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The Water-Soluble Peripheral Substituted Phthalocyanines as Corrosion Inhibitors for Copper in 0.1 N HCl: Gravimetric, Electrochemical, SEM-EDS, and Quantum Chemical Calculations

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Abstract

Corrosion inhibition effects of water-soluble peripheral substituted cobalt, copper and zinc metallophthalocyanines (CoPc (1), CuPc (2) and ZnPc (3)) on the copper metal in 0.1 N HCl were investigated by using gravimetric, electrochemical, SEM-EDS analysis and quantum chemical calculations. On the electrochemical investigations and gravimetric analysis the highest inhibitor efficiency was obtained with CoPc (1) at 1 × 10–2 mol/L concentration. SEM-EDS results indicated parallel results and oxygen atom content increased in the order of ZnPc (3), CuPc (2) and CoPc (1). According to the quantum chemical calculations, following corrosion inhibition efficiency ranking was obtained: CoPc (1) > CuPc (2) > ZnPc (3).

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ACKNOWLEDGMENTS

This work was supported by The Research Fund of Sakarya University (Project Number: Hızdep-2019-5-19-56). This research was made possible by TUBITAK ULAKBIM, High Performance and Grid Computing Center (TR-Grid e-Infrastructure).

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Authors and Affiliations

  1. Faculty of Art and Sciences, Department of Chemistry, Kocaeli University, 41380, Kocaeli, Turkey

    Mustafa Akin & Neslihan Şaki

  2. Research and Development Center, Petroyağve Kimyasallar San. ve Tic. A.Ş, 41400, Kocaeli, Turkey

    Mustafa Akin

  3. Department of Chemistry, Sakarya University, Esentepe, 54187, Sakarya, Turkey

    Armağan Günsel, Ahmet T. Bilgiçli, Gulnur Arabaci & M. Nilüfer Yarasir

  4. Department of Chemistry, Cumhuriyet University, 58140, Sivas, Turkey

    Burak Tüzün

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  1. Mustafa Akin
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  2. Armağan Günsel
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  3. Ahmet T. Bilgiçli
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  4. Burak Tüzün
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Correspondence to Neslihan Şaki or M. Nilüfer Yarasir.

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Akin, M., Günsel, A., Bilgiçli, A.T. et al. The Water-Soluble Peripheral Substituted Phthalocyanines as Corrosion Inhibitors for Copper in 0.1 N HCl: Gravimetric, Electrochemical, SEM-EDS, and Quantum Chemical Calculations. Prot Met Phys Chem Surf 56, 609–618 (2020). https://doi.org/10.1134/S207020512003003X

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  • DOI: https://doi.org/10.1134/S207020512003003X

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