On the basis of an investigation of the catalytic characteristics of iron-containing catalysts deposited on carbon nanotubes (CNT) and zirconium dioxide in the steam reforming of bioethanol at 300-500 °C it was shown that Fe/CNT exhibits high activity and productivity with respect to hydrogen at relatively low temperature. At this catalyst high conversion of ethanol (94%) and high selectivity for hydrogen (50%) are achieved at 400 °C.
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The work was carried out with partial financial support from a targeted program of scientific investigations of the National Academy of Sciences of Ukraine “Development of scientific bases for hydrogen production, storage, and use in autonomous energy supply systems.” The authors express their gratitude to I. B. Bychko for providing samples of catalysts based on carbon nanotubes and to E. M. Moroz (G. K. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences) for the X-ray investigations.
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Translated from Teoreticheskaya i Eksperimental’naya Khimiya, Vol. 56, No. 3, pp. 181-186, May-June, 2020.
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Dolgikh, L.Y., Staraya, L.O., Stolyarchuk, I.L. et al. Low-Temperature Steam Reforming of Ethanol Over Iron Catalysts on Oxide and Carbon Supports. Theor Exp Chem 56, 192–198 (2020). https://doi.org/10.1007/s11237-020-09651-5
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DOI: https://doi.org/10.1007/s11237-020-09651-5