Glycerol pressurized to 2 kbar and hyperquenched from the bulk liquid at rates of about $-10000\mathrm{K}/\mathrm{s}$, has been frozen to an extreme out-of-equilibrium state. As compared to conventionally cooled melts, the resulting material exhibits lower orientational correlations, enabling the observation of a secondary relaxation peak in the ambient-pressure dielectric response. The hyperquenching rather than the pressurizing part of the preparation protocol induces the observed structural changes. These vanish entirely only well above the glass transition temperature of the equilibrium liquid and are evidence for strong similarities between hyperquenched and vapor-deposited glass formers.

• Received 1 April 2020
• Accepted 7 July 2020

DOI:https://doi.org/10.1103/PhysRevLett.125.065503