Abstract
We have synthesized oxide composites based on TiO2 modified with aliovalent cations, W6+, Co3+, Cu2+, and Fe3+, in the range 5–30 wt %. Its deviation from stoichiometry is increased by active generation of Ti3+ cations during vacuum calcination at temperatures from 500 to 800°C. The photocatalytic activity (PCA) of the composites for dye degradation reactions under illumination with visible light exceeds that of analogous samples calcined in air. The PCA of the synthesized materials is an intricate function of their composition and structure. The highest PCA, which considerably exceeds the PCA of TiO2 of similar origin and that of the commercially available Degussa P-25 TiO2, is offered by the optimal compositions of the W- and Cu-modified samples for ferroin and methylene blue degradation and the Co- and Fe-modified samples for aniline degradation.
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REFERENCES
Henderson, V.A., A surface science perspective on TiO2 photocatalysis, Surf. Sci. Rep., 2011, vol. 66, pp. 185–297.
Bahnemann, W., Muneer, M., and Haque, M.M., Titanium dioxide-mediated photocatalysed degradation of few selected organic pollutants in aqueous suspensions, Catal. Today, 2007, vol. 124, pp. 133–148.
Gurevich, Yu.Ya. and Pleskov, Yu.V., Fotoelektrokhimiya poluprovodnikov (Photoelectrochemistry of Semiconductors), Moscow: Nauka, 1983.
Yan, J., Tang, Z., Luo, S., and Zhang, Z., The modified photocatalysts on a basis titanium dioxide working at an irradiation seen light, Rare Met. Mater. Eng., 2003, vol. 32, suppl. 1, pp. 582–585.
Fenezonov, V.B. and Parmon, V.N., Introduction to the physical chemistry of texturing of heterogeneous photocatalysts, in Promyshlennyi kataliz v lektsiyakh (Lectures on Industrial Catalysis), Moscow: Kalvis, 2005, part 1.
Sedneva, T.A., Lokshin, E.P., and Belikov, M.L., Ferroin adsorption on TiO2-based photocatalytic materials, Inorg. Mater., 2012, vol. 48, no. 5, pp. 480–487.
Liu, H., Ma, H.T., Li, X.Z., et al., The enhancement of TiO2 photocatalytic activity by hydrogen thermal treatment, Chemosphere, 2003, vol. 50, no. 1, pp. 39–46.
Mushii, R.Ya. and Pamfilov, A.V., Photoreduction of methylene blue on titanium dioxide, Ukr. Khim. Zh. (Russ. Ed.), 1958, vol. 24, pp. 462–466.
Pamfilov, A.V., Mushii, R.Ya., and Mazurkevich, Ya.S., Photocatalytic activity of anatase and rutile, Ukr. Khim. Zh. (Russ. Ed.), 1962, vol. 28, no. 5, pp. 589–594.
Pamfilov, A.V. and Mazurkevich, Ya.S., Photocatalysis and surface properties, Ukr. Khim. Zh. (Russ. Ed.), 1964, vol. 30, no. 1, pp. 43–48.
Mazurkevich, Ya.S., Noval’kovskii, N.P., Pamfilov, A.V., and Savitskii, A.V., Magnetic susceptibility and photocatalytic activity of zinc and titanium oxides, Ukr. Khim. Zh. (Russ. Ed.), 1965, vol. 31, no. 3, pp. 252–257.
Hauffe, K., Application of the semiconductor theory to problems of heterogeneous catalysis, Angew. Chem., 1955, vol. 67, pp. 189–207.
Sedneva, T.A., Lokshin, E.P., Belikov, M.L., and Kalinnikov, V.T., RF Patent 2 435 733, Byull. Izobret., 2011, no. 34.
Sedneva, T.A., Lokshin, E.P., Belikov, M.L., and Belyaevskii, A.T., Preparation and properties of photocatalytic composites based on titanium(IV), copper(II), and sodium(I) oxides, Inorg. Mater., 2014, vol. 50, no. 11, pp. 1104–1113. https://doi.org/10.1134/S0020168514110168
Sedneva, T.A., Lokshin, E.P., Belikov, M.L., and Kalinnikov, V.T., Photocatalytic activity of tungsten-modified titanium oxide, Dokl. Phys. Chem., 2012, vol. 443, no. 1, pp. 57–59. https://doi.org/10.1134/S0012501612030037
Sedneva, T.A., Lokshin, E.P., and Belikov, M.L., Photocatalytic activity of iron-modified titanium oxide, Khim. Tekhnol., 2012, no. 2, pp. 75–82.
Spravochnik khimika (Chemist’s Handbook), Nikol’skii, B.P., Ed., Leningrad: Khimiya, 1966, vol. 1.
Gregg, S.J. and Sing, K.S.W., Adsorption, Surface Area, and Porosity, New York: Academic, 1982.
Nayanova, E.V., Elipasheva, E.V., Sergeev, G.M., and Sergeeva, V.P., Redox properties of methylene blue as a promising photometric reagent for determination of halogen oxidants, Anal. Kontrol, 2015, vol. 19, no. 2, pp. 154–160.
Vakulin, I.V., Bugaets, D.V., and Zil’berg, R.A., Accuracy analysis for AM1, RM1, and PM7 semiempirical calculations of the redox potentials of substituted phenols, quinones, and anilines, Butlerovsk.Soobshch., 2017, vol. 52, no. 11, pp. 53–59.
Burykina, O.V., Mal’tseva, V.S., and Fat’yanova, E.A., Fiziko-khimicheskie kharakteristiki organicheskikh i neorganicheskikh veshchestv. Metodicheskoe posobie (Physicochemical Characteristics of Organic and Inorganic Substances), Kursk: KGTU, 2008.
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Belikov, M.L., Sedneva, T.A. & Lokshin, E.P. Synthesis, Properties, and Visible Light Photocatalytic Activity of Nonstoichiometric Titanium Dioxide-Based Composites. Inorg Mater 56, 723–733 (2020). https://doi.org/10.1134/S0020168520060023
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DOI: https://doi.org/10.1134/S0020168520060023