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Comparative Analysis of Sun Protection Characteristics of Nanocrystalline Cerium Dioxide

  • SYNTHESIS AND PROPERTIES OF INORGANIC COMPOUNDS
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Abstract

In spite of good sun protection characteristics, nanocrystalline TiO2 and ZnO widely used as inorganic UV filters can display a negative effect on skin. Nanocrystalline cerium dioxide was proposed as a promising component of sun protection cosmetics, however, no quantitative comparison of sun protection characteristics of CeO2 with other metal oxides was carried out until now. In this work, we experimentally determined for the first time the values of sun protection factor and UVA protection factor for CeO2 nanoparticles in accordance with the State Standard ISO 24443-2016 and compared them with characteristics of TiO2 and ZnO. Effect of size factor on CeO2 sun protection characteristics has been found.

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REFERENCES

  1. S. González, M. Fernández-Lorente, and Y. Gilaberte-Calzada, Clin. Dermatol. 26, 614 (2008). https://doi.org/10.1016/j.clindermatol.2007.09.010

    Article  PubMed  Google Scholar 

  2. T. G. Smijs and S. Pavel, Nanotechnol. Sci. Appl. 4, 95 (2011). https://doi.org/10.2147/NSA.S19419

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  3. https://ec.europa.eu/health/sites/health/files/scientific_committees/consumer_safety/docs/sccs_o_202.pdf

  4. https://ec.europa.eu/health/sites/health/files/scientific_committees/consumer_safety/docs/sccs_o_206.pdf

  5. https://ec.europa.eu/health/scientific_committees/consumer_safety/docs/sccs_o_103.pdf

  6. N. M. Zholobak, V. K. Ivanov, A. B. Shcherbakov, et al., J. Photochem. Photobiol. B 102, 32 (2011). https://doi.org/10.1016/j.jphotobiol.2010.09.002

    Article  CAS  PubMed  Google Scholar 

  7. F. Caputo, M. De Nicola, A. Sienkiewicz, et al., Nanoscale 7, 15643 (2015). https://doi.org/10.1039/c5nr03767k

    Article  CAS  PubMed  Google Scholar 

  8. S. A. Kuznetsova, A. A. Gordeev, and D. A. Fedorishin, Nanosystems: Phys. Chem. Math. 10, 456 (2019). https://doi.org/10.17586/2220-8054-2019-10-4-456-465

  9. T. Herrling, M. Seifert, and K. Jung, SOFW-J 139 (5), 10 (2013). https://doi.org/10.1002/adma.201302511

    Article  CAS  Google Scholar 

  10. A. B. Shcherbakov, N. M. Zholobak, and V. K. Ivanov, Cerium Oxide (CeO2): Synthesis. Properties and Applications (Elsevier, 2020) p. 279. https://doi.org/10.1016/C2017-0-02724-6

  11. A. P. Popov, A. V. Zvyagin, J. Lademann, et al., J. Biomed. Nanotechnol. 6, 432 (2010). https://doi.org/10.1166/jbn.2010.1144

    Article  CAS  PubMed  Google Scholar 

  12. J. F. Muth, R. M. Kolbas, A. K. Sharma, et al., J. Appl. Phys. 85, 7884 (1999). https://doi.org/10.1063/1.370601

    Article  CAS  Google Scholar 

  13. D. P. Edward and I. Palik, Handbook of Optical Constants of Solids (Academic Press, Orlando, 1985).

    Google Scholar 

  14. S. Debnath, M. R. Islam, and M. S. R. Khan, Bull. Mater. Sci. 30, 315 (2007). https://doi.org/10.1007/s12034-007-0052-3

    Article  CAS  Google Scholar 

  15. C. Antoniou, M. G. Kosmadaki, A. J. Stratigos, et al., JEADV 22, 1110 (2008). https://doi.org/10.1111/j.1468-3083.2007.02580.x

    Article  CAS  PubMed  Google Scholar 

  16. https://eur-lex.europa.eu/LexUriServ/LexUriServ.do? uri=OJ:L:2006:265:0039:0043:en:PDF

  17. M. Pissavini, C. Tricaud, G. Wiener, et al., Int. J. Cosmet. Sci. 40, 263 (2018). https://doi.org/10.1111/ics.12459

    Article  Google Scholar 

  18. V. K. Ivanov, A. E. Baranchikov, O. S. Polezhaeva, et al., Russ. J. Inorg. Chem. 55, 325 (2010). https://doi.org/10.1134/S0036023610030034

    Article  CAS  Google Scholar 

  19. V. Petříček, M. Dušek, and L. Palatinus, Z. Kristallogr. 229, 345 (2014). https://doi.org/10.1515/zkri-2014-1737

    Article  CAS  Google Scholar 

  20. O. O. Stoianov, V. K. Ivanov, A. B. Shcherbakov, et al., Russ. J. Inorg. Chem. 59, 15 (2014). https://doi.org/10.1134/S0036023614020181

    Article  CAS  Google Scholar 

  21. V. K. Ivanov, O. S. Polezhaeva, and Y. D. Tret’yakov, Russ. J. Gen. Chem. 80, 604 (2010). https://doi.org/10.1134/S1070363210030412

    Article  CAS  Google Scholar 

  22. Y. Chen, T. Liu, C. Chen, et al., Mater. Lett. 96, 210 (2013). https://doi.org/10.1016/j.matlet.2013.01.069

    Article  CAS  Google Scholar 

  23. C. Sun, H. Li, H. Zhang, et al., Nanotecnology 16, 1454 (2005). https://doi.org/10.1088/0957-4484/16/9/006

    Article  CAS  Google Scholar 

  24. F. Meng, Q. Bo, C. Zhang, et al., J. Nanosci. Nanotechnol. 13, 6653 (2013). https://doi.org/10.1166/jnn.2013.7527

    Article  PubMed  Google Scholar 

  25. J. Q. Chen, Z. G. Chen, and Y. Wei, Mater. Sci. Forum 743–744, 389 (2013). https://doi.org/10.4028/www.scientific.net/msf.743-744.389

    Article  Google Scholar 

  26. Z. Zhang, L. Wang, M. Shao, et al., Micro Nano Lett. 7, 770 (2012). https://doi.org/10.1049/mnl.2012.0406

    Article  CAS  Google Scholar 

  27. T. V. Plakhova, A. Y. Romanchuk, S. N. Yakunin, et al., J. Phys. Chem. C 120, 22615 (2016). https://doi.org/10.1021/acs.jpcc.6b05650

    Article  CAS  Google Scholar 

  28. J. Feng, X. Zhang, J. Fu, et al., Catal. Commun. 110, 28 (2018). https://doi.org/10.1016/j.catcom.2018.03.001

    Article  CAS  Google Scholar 

  29. Y. Chen, T. Liu, C. Chen, et al., Ceram. Int. 39, 6607 (2013). https://doi.org/10.1016/j.ceramint.2013.01.096

    Article  CAS  Google Scholar 

  30. V. K. Ivanov, O. S. Polezhaeva, and Yu. D. Tret’yakov. Ross. Khim. Zh. 53 (2), 56 (2009).

    CAS  Google Scholar 

  31. A. E. Baranchikov, O. S. Polezhaeva, V. K. Ivanov, et al., CrystEngComm 12, 3531 (2010). https://doi.org/10.1039/c0ce00245c

    Article  CAS  Google Scholar 

  32. N. M. Zholobak, V. K. Ivanov, A. B. Shcherbakov, et al., J. Photochem. Photobiol. B 102, 32 (2011). https://doi.org/10.1016/j.jphotobiol.2010.09.002

    Article  CAS  PubMed  Google Scholar 

  33. V. K. Ivanov, A. B. Shcherbakov, A. V. Usatenko, Russ. Chem. Rev. 78, 855 (2009). https://doi.org/10.1070/RC2009v078n09ABEH004058

    Article  CAS  Google Scholar 

  34. www.carecreations.basf.com/sunscreen-simulator

  35. I. V. Kolesnik, A. N. Aslandukov, A. S. Arkhipin, et al., Crystals 9, 332 (2019). https://doi.org/10.3390/cryst9070332

    Article  CAS  Google Scholar 

  36. T. O. Shekunova, L. A. Lapkina, A. B. Shcherbakov, et al., J. Photochem. Photobiol. A 382, 111925 (2019). https://doi.org/10.1016/j.jphotochem.2019.111925

    Article  CAS  Google Scholar 

  37. A. Amaro-Ortiz, B. Yan, and J. D’Orazio, Molecules 19, 6202 (2014). https://doi.org/10.3390/molecules19056202

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  38. D. Schubert, R. Dargusch, J. Raitano, et al., Biochem. Biophys. Res. Commun. 342, 86 (2006). https://doi.org/10.1016/j.bbrc.2006.01.129

    Article  CAS  PubMed  Google Scholar 

  39. M. Das, S. Patil, N. Bhargava, et al., Biomaterials 28, 1918 (2007). https://doi.org/10.1016/j.biomaterials.2006.11.036

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  40. N. Singh, C. A. Cohen, and B. A. Rzigalinski, Ann. N. Y. Acad. Sci. 1122, 219 (2007). https://doi.org/10.1196/annals.1403.015

    Article  CAS  PubMed  Google Scholar 

  41. J. Niu, A. Azfer, L. M. Rogers, et al., Cardiovasc. Res. 73, 549 (2007). https://doi.org/10.1016/j.cardiores.2006.11.031

    Article  CAS  PubMed  Google Scholar 

  42. J. Niu, K. Wang, and P. E. Kolattukudy, J. Pharmacol. Exp. Ther. 338, 53 (2011). https://doi.org/10.1124/jpet.111.179978

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  43. S. M. Hirst, A. Karakoti, S. Singh, et al., Environ. Toxicol. 28, 107 (2013). https://doi.org/10.1002/tox.20704

    Article  CAS  PubMed  Google Scholar 

  44. J. Colon, L. Herrera, J. Smith, et al., Nanomedicine 5, 225 (2009). https://doi.org/10.1016/j.nano.2008.10.003

    Article  CAS  PubMed  Google Scholar 

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Funding

This work was supported by the Russian Science Foundation (project no. 19-13-00416).

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Correspondence to V. K. Ivanov.

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Translated by I. Kudryavtsev

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Kolesnik, I.V., Shcherbakov, A.B., Kozlova, T.O. et al. Comparative Analysis of Sun Protection Characteristics of Nanocrystalline Cerium Dioxide. Russ. J. Inorg. Chem. 65, 960–966 (2020). https://doi.org/10.1134/S0036023620070128

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