Elsevier

Precambrian Research

Volume 350, November 2020, 105893
Precambrian Research

Amalgamation between the Yangtze and Cathaysia blocks in South China: Evidence from the ophiolite geochemistry

https://doi.org/10.1016/j.precamres.2020.105893Get rights and content

Highlights

  • The Xiwan peridotites underwent an initial melt extraction at 1.8–2.1 Ga.

  • The Fuchuan peridotites were formed by second stage melting of a depleted mantle induced by slab fluids.

  • The ophiolites were formed in a subduction-related setting.

Abstract

Neoproterozoic ophiolites in the southeastern margin of the Yangtze Block record tectonic evolution of South China. The ∼1.0 Ga Xiwan ophiolite and the ca. 830 Ma Fuchuan ophiolite indicate a long-term assembly of the Yangtze and Cathaysia blocks during the Neoproterozoic time. Peridotites from the Xiwan ophiolite show high Al2O3 (1.24–2.67 wt%) and low MgO contents (39.61–44.26 wt%), similar to the abyssal and back-arc peridotites that experienced low degrees of partial melting. Their U-shaped REE patterns and HFSE enrichment indicate weak melt metasomatism. Whole rock 187Re/188Os (0.09–0.29) and 187Os/188Os ratios (0.11526–0.12193) yield a melt-extraction age of 1.8–2.1 Ga. However, peridotites from the Fuchuan ophiolite are more refractory and have low Al2O3 (0.51–0.95 wt%) and high MgO contents (43.99–48.24 wt%), similar to the forearc peridotites that underwent high degrees of melt extraction. Their 187Re/188Os (0.01–1.08) and 187Os/188Os (0.11852–0.12867) variations may have resulted from fluxed melting induced by the subduction-related fluids. The peridotites, in combination with the overlying mafic oceanic crustal rocks, suggest that the Xiwan and Fuchuan ophiolites are SSZ-type ophiolites which were formed in back-arc and forearc settings, respectively, followed by the collision between the Yangtze and Cathaysia blocks at ca. 830 Ma.

Introduction

Ophiolites in orogenic belts represent fragments of ancient oceanic lithosphere (Dewey and Bird, 1971, Nicolas, 1989, Lister and Forster, 2009, Dilek and Furnes, 2011), and record whole or part of geological history related to the tectonic evolution of oceanic basin during the Wilson cycle (Moores and Vine, 1971). They carry unique information of the disappeared oceans, thus are important for the paleo-plate reconstruction (Taylor and McLennan, 1995, Dilek and Furnes, 2011, Hébert et al., 2012, Kusky et al., 2018). A complete ophiolite succession includes, from bottom to top, mantle peridotite, ultramafic–mafic cumulate, isotropic gabbro, sheeted dike, pillow lava associated with minor plagiogranite that are overlain by pelagic sediments (Moores, 2002, Dilek and Robinson, 2003, Kusky, 2004, Pearce, 2014). Ophiolites are generally classified as supra-subduction zone (SSZ) and mid-ocean ridge (MOR) types (Dilek and Furnes, 2011, Pearce, 2014), and peridotite from the SSZ-type ophiolite is more refractory than that from the MOR-type ophiolite (Liu et al., 2019).

The Neoproterozoic Jiangnan Fold Belt is a suture zone that represents the assembly between the Yangtze and Cathaysia blocks. Two ophiolite suites have been recognized at the Xiwan and Fuchuan regions in the eastern segment of the Jiangnan Fold Belt (Figs. 1 and 2a). Zircon U-Pb dating revealed that they were formed at ∼1.0 Ga and ∼830 Ma, respectively (Li et al., 1994, Li et al., 2017, Ding, 2008, Gao et al., 2009, Zhang et al., 2012a, Zhang et al., 2013, Wang et al., 2015a, Sun et al., 2018). The Xiwan ophiolite is classified as an SSZ-type ophiolite, which was proposed to have been formed in various tectonic settings, including forearc basin (Sun et al., 2018), back-arc basin (Zhou et al., 1989, Li et al., 1997, Wang et al., 2015a), island arc (Xing, 1990, Chen et al., 1991), as well as ridge-subduction (Zhang et al., 2015). Similarly, the Fuchuan ophiolite also displays subduction-related lithological and geochemical features (Ding, 2008, Zhang et al., 2012a, Sun et al., 2018). The coeval bimodal dike swarms, gabbro, spilite, granite and sedimentary sequences suggest that the Fuchuan ophiolite was probably formed in forearc (Zhang et al., 2013) or back-arc settings (Zhang et al., 2012a, Sun et al., 2018). Compared with basaltic to granitic rocks, peridotite can provide direct information for formation age, petrological and geochemical features, as well as evolutionary history of the mantle source (Irvine et al., 2001, Yuan et al., 2007, Schulte et al., 2009, Harvey et al., 2010, Liu et al., 2012, Liu et al., 2019, Ionov et al., 2015, Hu et al., 2020). Although extensive studies have been carried out on the mafic rocks of the ophiolites in the eastern Jiangnan Fold Belt, the mantle peridotites have not been well addressed. The nature of the mantle source, the tectonic settings and emplacement dynamics of the ophiolites are still unclear.

In this paper, we present whole-rock major and trace elements and Re-Os isotopes for the mantle peridotites from the above two sets of ophiolites, as well as zircon U-Pb ages for the granite and gabbro from the Fuchuan ophiolite. The new results show that the Xiwan and Fuchuan ophiolites are SSZ-type ophiolites which were formed in back-arc and forearc settings, respectively. The mantle peridotites underwent variable degrees of depletion and metasomatism, and indicate the multistage assembly of South China.

Section snippets

Regional geology

South China comprises the Yangtze Block to the northwest and the Cathaysia Block to the southeast, which were amalgamated together along the Jiangnan Fold Belt during the Neoproterozoic (Fig. 1; Zhao and Cawood, 2012). The fold belt consists of the late Mesoproterozoic to early Neoproterozoic sedimentary and volcanic rocks that underwent strong deformation and greenschist facies metamorphism (Zhao et al., 2011, Wang et al., 2013a). The late Mesoproterozoic sequences, such as the Tieshajie

Zircon U-Pb dating

Representative zircon grains were separated using heavy liquid and magnetic techniques, mounted in epoxy, polished, coated with gold, and photographed in transmitted and reflected light. Cathodoluminescence (CL) images were used to reveal internal structures so as to select zircon grains for U-Pb dating. U-Pb isotopic ratios were measured using the Cameca IMS 1280 large-radius SIMS at the Institute of Geology and Geophysics (IGG), Chinese Academy of Sciences (CAS), Beijing. Analytical

Zircon U-Pb ages

Two samples from the granites and gabbros in the Fuchuan ophiolite were selected for zircon separation. Zircons from the granite sample SHE7 are subhedral to euhedral, colorless and transparent, 90–230 µm long with aspect ratios of 1:1–1:4. Most grains show unzoned or faintly zoned interiors surrounded by oscillatory-zoned rims, indicating magmatic origin. Some zircons contain rounded and faintly zoned core (Fig. 4a). They display high U (140–631 ppm) and Th concentrations (36–220 ppm) with

The effect of serpentinization

Serpentinization is ubiquitous in ultramafic rocks, and converts olivine and pyroxene to serpentine and magnetite, and changes whole rock geochemical compositions (Rudnick and Walker, 2009). Peridotites from the Xiwan and Fuchuan ophiolites underwent strong serpentinization as indicated by their lithologies (Fig. 3) and high loss on ignition (11.08–15.51 wt%; Table 2), which resulted in collateral losses in MgO (Snow and Dick, 1995, Paulick et al., 2006, Kodolányi et al., 2012). It should be

Conclusions

  • (1)

    The peridotites from the ∼1.0 Ga Xiwan ophiolite are chemically similar to the abyssal and back-arc peridotites, and experienced partial melting at 1.8–2.1 Ga. The peridotites from the ∼830 Ma Fuchuan ophiolite are akin to the forearc peridotites, and represent a more refractory depleted mantle source after two stages of partial melting.

  • (2)

    Both the Xiwan and Fuchuan ophiolites are SSZ-type ophiolites that were formed in back-arc and forearc settings, respectively. The united South China Craton was

Declaration of Competing Interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Acknowledgments

We thank Prof. Zhu-Yin Chu for his assistance in Re-Os isotope analyses and Dr. Wen-Jun Hu for his constructive comments that helped to clarify our discussion. Two anonymous reviewers are highly appreciated for their helpful comments. This work was substantially supported by the National Nature Science Foundation of China (41773027 and 41973031) and MOST Special Fund from the State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences.

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