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Application of zirconium-based metal–organic frameworks for micro-extraction by packed sorbent of urinary trans, trans-muconic acid

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Abstract

In this study, we report for the first time developing an analytical method based on three metal–organic frameworks (MOF) including UiO-66, UiO-66-NH2 and UiO-66-NH2 @ Fe3O4-SiO2 in micro-extraction by packed sorbent (MEPS) extracting trans, trans-muconic acid (tt-MA) in urine. The FT-IR, XRD and FE-SEM techniques were used for characterization of the synthesized MOFs. The effects of some analytical parameters were investigated on the MEPS performance using central composite design by response surface methodology. The findings demonstrated that the sample volume and desorption cycles were the most important parameters for the extraction of tt-MA using UiO-MEPS procedure combined with high-performance liquid chromatography (HPLC). The limit of quantification (LOQ) of UiO-MEPS-HPLC procedure for UiO-66, UiO-66-NH2 and UiO-66-NH2 @ Fe3O4-SiO2 core–shell was 0.005, 0.005 and 0.003 µg mL−1, respectively. Under optimal conditions, the UiO-MEPS-HPLC method offered a good performance for extracting tt-MA from urine samples (UiO-66, UiO-66-NH2 and UiO-66-NH2 @ Fe3O4-SiO2 core–shell: 86%, 0.95% and 98.5%, respectively, RSD < 3.54%). The results indicated that this technique was a sensitive, fast and reusable method and can be applied to extract and determine trace amounts of urinary tt-MA in the urine matrix.

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Abbreviations

T,t- MA:

Trans, trans muconic acid

ACGIH:

American conference of governmental industrial hygienists

LLE:

Liquid-liquid extraction

SPE:

Solid phase extraction

HF- LPME:

Hollow-fiber liquid-phase micro- extraction

DLLME:

Dispersive liquid–liquid micro extraction

SLM:

Supported liquid membrane

MEPS:

Micro extraction by packed sorbent

MOF:

Metal- organic frameworks

UiO:

University of Oslo

HCl:

Hydrochloric acid

APTES:

3- Amino propyl triethoxysilane

DMF:

Dimethyl formamide

TEOS:

Tetraethylorthosilicate

CCD:

Central composite design

RSM:

Response surface methodology

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Acknowledgment

This work is a part of a Ph.D. dissertation (No. 9709275744) at Hamadan University of Medical Sciences, Iran. The authors would like to thank the Occupational Health and Safety Research Center, Hamadan University of Medical Sciences of Iran for financial support.

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Authors and Affiliations

  1. Center of Excellence for Occupational Health, Occupational Health and Safety Research Center, School of Public Health, Hamadan University of Medical Sciences, Hamadan, Iran

    Razzagh Rahimpoor, Abdulrahman Bahrami & Farshid Ghorbani Shahna

  2. Department of Chemistry, Bu-Ali-Sina University, Hamadan, Iran

    Davood Nematollahi

  3. Department of Biostatistics, School of Public Health and Research Center for Health Sciences, Hamadan University of Medical Sciences, Hamadan, Iran

    Maryam Farhadian

  4. Department of Occupational Health, School of public Health, Hamadan University of Medical Sciences, Hamadan, 65175-4171, 6517838695, Iran

    Abdulrahman Bahrami

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  1. Razzagh Rahimpoor
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  2. Abdulrahman Bahrami
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  4. Farshid Ghorbani Shahna
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Correspondence to Abdulrahman Bahrami.

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Rahimpoor, R., Bahrami, A., Nematollahi, D. et al. Application of zirconium-based metal–organic frameworks for micro-extraction by packed sorbent of urinary trans, trans-muconic acid. J IRAN CHEM SOC 17, 2345–2358 (2020). https://doi.org/10.1007/s13738-020-01930-1

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