Abstract
Knowledge of the stability limit and critical point of the H2–CO2–CH4–CO–H2O system is significant for the management and optimization of the gasification systems of organic substances in supercritical water. We report thermodynamic calculations of the stability limits and critical points of the H2–CO2–CH4–CO–H2O system based on the cubic equation of state. Prior to the calculations of the quinary system, phase equilibria of the H2–CO2 and CH4–C2H6 systems and critical points of the CO2–H2O system were calculated and compared with experimental data. The calculated temperature stability limit decreased as the mole fraction of H2 in the quinary system increased. The calculated critical point of the (0.50 H2 + 0.01 CO2 + 0.02 CH4 + 0.02 CO + 0.45 H2O) mixture (in mole fractions) was at about 610 K and 300 MPa. The increase in the mole fraction of CO2 or H2O and the corresponding decrease of the mole fraction of H2 in the quinary system would make the critical temperature and pressure change significantly. The calculations indicated that all the p–T states of the quinary system in our previous work were stable.
Similar content being viewed by others
References
B. Bai, Y. Liu, Q. Wang, J. Zou, H. Zhang, H. Jin, X. Li, Renew. Energy 135, 32 (2019)
X. Zhao, H. Jin, Y. Chen, Z. Ge, Comput. Math. Appl. (2020). https://doi.org/10.1016/j.camwa.2019.11.012
X. Zhao, H. Jin, Int. J. Heat Mass Transf. 133, 718 (2019)
H. Jin, H. Wang, Z. Wu, Z. Ren, Z. Ou, Renew. Energy 138, 11 (2019)
S. Cheng, F. Shang, W. Ma, H. Jin, N. Sakoda, X. Zhang, L. Guo, J. Chem. Eng. Data 64, 1693 (2019)
S. Cheng, F. Shang, W. Ma, H. Jin, N. Sakoda, X. Zhang, L. Guo, J. Chem. Eng. Data 64, 4024 (2019)
X. Yang, J. Xu, S. Wu, M. Yu, B. Hu, B. Cao, J. Li, Int. J. Hydrog. Energy 43, 10980 (2018)
Y. Liu, W. Hong, B. Cao, Energy 188, 116091 (2020)
Y. Liu, B. Cao, Int. J. Hydrog. Energy 45, 4297 (2020)
X. Yang, Y. Feng, J. Jin, Y. Liu, B. Cao, J. Mol. Liq. 299, 112133 (2020)
X. Yang, C. Duan, J. Xu, Y. Liu, B. Cao, Int. J. Heat Mass Transf. 135, 413 (2019)
S. Cheng, F. Shang, W. Ma, H. Jin, N. Sakoda, X. Zhang, L. Guo, J. Chem. Eng. Data (2020). https://doi.org/10.1021/acs.jced.0c00176
X. Yang, Y. Feng, J. Xu, J. Jin, Y. Liu, B. Cao, Appl. Therm. Eng. 162, 114228 (2019)
A. Baiker, Chem. Rev. 99, 453 (1999)
P.E. Savage, S. Gopalan, T.I. Mizan, C.J. Martino, E.E. Brock, AIChE J. 41, 1723 (1995)
M.J. Burk, S. Feng, M.F. Gross, W. Tumas, J. Am. Chem. Soc. 117, 8277 (1995)
C.Y. Tsang, W.B. Streett, Chem. Eng. Sci. 36, 993 (1981)
C.Y. Tsang, P. Clancy, J.C.G. Galado, W.B. Streett, Chem. Eng. Commun. 6, 365 (1980)
C.Y. Tsang, W.B. Streett, Fluid Phase Equilib. 6, 261 (1981)
T.M. Seward, E.U. Franck, Ber. Bunsenges. Phys. Chem. 85, 2 (1981)
H.G. Donnelly, D.L. Katz, Ind. Eng. Chem. 46, 511 (1954)
K. Tödheide, E.U. Franck, Z. Phys. Chem. 37, 387 (1963)
S. Takenouchi, G.C. Kennedy, Am. J. Sci. 262, 1055 (1964)
D. Chokappa, P. Clancy, W.B. Streett, U.K. Deiters, A. Heintz, Chem. Eng. Sci. 40, 1831 (1985)
N. Sakoda, M. Kohno, Y. Takata, J. Therm. Sci. Technol. 8, 603 (2013)
J.W. Qian, J.N. Jaubert, R. Privat, J. Supercrit. Fluids 75, 58 (2013)
T. Endo, D. Arai, M. Uematsu, B-hen 59, 529 (1993)
M.L. Michelsen, Fluid Phase Equilib. 9, 1 (1982)
M.L. Michelsen, Fluid Phase Equilib. 9, 21 (1982)
G. Soave, Chem. Eng. Sci. 27, 1197 (1972)
P.J. Mohr, D.B. Newell, B.N. Taylor, J. Phys. Chem. Ref. Data 45, 043102 (2016)
D.Y. Peng, D.B. Robinson, Ind. Eng. Chem. Fund. 15, 59 (1976)
J. Meija, T.B. Coplen, M. Berglund, W.A. Brand, P. De Bièvre, M. Gröning, N.E. Holden, J. Irrgeher, R.D. Loss, T. Walczyk, T. Prohaska, Pure Appl. Chem. 88, 265 (2016)
I. Martinez, Properties of gases. http://webserver.dmt.upm.es/~isidoro/dat1/eGAS.pdf. Accessed 10 Nov 2017
B.E. Poling, J.M. Prausnitz, J.P. O’Connell, The Properties of Gases and Liquids, 5th edn. (McGraw-Hill: New York, 2001) Appendix A, Section A, pp. A.5–A.19
J.W. Leachman, R.T. Jacobsen, S.G. Penoncello, E.W. Lemmon, J. Phys. Chem. Ref. Data 38, 721 (2009)
R. Span, W. Wagner, J. Phys. Chem. Ref. Data 25, 1509 (1996)
U. Setzmann, W. Wagner, J. Phys. Chem. Ref. Data 20, 1061 (1991)
R.D. Goodwin, J. Phys. Chem. Ref. Data 14, 849 (1985)
W. Wagner, A. Pruss, J. Phys. Chem. Ref. Data 31, 387 (2002)
D. Bücker, W. Wagner, J. Phys. Chem. Ref. Data 35, 205 (2006)
A. Heintz, W.B. Streett, Bunsenges. Phys. Chem. 87, 298 (1983)
M.L. Michelsen, Fluid Phase Equilib. 4, 1 (1980)
R.A. Heidemann, A.M. Khalil, AIChE J. 26, 769 (1980)
M.L. Michelsen, R.A. Heidemann, AIChE J. 27, 521 (1981)
M. Ruhemann, Proc. R. Soc. A 171, 121 (1939)
J. Davalos, W.R. Anderson, R.E. Phelps, A.J. Kidnay, J. Chem. Eng. Data 21, 81 (1976)
M.K. Gupta, G.C. Gardner, M.J. Hegarty, A.J. Kidnay, J. Chem. Eng. Data 25, 313 (1980)
I. Wichterle, R. Kobayashi, J. Chem. Eng. Data 17, 9 (1972)
C. Zhu, X. Liu, S. Xue, M. He, J. Chem. Eng. Data (2020). https://doi.org/10.1021/acs.jced.0c00236
C.P. Hicks, C.L. Young, Chem. Rev. 75, 119 (1975)
Acknowledgment
This work was supported by the National Key R&D Program of China (Contract no. 2016YFB0600100).
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Cheng, S., Ma, W., Sakoda, N. et al. Thermodynamic Calculations of the Critical Points of the H2–CO2–CH4–CO–H2O System. Int J Thermophys 41, 141 (2020). https://doi.org/10.1007/s10765-020-02725-5
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s10765-020-02725-5