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Heterogeneous Catalysis and Nonlinear Dynamics

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Abstract

The present paper reviews recent achievements in studies of nonlinear phenomena in heterogeneous catalytic systems. The results concerning the multiplicity of steady states, reaction rate oscillations, and spatial structures on the catalyst surface were presented. The use of new physical methods in studies of reaction rate oscillations were discussed. New mathematical models of nonlinear phenomena in heterogeneous catalytic systems were analyzed, and their importance for heterogeneous catalysis was shown.

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Funding

This study was performed under government contract 46.13 (no. AAAA-A18-118020890105-3).

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Authors and Affiliations

  1. Semenov Institute of Chemical Physics, 119991, Moscow, Russia

    M. M. Slinko

  2. Faculty of Computational Mathematics and Cybernetics, Moscow State University, 119991, Moscow, Russia

    A. G. Makeev

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Correspondence to M. M. Slinko.

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Translated by L. Smolina

Abbreviations and notation: PEEM, photoemission electron microscopy; FIM, field ion microscopy; TOF, turnover number; TGA, thermogravimetric analysis; TPR, thermoprogrammed reaction; XRD, X-ray diffraction analysis; XPS, X-ray photoelectron spectroscopy; SEM, scanning electron microscopy; LEEM, low-energy electron microscopy; NAP, near-ambient pressure; STM, scanning tunneling microscopy; XAS, X-ray absorption spectroscopy; SXRD, surface X-ray diffraction; EXAFS, extended X-ray absorption fine structure; PM-IRAS, polarization modulation infrared absorption spectroscopy; ODE, ordinary differential equation; S.T.M., Sales–Turner–Maple mathematical model; CSTR, continuous stirred-tank reactor; 3D-RDC, reaction–diffusion–convection model including the diffusion and convective transport of particles in the reactor; PLIF, planar laser-induced fluorescence.

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Slinko, M.M., Makeev, A.G. Heterogeneous Catalysis and Nonlinear Dynamics. Kinet Catal 61, 495–515 (2020). https://doi.org/10.1134/S0023158420040114

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