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Effect of the Oxidation Degree of a Nickel Foil Surface on Its Catalytic Activity in the Reaction of Ethylene Oxidation

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Abstract

The effect of the oxidation degree of a nickel foil surface on the rate of catalytic oxidation of ethylene was studied by a pulse method at 600 and 700°C. It was shown that a reduced metallic surface demonstrated a high activity in partial ethylene oxidation, whereas a partially oxidized surface with an oxidation degree of ~24 formal O2 monolayers, in the total oxidation of C2H4. A SEM investigation has revealed that the oxidized surface was partially coated with nickel oxide nanocrystals. A further increase in the surface oxidation degree led to a continuous coverage of the Ni surface with oxide crystals and a dramatic decrease of catalytic activity. In addition, a low maximum of total ethylene oxidation was observed at 700°C in the range of surface oxidation degree of 95–135 O2 monolayers.

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Funding

This work was supported by the Russian Foundation for Basic Research (grant no. 19-03-00096) and state assignment V.46.13, 0082-2014-007 no. AAAA-A18-11802089010503.

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Authors and Affiliations

  1. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 119991, Moscow, Russia

    V. Yu. Bychkov, Yu. P. Tulenin, A. Ya. Gorenberg & V. N. Korchak

Authors
  1. V. Yu. Bychkov
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  2. Yu. P. Tulenin
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  3. A. Ya. Gorenberg
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  4. V. N. Korchak
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Corresponding author

Correspondence to V. Yu. Bychkov.

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Translated by Valentin Makhlyarchuk

Abbreviations: XAS, X-ray absorption spectroscopy; EXAFS, extended X-ray absorption fine structure; AP-XPS, ambient pressure X-ray photoelectron spectroscopy; DRIFTS, diffuse reflectance infrared Fourier transform spectroscopy; SEM, scanning electron microscopy; TPR-H2, temperature-programmed reduction with hydrogen.

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Bychkov, V.Y., Tulenin, Y.P., Gorenberg, A.Y. et al. Effect of the Oxidation Degree of a Nickel Foil Surface on Its Catalytic Activity in the Reaction of Ethylene Oxidation. Kinet Catal 61, 631–636 (2020). https://doi.org/10.1134/S0023158420040023

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