Skip to main content
Log in

Manganese Incorporated Eosin Y Dye/Graphene Nanocomposite: an Efficient Visible Light Active Photocatalyst

  • CHEMICAL PHYSICS OF NANOMATERIALS
  • Published:
Russian Journal of Physical Chemistry B Aims and scope Submit manuscript

Abstract

A novel graphene supported Mn-doped Eosin Y based nanocomposite has been successfully prepared by hydrothermal method. Eosin Y–graphene nanocomposite acts uniquely as a metal free visible light photocatlyst without TiO2 or Bismuth Vanadate and incorporation of Mn further enhances the activity of the composite. Photocatalyst was active under visible light and photocatalytic activity strongly depends on pH of the degrading dye solutions. Photo-activation of the system in visible light is the consequence of Eosin Y doping while strong photocatalytic performance of the composite is attributed to reduce graphene oxide that supports better mobility of electrons within composites as well as provide more sites for photo-reduction. This newly developed composite has a potential to remove industrial dyes efficiently and cheaply to reduce water pollution.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.

Similar content being viewed by others

REFERENCES

  1. V. M. Esquerdo, T. Cadaval, Jr., G. Dotto, and L. Pinto, J. Colloid Interface Sci. 424, 7 (2014).

    Article  CAS  Google Scholar 

  2. Z.-L. Wu, F. Liu, C.-K. Li, X.-Q. Chen, and J.-G. Yu, Colloids Surf. A 509, 65 (2016).

    Article  CAS  Google Scholar 

  3. Y. Yang, G. Liu, J. T. Irvine, and H. M. Cheng, Adv. Mater. 28, 5850 (2016).

    Article  CAS  Google Scholar 

  4. P. Kundu, A. Kaur, S. Mehta, and S. K. Kansal, J. Nanosci. Nanotechnol. 14, 6991 (2014).

    Article  CAS  Google Scholar 

  5. A. Shameem, A. A. Kashmeri, F. Nawaz, M. S. Mahr, A. Pervaiz, and J. Iqbal, Chem. Sel. 3, 6701(2018).

    CAS  Google Scholar 

  6. S. V. Faleev, M. Van Schilfgaarde, and T. Kotani, Phys. Rev. Lett. 93, 126406 (2004).

    Article  Google Scholar 

  7. Y. Qian, S. Lu, and F. Gao, Mater. Lett. 65, 56 (2011).

    Article  CAS  Google Scholar 

  8. T. Chhabra, A. Kumar, A. Bahuguna, and V. Krishnan, Vacuum 160, 333 (2019).

    Article  CAS  Google Scholar 

  9. H. Yang, S. V. Kershaw, Y. Wang, X. Gong, S. Kalytchuk, A. L. Rogach, and W. Y. Teoh, J. Phys. Chem. C 117, 20406 (2013).

    Article  CAS  Google Scholar 

  10. T.-F. Yeh, J. Cihlář, C.-Y. Chang, C. Cheng, and H. Teng, Mater. Today 16, 78 (2013).

    Article  CAS  Google Scholar 

  11. S. William, J. Hummers, and R. E. Offeman, J. Amer. Chem. Soc. 80, 1339 (1958).

    Article  Google Scholar 

  12. X. Li, Y. Du, J. Dai, X. Wang, and P. Yang, Catal. Lett. 118, 151 (2007).

    Article  CAS  Google Scholar 

  13. X. Li, B. Li, M. Cheng, Y. Du, X. Wang, and P. Yang, J. Mol. Catal. A 284, 1 (2008).

    Article  CAS  Google Scholar 

  14. Z.-H. Liu, Z.-M. Wang, X. Yang, and K. Ooi, Langmuir 18, 4926 (2002).

    Article  CAS  Google Scholar 

  15. Y. Qian, S. Lu, and F. Gao, J. Mater. Sci. 46, 3517 (2011).

    Article  CAS  Google Scholar 

  16. V. Subramanian, H. Zhu, and B. Wei, J. Power Sources 159, 361 (2006).

    Article  CAS  Google Scholar 

  17. M. Frisch, G. Trucks, H. B. Schlegel, G. Scuseria, M. Robb, J. Cheeseman, G. Scalmani, V. Barone, B. Mennucci, G. Petersson, et al., Gaussian 09 (Gaussian, Inc., Wallingford CT, 2009).

    Google Scholar 

  18. Z. Mou, Y. Dong, S. Li, Y. Du, X. Wang, P. Yang, and S. Wang, Int. J. Hydrogen Energy 36, 8885 (2011).

    Article  CAS  Google Scholar 

  19. J. Paredes, S. Villar-Rodil, A. Martínez-Alonso, and J. Tascon, Langmuir 24, 10560 (2008).

    Article  CAS  Google Scholar 

  20. G. R. Desiraju, Acc. Chem. Res. 35, 565 (2002).

    Article  CAS  Google Scholar 

  21. Y. Zhu, Z. Yang, M. Chi, M. Li, C. Wang, and X. Lu, Talanta 181, 431 (2018).

    Article  CAS  Google Scholar 

Download references

ACKNOWLEDGMENTS

The authors acknowledge the financial and technical support from Punjab Bio-energy Institute (PBI) located at University of Agriculture Faisalabad (UAF), Pakistan funded by Govt. of the Punjab, Pakistan. The authors also acknowledge the technical support from Department of Chemistry, University of Agriculture Faisalabad, Pakistan.

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Faisal Nawaz or Javed Iqbal.

Ethics declarations

Authors declare that there is no conflict of interest and all are agreed on the publication of this work.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ahmad Ali Kashmeri, Nawaz, F., Yousaf, M. et al. Manganese Incorporated Eosin Y Dye/Graphene Nanocomposite: an Efficient Visible Light Active Photocatalyst. Russ. J. Phys. Chem. B 14, 552–558 (2020). https://doi.org/10.1134/S1990793120030069

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1990793120030069

Keywords:

Navigation