, J.T. Rajamathi, N. Ravishankar, C. Shivakumara, and M. Rajamathi, Langmuir 24, 8240 (2008).

    Article  CAS  Google Scholar 

  5. Y. Zhao, M. Wei, L. Jun, Z.L. Wang, and X. Duan, ACS Nano 3, 4009 (2009).

    Article  CAS  Google Scholar 

  6. S.J. Palmer and R.L. Frost, Ind. Eng. Chem. Res. 49, 8969 (2010).

    Article  CAS  Google Scholar 

  7. V. Prevot, N. Caperaa, C. Taviot-Gueho, and C. Forano, Cryst. Growth Des. 9, 3646 (2009).

    Article  CAS  Google Scholar 

  8. B. Zümreoglu-Karan and A. Ay, Chem. Pap. 66, 1 (2012).

    Article  CAS  Google Scholar 

  9. J.-H. Choy, J.-M. Oh, M. Park, K.-M. Sohn, and J.-W. Kim, Adv. Mater. 16, 1181 (2004).

    Article  CAS  Google Scholar 

  10. L. Mohapatra and K. Parida, J. Mater. Chem. A 4, 10744 (2016).

    Article  CAS  Google Scholar 

  11. F. Li and X. Duan, Layered Double Hydroxides, ed. X. Duan and D.G. Evans (Berlin: Springer, 2006), p. 193.

    Chapter  Google Scholar 

  12. C. Del Hoyo, Appl. Clay Sci. (2007). https://doi.org/10.1016/j.clay.2006.06.010.

    Article  Google Scholar 

  13. C. Aguzzi, P. Cerezo, C. Viseras, and C. Caramella, Appl. Clay Sci. 36, 22–36 (2007).

    Article  CAS  Google Scholar 

  14. M.R. Berber, I.H. Hafez, K. Minagawa, T. Mori, and M. Tanaka, Advances in Nanocomposite Technology, ed. A.A. Hashim (InTech: Rijeka, 2011), p. 335.

    Google Scholar 

  15. P. Nalawade, B. Aware, V.J. Kadam, and R.S. Hirlekar, J. Sci. Ind. Res. 68, 267 (2009).

    CAS  Google Scholar 

  16. J.-H. Choy, S.-J. Choi, O. Jae-Min, and T. Park, Appl. Clay Sci. 36, 122 (2007).

    Article  CAS  Google Scholar 

  17. S. Aisawa, N. Higashiyama, S. Takahashi, H. Hirahara, D. Ikematsu, H. Kondo, H. Nakayama, and E. Narita, Appl. Clay Sci. 35, 146 (2007).

    Article  CAS  Google Scholar 

  18. S. Aisawa, H. Kudo, T. Hoshi, S. Takahashi, H. Hirahara, Y. Umetsu, and E. Narita, J. Solid State Chem. 177, 3987 (2004).

    Article  CAS  Google Scholar 

  19. J.-C. Dupin, H. Martinez, C. Guimon, E. Dumitriu, and I. Fechete, Appl. Clay Sci. 27, 95 (2004).

    Article  CAS  Google Scholar 

  20. E.M. Seftel, E. Dvininov, D. Lutic, E. Popovici, and C. Ciocoiu, J. Optoelectron. Adv. Mater. 7, 2869 (2005).

    CAS  Google Scholar 

  21. R.P. Wijitwongwan, S.G. Intasa-ard, and M. Ogawa, Chem. Eng. 3, 68 (2019).

    CAS  Google Scholar 

  22. P.S. Braterman, Z.P. Xu, and F. Yarberry, In Handbook of Layered Materials, ed. S.M. Auerbach, K.A. Carrado, and P.K. Dutta (New York: Marcel Decker Inc., 2004), p. 374.

    Google Scholar 

  23. E.L. Crepaldi, P.C. Pavan, and J.B. Valim, J. Braz. Chem. Soc. 11, 64 (2000).

    Article  CAS  Google Scholar 

  24. K.M. Parida and L. Mohapatra, Chem. Eng. J. 179, 131 (2012).

    Article  CAS  Google Scholar 

  25. C.R. Gordijo, V.R.L. Constantino, and D. de Oliveira Silva, J. Solid State Chem. 180, 1967 (2007).

    Article  CAS  Google Scholar 

  26. F. Cavani, F. Trifiro, and A. Vaccari, Catal. Today 11, 173 (1991).

    Article  CAS  Google Scholar 

  27. M.S. Gasser, Colloids Surf. B: Biointerfaces 73, 103 (2009).

    Article  CAS  Google Scholar 

  28. N. Baliarsingh, L. Mohapatra, and K. Parida, J. Mater. Chem. A 1, 4236 (2013).

    Article  CAS  Google Scholar 

  29. N. Baliarsingh, K.M. Parida, and G.C. Pradhan, Ind. Eng. Chem. Res. 53, 3834 (2014).

    Article  CAS  Google Scholar 

  30. Y.C. Kang, H.S. Roh, D.J. Seo, and S.B. Park, J. Mater. Sci. Lett. 19, 1225 (2000).

    Article  CAS  Google Scholar 

  31. Huang-Yu Chen, H.-L. Lai, R.-Y. Yang, and S.-J. Chang, J. Mater. Sci.: Mater. Electron. 27, 2963 (2016).

    CAS  Google Scholar 

  32. V. Choudhary, R. Jha, and P.A. Choudhary, J. Chem. Sci. 117, 635 (2005).

    Article  CAS  Google Scholar 

  33. Z. Liu, R. Ma, M. Osada, N. Iyi, Y. Ebina, K. Takada, and T. Sasaki, J. Am. Chem. Soc. 128, 4872 (2006).

    Article  CAS  Google Scholar 

  34. K. Okamoto, T. Sasaki, T. Fujita, and N. Iyi, J. Mater. Chem. 16, 1608 (2006).

    Article  CAS  Google Scholar 

  35. F. Leroux and C. Taviot-Guého, J. Mater. Chem. 15, 3628 (2005).

    Article  CAS  Google Scholar 

  36. W. Chen, L. Feng, and Q. Baojun, Chem. Mater. 16, 368 (2004).

    Article  CAS  Google Scholar 

  37. L. Qiu and Q. Baojun, J. Colloid Interface Sci. 301, 347 (2006).

    Article  CAS  Google Scholar 

  38. B.R. Venugopal, N. Ravishankar, C.R. Perrey, C. Shivakumara, and M. Rajamathi, J. Phys. Chem. B 110, 772 (2006).

    Article  CAS  Google Scholar 

  39. L. Li, R. Ma, N. Iyi, Y. Ebina, K. Takada, and T. Sasaki, Chem. Commun. 29, 3125 (2006).

    Article  CAS  Google Scholar 

  40. R. Ma, Z. Liu, L. Li, N. Iyi, and T. Sasaki, J. Mater. Chem. 16, 3809 (2006).

    Article  CAS  Google Scholar 

  41. B. Li, J. He, D.G. Evans, and X. Duan, J. Phys. Chem. Solids 67, 1067 (2006).

    Article  CAS  Google Scholar 

  42. H. Zhang, R. Qi, D.G. Evans, and X. Duan, J. Solid State Chem. 177, 772 (2004).

    Article  CAS  Google Scholar 

  43. G. Fan, F. Li, D.G. Evans, and X. Duan, Chem. Soc. Rev. 43, 7040 (2014).

    Article  CAS  Google Scholar 

  44. Z. Wang, F. Liu, and L. Chao, Biosens. Bioelectron. 60, 237 (2014).

    Article  CAS  Google Scholar 

  45. E. Rauwel, A. Galeckas, P. Rauwel, and H. Fjellvåg, Adv. Func. Mater. 22, 1174 (2012).

    Article  CAS  Google Scholar 

  46. Y. Zhao, J.-G. Li, M. Guo, and X. Yang, J. Mater. Chem. C 1, 3584 (2013).

    Article  CAS  Google Scholar 

  47. X. Gao, X. Li, and Yu Weidong, J. Phys. Chem. B 109, 1155 (2005).

    Article  CAS  Google Scholar 

  48. R.R. Piticescu, R.M. Piticescu, and C.J. Monty, J. Eur. Ceram. Soc. 26, 2979 (2006).

    Article  CAS  Google Scholar 

  49. H.-M. Xiong, X. Yang, Q.-G. Ren, and Y.-Y. Xia, J. Am. Chem. Soc. 130, 7522 (2008).

    Article  CAS  Google Scholar 

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Correspondence to Sushama M. Giripunje.

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Thite, V., Giripunje, S.M. Structural Characterization and Photoluminescent Behavior of CO3 Intercalated Zn-Fe Layered Double Hydroxide (LDH) and its Colloids. J. Electron. Mater. 50, 1601–1607 (2021). https://doi.org/10.1007/s11664-020-08356-8

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