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Recent Advances on the Preparation and Catalytic Applications of Metal Complexes Supported-Mesoporous Silica MCM-41 (Review)

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Abstract

Heterogeneous catalysts were used in several production processes for the synthesis of different products such as chemicals, drugs, energy resources, fuels and other specific products. In recent years, mesoporous silica, in particular MCM-41 was widely used in several fields, including catalysis and catalytic support, due to its remarkable textural properties. This material cannot be used directly in catalysis due to its inner surface containing only silanol groups. Therefore, several attempts were proposed in order to obtain an effective catalyst. The immobilization of metal complexes on the surface of mesoporous silica is one of the most popular methods. The metal complexes immobilized on the mesoporous silica MCM-41 exhibit significant catalytic activities due to the increased dispersion of the active sites and the faster diffusion of large organic molecules. The strong interactions between the metal and the ligand generate significant stability for this kind of catalyst, which allows them to be reused in several cycles without losing their efficiency. This review mainly discusses the immobilization strategies of different metal complexes supported on the mesoporous silica MCM-41. A recent study was presented and well detailed based on the different preparation methods, catalytic applications and the stability of metal complexes supported on mesoporous silica MCM-41.

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Copyright 2017 WILEY-VCH Verlag GmbH & Co. KGaA,Weinheim

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Authors and Affiliations

  1. Département de Génie des Matériaux, Faculté de Chimie, Université des Sciences et de la Technologie Mohamed Boudiaf, El-Mnaouer, BP 1505, Oran, Algeria

    Fatima Habeche, Fadila Benali, Amel Mekki & Bouhadjar Boukoussa

  2. Laboratoire de Chimie des Matériaux LCM, Université Oran1 Ahmed Ben Bella, El-Mnaouer, BP 1524, 31000, Oran, Algeria

    Mohammed Hachemaoui, Adel Mokhtar & Bouhadjar Boukoussa

  3. Département Génie des Procédés, Institut des Sciences et Technologies, Centre Universitaire Ahmed Zabana Relizane, Relizane, Algeria

    Adel Mokhtar

  4. Laboratoire de Chimie des Polymères, Université Oran1 Ahmed Ben Bella, El-Mnaouer, BP 1524, 31000, Oran, Algeria

    Karim Chikh & Zakaria Cherifi

  5. Laboratoire de chimie physique macromoléculaire, Département de chimie, Université Oran1 Ahmed Ben Bella, El-Mnaouer, BP 1524, 31100, Oran, Algeria

    Farouk Zaoui

  6. Centre de Recherche Scientifique et Technique en Analyses Physico-Chimique (CRAPC), Siege ex-Pasna Zone Industrielle, Bou-Ismail, BP 384, CP 42004, Tipaza, Algeria

    Zakaria Cherifi

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  1. Fatima Habeche
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Habeche, F., Hachemaoui, M., Mokhtar, A. et al. Recent Advances on the Preparation and Catalytic Applications of Metal Complexes Supported-Mesoporous Silica MCM-41 (Review). J Inorg Organomet Polym 30, 4245–4268 (2020). https://doi.org/10.1007/s10904-020-01689-1

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